The invention provides a catalyst for propylene
ammoxidation reaction and a preparation method and application thereof, and the preparation method comprises the following steps: uniformly mixing a
metal salt solution with a first
silicon source and alkaline silica
sol, and then mixing with a second
silicon source to obtain
slurry; and carrying out
spray drying and
roasting on the
slurry to obtain the catalyst for propylene
ammoxidation reaction, wherein the first
silicon source comprises one or more of acidic silica
sol, tetraethoxysilane and
potassium silicate, and the second silicon source is a
solid silicon source. According to the preparation method disclosed by the invention, the acid-base property of the catalyst can be adjusted by introducing the liquid first silicon source, the composition of the catalyst is further regulated and controlled, and the selectivity of byproducts CO and CO2 in the propylene
ammoxidation reaction is reduced; in addition, the
solid second silicon source is added to provide a core for
drying and forming of the catalyst, distribution of catalyst particles is more concentrated, the
mechanical strength of the catalyst is enhanced, and the use stability of the catalyst and the conversion rate and selectivity of a catalytic reaction are improved.