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Method for increasing butadiene yield

A butadiene and reactor technology, which is applied in the field of selective hydrogenation of highly unsaturated hydrocarbons to increase production of butadiene, can solve problems such as deactivation, easy aggregation of active components and poisoning

Active Publication Date: 2018-11-23
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0014] The active components of conventional noble metal catalysts are prone to agglomeration and poisoning and deactivation during the reaction process, and the dispersion of palladium metal is a problem that many researchers are trying to solve

Method used

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  • Method for increasing butadiene yield
  • Method for increasing butadiene yield
  • Method for increasing butadiene yield

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0056] Embodiment uses the preparation of catalyst 1~6

[0057] Preparation of Catalyst C1:

[0058] Dilute 2L concentration to 100g Al 2 o 3 / L of sodium metaaluminate solution is placed in a stainless steel container with a stirrer and gas can be introduced into the bottom of the tank, the nickel nitrate solution is prepared and placed in a high-position container, a mixed gas of carbon dioxide and air is introduced, and the peristaltic pump is started at the same time Control the flow rate and drop the prepared nickel nitrate solution, the carbon dioxide concentration in the mixed gas is 60v%, and the flow rate is 5Nm 3 / h, the reaction temperature is 40°C, the pH value at the end of the reaction is 9.5, stop feeding carbon dioxide, age for 30 minutes, filter and separate the mother liquor, wash, and dry at 120°C for 5 hours to obtain nickel-containing pseudo-boehmite.

[0059] Mix and knead nickel-containing pseudo-boehmite with nitric acid and water, extrude into strip...

Embodiment 1

[0086] Dilute the alkyne-rich C4 fraction with raffinate C4 and cracked C4, and the weight ratio of the alkyne-rich C4 fraction to (raffinate + cracked C4) is 1:4. The adiabatic reactor adopts a single-stage adiabatic bubbling bed, using catalyst C1, and the catalyst is reduced at 120°C for 6h under a hydrogen atmosphere. The reaction inlet temperature is 50°C, the reaction pressure is 2.0MPa, and the liquid space velocity is 10h -1 , the molar ratio of hydrogen to alkyne is 4.0, Table 2 is the composition of materials before and after the reaction.

[0087] Material composition before and after table 2 reaction

[0088]

Embodiment 2

[0090] The C4 fraction rich in alkynes is diluted with C4 raffinate and C4 cracked, and the weight ratio of the C4 fraction rich in alkynes to (C4 raffinate+C4 cracked) is 1:5. The adiabatic reactor adopts a single-stage adiabatic bubbling bed, using catalyst C2, and the catalyst is reduced at 120°C for 6 hours under a hydrogen atmosphere. The reaction inlet temperature is 45°C, the reaction pressure is 1.5MPa, and the liquid space velocity is 12h -1 , the molar ratio of hydrogen to alkyne is 3.0, Table 3 is the composition of materials before and after the reaction.

[0091] Table 3 Composition of materials before and after reaction

[0092]

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Abstract

The invention discloses a method for increasing butadiene yield. According to the method, carbon-4 cut fraction rich in alkyne after butadiene extraction is utilized as a raw material; under the existence of a catalyst, an adiabatic reactor is utilized, and selective hydrogenation is performed to obtain 1,3-butadiene; utilized hydrogenation operation conditions are that an inlet temperature of thereactor is 20 to 70 DEG C, reaction pressure is 0.8 to 3.0 MPa, and a liquid space velocity is 10 to 30 h<-1>. The catalyst is a palladium-silver-lead series catalyst which is prepared from a nickel-containing aluminum oxide carrier with a specific crystal form, so that dispersity and a utilization rate of active metal can be greatly improved, and hydrogenation performance of the catalyst is improved. The method disclosed by the invention has very obvious good effects on effectively utilizing carbon-4 cut fraction rich in alkyne after butadiene extraction, reducing resource waste and improving economical benefits.

Description

technical field [0001] The invention relates to a method for increasing the production of butadiene, in particular to a method for increasing the production of butadiene by selective hydrogenation of highly unsaturated hydrocarbons in the C4 fraction. Background technique [0002] The cracked C4 fraction usually contains 40% to 60% butadiene by mass in the pyrolysis of hydrocarbons to produce ethylene. Butadiene is an important monomer in the synthetic rubber industry. The extraction of butadiene from the cracked C4 fraction usually adopts solvent extraction methods, such as acetonitrile method, N-methylpyrrolidone method and dimethylformamide method. Due to the high concentration of alkynes in the extracted C4 fraction, and there is no industrial use value at present, it can only be used for combustion treatment. However, because of the danger of explosion of high-concentration alkynes, it is recommended for safety reasons in industrial production. Considering that when se...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C5/05C07C11/167B01J23/89B01J35/10
CPCC07C5/05B01J23/002B01J23/8966C07C2523/89B01J2523/00B01J35/613B01J35/635B01J35/633C07C11/167B01J2523/824B01J2523/18B01J2523/44B01J2523/847B01J2523/22B01J2523/11B01J2523/3706B01J2523/13B01J2523/3712
Inventor 钱颖郑云弟胡晓丽马好文展学成王斌孙利民蒋彩兰黄德华边虎刘敏尹玲玲
Owner PETROCHINA CO LTD
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