63results about How to "High active site density" patented technology

Carbon nanotube structures are disclosed in which nanotubes are disposed over a porous support such as a foam, felt, mesh, or membrane. Techniques of making these structures are also disclosed. In some of these techniques, a support is pretreated with a templated surfactant composition to assist with the formation of a nanotube layer.

Carbon nanotube structures are disclosed in which nanotubes are disposed over a porous support such as a foam, felt, mesh, or membrane. Techniques of making these structures are also disclosed. In some of these techniques, a support is pretreated with a templated surfactant composition to assist with the formation of a nanotube layer.

The invention discloses a hydrorefining catalyst and a preparation method thereof. The catalyst is a bulk phase hydrorefining catalyst, and comprises alumina and hydrogenation active metal components W, Ni and Mo. The surface phase of the catalyst has the characteristics of high content of active metals, large density of active sites, uniform dispersion of the active metals, good coordination and cooperation among the active metals, and high utilization rate of the active metals, and the catalyst has the characteristics of reasonable pore structure, high mechanical strength and high hydrodesulfurization and hydrodenitrogenation reaction performances, and is especially suitable for being applied to ultra deep hydrodesulfurization and nitrogen removal reaction of diesel oil fraction.

A continuous, uninterrupted two-step treatment process capable of forming nanometer scale physical structures on the surface of articles fabricated from metallic, ceramic, glass, or plastic materials, and then depositing a thin conformal coating on the nanostructured surface such that the physical structures previously produced are neither masked nor are the dimensions of the physical structures substantially altered. In an additional embodiment, a thicker coating can be grown from the thin conformal coating which itself can be nanostructured as it is deposited. In this case adhesion of the thicker coating is not dependent upon the use of conventional surface pretreatments such as machining, chemical etching, or abrasive blasting. Surface texturing may be performed by ion beam sputtering, and ion assisted coating forms the thin conformal coating, and thicker coating if desired. The treatment process is useful for improving the mechanical, catalytic, chemical, or biological activity of the surfaces so treated. The process thus has application on industrial machinery and equipment of all types, engines of all types, manufacturing tooling and wear parts of all types, and medical equipment and prostheses.

A continuous, uninterrupted two-step treatment process capable of forming nanometer scale physical structures on the surface of articles fabricated from metallic, ceramic, glass, or plastic materials, and then depositing a thin conformal coating on the nanostructured surface such that the physical structures previously produced are neither masked nor are the dimensions of the physical structures substantially altered. In an additional embodiment, a thicker coating can be grown from the thin conformal coating which itself can be nanostructured as it is deposited. In this case adhesion of the thicker coating is not dependent upon the use of conventional surface pretreatments such as machining, chemical etching, or abrasive blasting. Surface texturing may be performed by ion beam sputtering, and ion assisted coating forms the thin conformal coating, and thicker coating if desired. The treatment process is useful for improving the mechanical, catalytic, chemical, or biological activity of the surfaces so treated. The process thus has application on industrial machinery and equipment of all types, engines of all types, manufacturing tooling and wear parts of all types, and medical equipment and prostheses.

The invention belongs to the field of fuel cell electrocatalysts, and provides a preparation method and application of a porous composite material electrocatalyst based on bimetallic macrocyclic compound. The method comprises the steps of: stirring transition metal salt, a nitrogen-containing organic ligand and a metal macrocyclic compound according to a certain proportion at the temperature of 0-80 DEG C by adopting simple solution reaction and performing reaction for a certain period of time, so that the metal macrocyclic compound is embedded into a pore channel formed by the metal salt andthe organic ligand to serve as a precursor material, and the final catalyst is obtained through high-temperature heat treatment. The material is high in porosity, the metal macrocyclic compound is embedded, the active site density is remarkably improved, and particle aggregation and hole collapse in the high-temperature pyrolysis process are avoided. Compared with the traditional non-noble metal electrocatalyst, the material has higher oxygen reduction catalytic activity under acidic and alkaline conditions.

The invention discloses a method for preparing dendritic Pt-Ni-Cu alloy nano-particles. Chloroplatinic acid, copper chloride and nickel chloride are taken as raw materials, glycine and methyl are taken as double reducing agents, polyvinylpyrrolidone is taken as a protective agent and stabilizer, dendritic Pt-Ni-Cu alloy nano-particles with higher selectivity are prepared, and the preparation method is green and clean. The step atoms of the obtained dendritic Pt-Ni-Cu alloy nano-particles are many, the active site density is high, excellent methyl and formic acid electrochemical activities areshown, and the dendritic Pt-Ni-Cu alloy nano-particles have a wide application prospect.

The invention relates to an oxygen reduction electrocatalyst and a preparation method thereof and relates to a catalyst. The oxygen reduction electrocatalyst is prepared from the following raw materials: a metal source, a nitrogen source, carbon black, inorganic acid and peroxide, as well as sulfanilic acid, inorganic base and reduced iron powder. One preparation method comprises the following steps of: dissolving the carbon black in water for ultrasonic screening, and carrying out ultrasonic treatment and dispersion treatment; encapsulating the carbon black by a polymer; washing the encapsulated carbon black; adding water and a ferric slat into a dried solid, carrying out rotary evaporation, drying and rough grinding to obtain a powdery solid the ingredient of which is iron doped polymer encapsulated carbon black; carrying out primary thermal treatment; pickling the resulting product; carrying out secondary thermal treatment on the pickled product to obtain the electrocatalyst. Another preparation method comprises the following steps of: dissolving the carbon black in water for ultrasonic screening, and carrying out ultrasonic treatment and dispersion treatment; carrying out carbon black grafting; encapsulating the carbon black by a polymer; washing the encapsulated carbon black; adding water and a ferric slat into a dried solid, carrying out rotary evaporation, drying and rough grinding to obtain a powdery solid the ingredient of which is iron doped polymer encapsulated grafted carbon black; carrying out primary thermal treatment; pickling the resulting product; carrying out secondary thermal treatment on the pickled product to obtain the electrocatalyst. The electrocatalyst is excellent in performance, low in cost, and easy in mass production.

The invention discloses an efficient photo-catalytic reactor which comprises an upper cover plate and a base. The upper cover plate is arranged on the base, the efficient photo-catalytic reactor is characterized in that a first rectangular concave plane is formed in the upper end surface of the base, conducting glass is placed in the first rectangular concave plane, and a photocatalyst is arranged on the upper surface of the conducting glass; the photocatalyst is a nanorod array thin film photocatalyst; a second rectangular concave plane is formed in the lower end surface of the upper cover plate and corresponds to the first rectangular concave plane in position; an inverted micro boss array is arranged in the second rectangular concave plane; the upper cover plate is provided with a fluid inlet and a fluid outlet, and the fluid inlet and the fluid outlet communicate with the second rectangular concave plane through micro fluid input channels and micro fluid output channels correspondingly; and the micro fluid input channels and the micro fluid output channels are formed in the upper cover plate. The efficient photo-catalytic reactor provided by the invention is simple in structure, easy to mount, low in cost, high in reaction efficiency and capable of being widely applied to the fields of energy, environment protection and the like.

The invention belongs to the technical field of preparation of anticorrosive coatings, and particularly relates to a preparation method and application of a modified anticorrosive super-hydrophobic integrated coating, the method comprises the following steps: respectively preparing a graphene titanium dioxide compound from graphene and tetrabutyl titanate, preparing a zinc-aluminum hydrotalcite anticorrosive material from sodium metavanadate, zinc chloride and aluminum chloride, preparing a PDMS organic emulsion from polydimethylsiloxane and tetrahydrofuran, then performing surface modification on the graphene titanium dioxide compound through dopamine hydrochloride and a zinc-aluminum hydrotalcite anticorrosive material to obtain a dopamine modified composite material, and finally, preparing the modified anticorrosive super-hydrophobic integrated coating from the dopamine modified composite material and a PDMS organic emulsion. Performance tests show that compared with a conventionalmarine anticorrosive coating, the coating prepared by the invention has better anticorrosive and super-hydrophobic effects, is applied to the field of marine corrosion prevention, and can effectivelyprolong the service life of the coating on a protective substrate.

The invention discloses an iron-nitrogen doped hollow porous carbon material and a preparation method thereof, and relates to a synthesis technology of porous materials. The preparation method comprises the following steps: (1) synthesizing SiO2 spheres; (2) preparing SiO2 modified by polyelectrolyte; (3) preparing an iron-doped ZIF-8 coated polyelectrolyte modified SiO2 composite material; and (4) preparing an iron-nitrogen doped hollow porous carbon material. The iron-nitrogen doped hollow porous carbon material prepared by the preparation method disclosed by the invention is uniform in size, has good ORR catalytic activity and stability, and is lower in price compared with a traditional Pt / C catalyst.

The invention discloses a preparation method of porous multi-branch Pt-Ni-Cu alloy nanoparticles. The invention takes chloroplatinic acid, copper chloride and nickel chloride as raw materials, glycineand PVP as dual reducing agents, adopts specific addition amount of 1, 3- propylene glycol and NaF, the porous and multibranched Pt-Ni-Cu alloy nanoparticles which are highly selective are prepared through a microwave synthesis method, and the preparation method is green and efficient. The porous multibranched Pt-Ni-Cu alloy nanoparticles have many step atoms and high active site density, which show excellent electrochemical activity of methanol and formic acid, and have wide application prospects.

The invention relates to rough octahedral-morphology PtCoFe alloy particles and a preparation method thereof. The rough octahedral-morphology PtCoFe alloy nano particles with relatively high selectivity are obtained by adopting chloroplatinic acid, cobalt chloride and ferric trichloride as raw materials, adopting glycine as a reduction agent and morphology control agent, adopting SDS as a protective agent, and adding a specific content of NaI in an oxygen atmosphere. The preparation method is environment-friendly and clean. The obtained rough octahedral-shape PtCoFe alloy nano particles are more in step atoms, high in active site density and wide in application prospect.

The invention relates to the technical field of alkylation catalyzed by acidic polymerized ionic liquids, and particularly relates to a method of preparing alkylate oil by utilizing a Lewis acid based acidic polymerized ionic liquid catalyst. A polymerized ionic liquid acidified by adopting a Lewis acid is adopted as the catalyst of the method, and a continuous catalytic liquid-phase butane / butylenes alkylation reaction is performed at 20-200 DEG C by adopting a fixed bed reactor. The catalyst is easy to prepare, durable in activity, convenient to regenerate and free of generation of waste acids, thus achieving green alkylation.

The invention relates to a realization method for improving the electrooxidation activity of a formic acid fuel cell. Formic acid electrooxidation test is cyclic voltammetry test in a 0.5 M H2SO4 and0.25 M HCOOH electrolyte, prepared polygonal PtCoFe is used as a formic acid fuel cell electrooxidation catalyst, PtCoFe alloy nano-particles having a high selectivity and a polygonal morphology are prepared in a hydrogen reducing atmosphere through using chloroplatinic acid, cobalt chloride and iron trichloride as raw materials, PVP as a reducing agent and a protecting agent and adding specific amounts of CTAB and NaBr, and the preparation process is green and clean. The obtained polygonal PtCoFe alloy nano-particles have the advantages of many step atoms, high active site density, excellentelectrocatalytic activity in formic acid fuel cell electrooxidation catalysis experiments, and wide application prospect.

The invention relates to polygonal morphology PtCoFe alloy nano-particles and a preparation method of the nano-particles. According to the method, the polygonal morphology PtCoFe alloy nano-particleswhich are high in selectivity can be obtained by taking chloroplatinic acid, cobalt chloride and ferric trichloride as raw materials, taking PVP as reducing agent and protecting agent, adding a certain amount of CTAB and NaBr and preparing in a hydrogen reduction atmosphere. The preparation method is green and clean. The obtained polygonal morphology PtCoFe alloy nano-particles are more in step atom, high in active site density and wide in application prospect.

The invention belongs to the technical field of application of an energy storage material, and gives out a nanometer composite oxygen electrode material. The nanometer composite oxygen electrode material comprises a carbon nanotube, wherein the carbon nanotube is provided with a hollow inner cavity, the inner cavity is encircled by a carbon layer, metal particles are arranged in the inner cavity of the carbon nanotube, and heteroatoms are doped in the carbon layer. The nanometer composite oxygen electrode material is a core-shell nanometer tubular composite material, shows excellent oxygen catalytic capability and shows relatively high power density, energy density and stability when applied to a metal-air battery.

The invention belongs to the technical field of new nano materials, and particularly relates to a preparation method of a CuO-Cu2O / CM nanowire array heterostructure and an application. The preparationmethod comprises the steps: mixing and stirring a NaOH solution and an ammonium persulfate solution to obtain a clear solution, placing a pretreated copper net in the mixed solution to be subjected to a soaking reaction, washing a product with distilled water, and then performing air drying to obtain a Cu(OH)2 precursor; placing the obtained Cu(OH)2 precursor in a tubular furnace, and performingcalcining to obtain a CuO-Cu2O / CM nanowire array. The nanowire array prepared by the invention has the advantages of large surface area, high active site density, good stability, high catalytic efficiency and the like, and is beneficial to generating a PEC signal.

The invention belongs to the field of new nanomaterials, and in particular relates to a composite material carrying a Cu2O-CuO nanowire array and a preparation method thereof, a biosensor and application thereof. The invention uses copper foam as a substrate to prepare a Cu(OH)2 nanowire array by a room-temperature solvent-heat method, and prepares a three-dimensional composite material loaded with the Cu2O-CuO nanowire array by annealing in air by precisely controlling time and temperature. The preparation method is simple and easy to operate. CuO will consume the electrons on the Cu2O conduction band by the composite material under light to reduce the photo-generated electron-hole recombination rate. As a three-dimensional electrode, the Cu2O-CuO nanowire array has a large surface area,high active site density and low series resistance, which is conducive to the generation of optoelectronic signals. The biosensor made of the composite material is used for the detection of tyrosinase.

The invention provides a copper-based methanol synthesis catalyst and a preparation method thereof. The method includes the steps that copper-zinc mixed liquor is mixed with a first precipitator aqueous solution in a parallel flow mode, the pH is controlled to be 7-8, standing is performed for ageing, and slurry A is formed; a second precipitator aqueous solution is added into a soluble aluminum salt aqueous solution, the pH is controlled to be 7-8, the temperature is controlled to be 40-50 DEG C, standing is performed for ageing, and slurry B is obtained; the slurry A and the slurry B are mixed and filtered, a solid phase is washed, dried, roasted and formed, and the copper-based methanol synthesis catalyst is obtained. According to the preparation method, the steps are simple, the controllability is high, the raw material source is wide, and industrialization is easy to achieve; by the adoption of the preparation method, the copper-based methanol synthesis catalyst with high catalytic activity and heat stability can be obtained and is suitable for producing methanol with synthesis gas containing CO, CO2 and H2 under the low temperature and low pressure conditions; besides, the catalyst does not need reduction before use and can be conveniently applied and popularized on a large scale.

The invention discloses a metal phase layered molybdenum disulfide / reduced graphene oxide composite catalyst carrier and a preparation method thereof.The preparation method comprises the steps that graphene oxide dispersion liquid, sulfur-doped reduced graphene oxide hydrogel and sulfur-doped reduced graphene oxide aerogel are prepared in sequence; and mixing the aerogel with a sulfur source and a molybdenum source at 150-180 DEG C for reaction to obtain the metal phase layered molybdenum disulfide / reduced graphene oxide composite catalyst carrier. According to the preparation method, the anchoring effect of reduced graphene oxide on molybdenum disulfide is improved through sulfur doping, the molybdenum disulfide exists in a metal phase instead of a conventional 2H phase, high conductivity of the catalyst carrier is guaranteed, the oxidation resistance of the catalyst carrier is enhanced through introduction of the metal phase molybdenum disulfide and the sulfur element, and the preparation method is suitable for industrial production. The composite catalyst carrier also has the advantages of large specific surface area, high catalytic activity and the like, and has a good application prospect.

The invention discloses a preparation method for an oxygen-reduction electrocatalyst taking aramid amide as a main precursor. The oxygen-reduction electrocatalyst is prepared from the following raw materials based on parts by weight: 5-20 parts of phenylenediamine, 5-20 parts of phthalic acid, 1-5 parts of metal source, 5-40 parts of carbon black and 8-20 parts of inorganic acid. The preparation method comprises the steps of performing ultrasonic dissolving on the carbon black, wrapping the polymer, washing, doping a metal source, performing initial thermal treatment, pickling and performing secondary thermal treatment. The oxygen-reduction electrocatalyst prepared by the method does not contain precious metal or contains low-content precious metal, a low-cost nitrogen-containing compound(aramid amide precursor is used as a nitrogen source) is employed to substitute a high-cost macrocyclic compound such as porphyrin and phthalocyanine, the oxygen-reduction electrocatalyst is low in cost, and yield is easy. By a mode wrapping the carbon black with an in-situ polymer, uniform distribution of active sites in a carbon black surface is facilitated, the active site density is improved,moreover, the yield of oxygen-reduction by-product H2O2 is reduced, the stability of the catalyst is ensured, and excellent performance is achieved.

The invention relates to a polyhedral PtCoFe nano-catalyst and study about the electro-catalytic performance thereof on methanol. Prepared polygonal PtCoFe is adopted as the catalyst, the catalyst isprepared from chloroplatinic acid, cobalt chloride and ferric trichloride as the raw materials, PVP is adopted as the reducing agent and protective agent, and CTAB and NaBr of specific content are added to prepare the polygonal PtCoFe nano-catalyst with high selectivity in a hydrogen reducing atmosphere, the preparation method is green and clean, the obtained polygonal PtCoFe alloy catalyst particles have a lot of stepped atoms and high active site density, cyclic voltammetry is employed for methanol electrooxidation testing in 0.5M H2SO4+2M CH3OH electrolyte, the polygonal PtCoFe nano-catalyst shows excellent electrocatalytic activity in electrooxidation catalytic experiments of methanol, and has wide application prospects.

The invention discloses a preparation method of an iron atom-loaded graphene-based nano material. The preparation method comprises the following steps of 1, adding 50-100mg of anhydrous ferric chloride into a 25ml volumetric flask, and adding tetrahydrofuran for dissolving to prepare a 3mg / ml ferric chloride solution; 2, taking 10-20 mg of graphene oxide and putting into the 25 ml volumetric flask, adding tetrahydrofuran for dissolution, and adding 126 mu L of the ferric chloride solution with the concentration being 3 mg / ml prepared in the step 1; 3, stirring the mixed solution in the step 2 on a magnetic stirrer for 12-36 hours until the solvent tetrahydrofuran is completely volatilized and a solid mixture is formed; and 4, grinding the solid mixture obtained in the step 3 into powder, putting the powder into a calcining vessel, putting the calcining vessel into a high-temperature furnace for calcining, raising the temperature from the room temperature 25 DEG C to 400-600 DEG C at the temperature raising rate of 1-10 DEG C / min, preserving heat for 1-3 hours, and then cooling to the room temperature. According to the present invention, the nano material with high active site density and high monatomic loading capacity is successfully prepared only by a one-step calcination method, and the inert atmosphere adopted for combustion is relatively safer and easy to realize.

The invention relates to an implement method for improving electrooxidation activity of a methanol fuel cell. The implement method is characterized in that: a cling cyclic voltammetry test is performed in 0.5M H2SO4+ and 2M CH3OH electrolyte, a prepared rough octahedron PtCoFe is taken as an electrooxidation catalyst of the methanol fuel cell; the catalyst is a high-selectivity rough octahedron PtCoFe alloy nanoparticle prepared by adding a specified volume of SDS and NaIinto taking chloroplatinic acid, cobalt chloride and ferric trichloride serving as raw materials, taking glycine serving asa reduction agent and a protection agent, and adding a specified volume of SDS and NaI. The preparation method is environment-environmentally friendly, the prepared rough octahedron PtCoFe alloy nanoparticle has a large quantity of stepped atoms, is high in active site density, is superior on in the aspect of electrocatalytic activity in the electrooxidation catalytic experiment of the methanol fuel cell, and has wide application prospect.

The invention provides a copper-based methanol synthesis catalyst and a preparation method thereof. The method comprises: mixing the copper-zinc mixed solution and the first precipitant aqueous solution in parallel, controlling the pH to be 7-8, and standing for aging to form a slurry A ; Add the second precipitant aqueous solution to the soluble aluminum salt aqueous solution, control the pH to 7-8, and the temperature to 40-50°C, leave it to age to obtain slurry B; mix slurry A and slurry B, filter, and pass through the solid phase Washing, drying, roasting, molding treatment, that is, the copper-based methanol synthesis catalyst is obtained. The above preparation method has simple steps, strong controllability, wide sources of raw materials, and easy industrialization. The preparation method of the present invention can obtain a copper-based methanol synthesis catalyst with high catalytic activity and thermal stability, which is suitable for the synthesis of methanol containing CO, CO2, H2 The synthesis gas can produce methanol under the condition of low temperature and low pressure, and the catalyst of the invention does not need to be reduced before use, which is convenient for large-scale popularization and application.

The invention provides a sulfur-tolerant catalyst for synthesized gas methanation. The sulfur-tolerant catalyst is characterized by being prepared form 60-70 wt% of Mo, 23-35 wt% of S, 3-6 wt% of Al and 1-4.5 wt% of an auxiliary. The sulfur-tolerant catalyst has the advantages of being simple in preparation process, good in catalytic performance and high in methane selectivity.

A method for recovering a byproduct ethylbenzene in production of epoxypropane by using a co-oxidation method comprises the following steps: (1) sequentially inputting reaction liquid from a POCHP peroxide section and a hydrogenolysis reaction section into an ethylbenzene heavy component removal tower and an ethylbenzene light component removal tower to remove heavy components and light components so as to obtain an ethylbenzene-rich stream; (2) feeding the ethylbenzene-rich stream obtained in the step (1) into a rectifying tower for azeotropic distillation by taking water as an entrainer and filling a reaction section with a catalyst, taking an ethylbenzene azeotrope formed byethylbenzene in the ethylbenzene-rich stream and water as a tower top material to be extracted from the tower top; enabling the residual 1, 5-dimethyl-2, 4-dioxane to be subjected to ring-opening decomposition under the action of a catalyst in the reaction section, and discharging a decomposition product, together with cyclohexanol, cumene and water from a tower kettle as a tower kettle material; (3) coalescing and separating water from the tower top material obtained in the step (2) to obtain an ethylbenzene product; and (4) coalescing and separating water from the tower kettle material obtained in the step (2) to obtain waste oil, and discharging the waste oil. According to the recovery method, high-purity recovery of the byproduct ethylbenzene can be realized, and the recovery rate is high.

The invention discloses a polycarbonyl polyimide organic electrode material as well as a preparation method and application thereof, and belongs to the technical field of lithium ion battery electrode materials. The preparation method comprises the following steps: under an inert condition and mechanical stirring, sequentially adding anhydride and a carbonyl-containing diamine monomer into an organic solvent, then adding isoquinoline, and heating until a reflux reaction is performed for a period of time to obtain a polyimide crude product mixed solution; and discharging the polyimide crude product mixed solution into methanol, ethanol or acetone, carrying out suction filtration to obtain filter residues, washing the filter residues with acetone and N-methyl pyrrolidone, and carrying out vacuum drying on the obtained solid to obtain the polycarbonyl polyimide electrode material. According to the invention, condensation polymerization of 1, 4, 5, 8-naphthalene tetracarboxylic anhydride and electroactive carbonyl-containing diamine is utilized to construct an electroactive polymer with an extended pi conjugated system, and high capacity and excellent cycle stability of an electrode material are realized by increasing the density of active sites in polyimide, so that large-scale production is facilitated, and the preparation method is suitable for industrial production. Therefore, the method has a very high application prospect.

The invention discloses a preparation method of electronic grade propylene glycol monomethyl ether and a product obtained by the preparation method, and belongs to the technical field of preparation of fine chemicals. The method comprises the following steps of: 1) mixing methanol, propylene oxide and a basic ionic liquid catalyst, and carrying out reaction in a micro-channel reactor to obtain a reaction solution; 2) removing light components from the reaction solution to obtain a light component removed reaction solution; and 3) evaporating the light component removed reaction solution obtained in step 2), and performing negative pressure rectification on the obtained steam to obtain the electronic grade propylene glycol monomethyl ether. The preparation method of the electronic grade propylene glycol monomethyl ether provided by the invention are mild in reaction conditions, the purity of the prepared product is high, the yield is high, and the activity and selectivity of the catalyst are high.