A kind of copper-based methanol synthesis catalyst and preparation method thereof
A technology for methanol synthesis and catalyst, applied in chemical instruments and methods, preparation of hydroxyl compounds, preparation of organic compounds, etc., can solve the problems of short service life, poor thermal stability, etc., to improve dispersion and utilization rate, and improve catalytic activity. , to ensure the effect of high activity and thermal stability
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Embodiment 1
[0038] The preparation method of the copper-based methanol synthesis catalyst described in the present embodiment comprises the steps:
[0039] Prepare 2L of aqueous solution containing 126g sodium oxalate; 136g Cu(NO 3 ) 2 ·3H 2 O and 110gZn(NO 3 ) 2 ·6H 2 O was dissolved in 2L of water to form a copper-zinc mixed solution; the above two solutions were added to the reaction kettle in parallel under continuous stirring, and the pH value of the reaction system was controlled to be 7-8. ;
[0040] Formulated to contain 88g of NH 4 HCO 3 Aqueous solution 1L stand-by; 139g Al(NO 3 ) 3 9H 2 Dissolve O in 1L of water; slowly add the ammonium bicarbonate aqueous solution to the aluminum nitrate aqueous solution, and react under stirring, and control the pH value of the reaction system to 7-8, the temperature is 50°C, keep stirring for 30 minutes, and stand still after the addition is completed Aging for 1 hour to obtain slurry B;
[0041] Fully mix slurry A and slurry B, ...
Embodiment 2
[0045] The preparation method of the copper-based methanol synthesis catalyst described in the present embodiment comprises the steps:
[0046] Prepare 2L of aqueous solution containing 127g sodium oxalate; 140g Cu(NO 3 ) 2 ·3H 2 O and 101g Zn(NO 3 ) 2 ·6H 2 O was dissolved in 2L of water to form a copper-zinc mixed solution; the above two solutions were added to the reaction kettle in parallel under continuous stirring, and the pH value of the reaction system was controlled to be 7-8. A;
[0047] Formulated to contain 81g of NH 4 HCO 3 Aqueous solution 1L stand-by; 128g Al(NO 3 ) 3 9H 2 Dissolve O in 1L of water; slowly add the ammonium bicarbonate aqueous solution to the aluminum nitrate aqueous solution, and react under stirring, and control the pH value of the reaction system to 7-8, the temperature is 50°C, keep stirring for 30 minutes, and stand still after the addition is completed Aging for 1 hour to obtain slurry B;
[0048] Fully mix slurry A and slurry B...
Embodiment 3
[0052] The preparation method of the copper-based methanol synthesis catalyst described in the present embodiment comprises the steps:
[0053] Prepare 2L of aqueous solution containing 126g sodium oxalate; 144g Cu(NO 3 ) 2 ·3H 2 O and 89gZn(NO 3 ) 2 ·6H 2 O was dissolved in 2L of water to form a copper-zinc mixed solution; the above two solutions were added to the reaction kettle in parallel under continuous stirring, and the pH value of the reaction system was controlled to be 7-8. ;
[0054] Formulated to contain 72g of NH 4 HCO 3 Aqueous solution 1L stand-by; 113g Al(NO 3 ) 3 9H 2 Dissolve O in 1L of water; slowly add the ammonium bicarbonate aqueous solution to the aluminum nitrate aqueous solution, react under stirring, and control the pH value of the reaction system to 7-8, the temperature is 50°C, continue to stir for 30 minutes, and stand still after the addition is completed Aging for 0.5h to obtain slurry B;
[0055] Fully mix slurry A and slurry B, stir...
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