The invention relates to a method for preparing a porous polyvinylidene fluoride alloy membrane for wastewater treatment and recycling, and belongs to the technical field of membrane separation technology and wastewater treatment and reutilization. The method comprises the following steps: firstly, weighing polyvinylidene fluoride, polymethyl methacrylate, a diluent or a latent solvent, and an additive according to proportion, placing the raw materials into a mixer in turn for mixing, cooling and granulating the mixture in the air, and obtaining blend raw materials; and secondly, adding the blend raw materials into a double screw extruder to form fused blends, making the fused blends be extruded by double screws and pass through a filter and a spinning pump in turn to form hollow nascent fibers, cooling and washing the hollow nascent fibers, and drying the hollow nascent fibers in the air. The porous polyvinylidene fluoride alloy hollow fiber microporous membrane prepared by the method has good chemical corrosion resistance and hydrophilicity, high strength, large flux, good toughness, uniform pore distribution and superior pollution resistance, and is most suitable to be used in MBR.