Compositions for manufacturing fiber-reinforced, starch-bound articles having a foamed cellular matrix

a technology of foamed cellular matrix and fiber reinforcement, which is applied in the direction of rigid pipes, rigid containers, packaged goods types, etc., can solve the problems of brittleness and fragile of foamed starch-based articles, even those that include quantities of shorter-length fibers, and the inability to simply be demolded without such overdrying, and the convenient starch-based cellular matrix alone is simply not strong enough to withstand internal buildup

Inactive Publication Date: 2006-10-17
EARTHSHELL SPE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0102]FIG. 22 shows a graph illustrating the effect of including varying amounts of pregelatinized starch on yield stress;
[0103]FIG. 23 shows a graph illustrating the effect of including varying mounts of pregelatinized starch on viscosity;
[0104]FIG. 24 shows a graph illustrating the effect of shear rate on viscosity for a predicted mixture containing 50 g starch and 800 g water;
[0105]FIG. 25

Problems solved by technology

Without the conditioning step to reintroduce moisture back into the starch-based matrix, foamed starch-based articles, even those that include quantities of shorter-length fibers, were usually too brittle and fragile for their intended use.
Moreover, such articles could not simply be demolded without such overdrying bec

Method used

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  • Compositions for manufacturing fiber-reinforced, starch-bound articles having a foamed cellular matrix
  • Compositions for manufacturing fiber-reinforced, starch-bound articles having a foamed cellular matrix
  • Compositions for manufacturing fiber-reinforced, starch-bound articles having a foamed cellular matrix

Examples

Experimental program
Comparison scheme
Effect test

examples 1-13

[0352]Drinking cups were formed from moldable mixtures containing different types of inorganic aggregates to determine the effects of the different aggregates. Each of the moldable mixtures had the following basic mix design measured by weight:

[0353]

39.8%Stalok 400 (modified potato starch)9.95%inorganic aggregate49.75%water0.5%magnesium stearate

[0354]Each moldable mixture was prepared in a small Hobart mixer. First, the dry ingredients (including the inorganic aggregate, starch, and magnesium stearate) were completely mixed. Then the water was added slowly while the dry materials were being mixed until a homogeneous mixture was obtained. The mixtures were extracted from the Hobart mixing bowl using a syringe. The weight of the moldable material used to manufacture a cup for each mixture was determined by first weighing the syringe containing the moldable mixture, expelling the contents of the syringe into the molding apparatus, and then weighing the syringe.

[0355]The molding system ...

example 14-18

[0366]Cups were made using collamyl starch with different concentrations of calcium carbonate to determine the effect of using collamyl starch. The same procedures and apparatus set forth in Examples 1-13 were used to make and test the cups of Examples 14-18. A base mixture was first prepared by combining the following components by weight:

[0367]

49.75%collamyl starch andRO40 calcium carbonate49.75%water0.5%magnesium stearate.

[0368]The calcium carbonate was added to the mixture in amounts of 20, 40, 50, and 60% by total weight of the calcium carbonate and starch-based binder. Summarized below are the properties of the articles made using different percentages of calcium carbonate.

[0369]

CalciumDis-CarbonateThermalplace-Ex-AggregateDen-Conduct.Energyment toPeakStiff-am-(weightsity(W / m ·to Fail.Failureloadnessple%)(g / cc)K.)(mJ)(%)(N)(N / m)14 00.170.04363.54.51.915200.170.04374.34.51.716400.240.04673.55.22.217500.270.04573.25.82.518600.320.05372.66.53.5

[0370]The increase in density was ne...

examples 19-26

[0372]Cups were made using different types of admixtures to determine their effects, if any, on the properties of the mixtures. The same procedures and apparatus set forth in Examples 1-13 were used to make and test the cups of the present examples. A base mixture was first prepared by combining the following components by weight:

[0373]

39.8%Stalok 400 (modified potato starch)9.95%RO40 calcium carbonate49.5%water0.5%magnesium stearate.

[0374]Admixtures, include Methocel® 240, Tylose® 15002 and polyvinyl alcohol (PVA), were then combined to the mixture by weight percentage of the total solids in the mixture. Summarized below is a list of the moldable mixtures and the properties resulting from their use.

[0375]

Dis-Ad-Thermalplace-Ex-mixturesDen-Conduct.Energyment toPeakStiff-am-(weightsity(W / m ·to Fail.Failureloadnessple%)(g / cc)K.)(mJ)(%)(N)(N / m)19None0.260.04542.24.52.8PVA201.90.260.04663.15.52.7212.90.270.04852.65.53.3223.40.260.04442.85.02.8Methocel ® 240230.50.190.04563.45.52.3241.00...

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Abstract

Compositions, methods, and systems for manufacturing articles, particularly containers and packaging materials, having a fiber-reinforced, starch-bound cellular matrix. Suitable mixtures used to form the articles are prepared by first preparing a viscous preblended mixture comprising water, a gelatinized starch-based binder, and fibers having an average length greater than about 2 mm. The highly viscous preblended mixture effectively transfers the shearing forces of the mixer to the fibers. The final moldable mixture is then prepared by mixing into the preblended mixture the remaining starch-based binder, water, and other desired admixtures, e.g., mold-releasing agents, inorganic filler rheology-modifying agents, plasticizers, coating materials, and dispersants, in the correct proportions to form an article which has the desired performance criteria. The moldable mixtures are heated between molds at an elevated temperature and pressure to produce form-stable articles having a desired shape and a selectively controlled foamed structural matrix. The articles may be manufactured to have properties substantially similar to articles presently made from conventional materials like paper, paperboard, polystyrene, plastic, or other organic-based materials and have especial utility in the mass-production of containers, particularly food and beverage containers.

Description

[0001]This application is a continuation-in-part of U.S. Ser. No. 08 / 288,664, filed Aug. 9, 1994, now allowed, and a continuation-in-part of U.S. Ser. No. 08 / 288,667, filed Aug. 9, 1994, pending U.S. Ser. No. 08 / 288,667 is a continuation-in-part of U.S. Ser. No. 08 / 218,971, filed Mar. 25, 1994, pending, and a continuation-in-part of U.S. Ser. No. 08 / 109,100, filed Aug. 18, 1993, now abandoned, and a continuation-in-part of U.S. Ser. No. 08 / 095,662, filed Jul. 21, 1993, now U.S. Pat. No. 5,385,764, and a continuation-in-part of U.S. Ser. No. 07 / 982,383, filed Nov. 25, 1992, now abandoned, and a continuation-in-part of U.S. Ser. No. 07 / 929,898, filed Aug. 11, 1992, now abandoned. U.S. Ser. No. 08 / 288,664 is a continuation-in-part of U.S. Ser. No. 07 / 928,898, filed Aug. 11, 1992, now abandoned. For purposes of disclosure of the present invention, each of the foregoing applications is incorporated herein by specific reference. BACKGROUND OF THE INVENTION[0002]1. Field of the Invention[0...

Claims

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Application Information

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IPC IPC(8): C04B14/38B01F3/12B05B11/00B05C1/08B05C3/18B05C5/02B27N3/00B28B1/00B28B1/52B28B3/00B28B3/02B28B3/12B28B3/20B28B3/26B28B7/42B28B11/00B28B11/24B28B13/02B28B13/06B28B23/00B28C7/02B29C33/36B29C39/00B29C39/42B29C43/00B29C43/02B29C43/06B29C43/08B29C43/34B29C43/36B29C43/38B29C44/04B29C45/00B29C49/00B29C51/00B29C51/04B29C51/10B29C53/06B29C53/58B29C55/18B29C67/20B29C67/24B29C70/02B29C70/12B29C70/50B29C71/00B31B17/00B32B5/02B32B5/14B32B5/18B32B13/02B32B27/04B32B27/20B32B37/12B32B37/14B65D5/00B65D43/16B65D65/38B65D65/46C04B7/52C04B14/06C04B16/02C04B20/00C04B22/00C04B22/04C04B24/00C04B24/14C04B24/38C04B26/00C04B26/02C04B26/28C04B28/00C04B28/02C04B32/00C04B38/00C04B40/00C04B40/06C04B41/45C04B41/61C08J9/00C08J9/12C08L1/28C08L3/00C08L3/02C08L5/02C08L5/12C08L5/14C08L89/06C08L97/02E05D1/02
CPCB05C1/0826B05C1/0834B05C3/18B05C5/0245B27N3/002B27N3/007B28B1/00B28B1/52B28B3/00B28B3/02B28B3/126B28B3/20B28B3/2645B28B7/42B28B11/00B28B11/003B28B11/008B28B11/24B28B11/245B28B13/021B28B13/06B28B23/00B28B23/0081B28B23/0087B28C7/02B29C33/10B29C33/20B29C33/36B29C39/003B29C39/42B29C43/00B29C43/003B29C43/02B29C43/06B29C43/08B29C43/34B29C43/36B29C43/38B29C44/0407B29C45/0013B29C49/0005B29C51/002B29C51/04B29C51/10B29C53/063B29C53/58B29C55/18B29C67/202B29C67/24B29C67/242B29C70/025B29C70/12B29C70/50B29C71/0009B29C2043/3433B29C2043/3615B29C2043/3621B29C2043/3623B29C2043/3689B29C2049/4608B29C2795/007B29K2003/00B29K2005/00B29K2089/00B29K2093/00B29K2105/12B29K2105/16B29L2024/00B29L2031/608B29L2031/712B29L2031/7132B31D1/005B32B5/02B32B5/14B32B5/18B32B13/02B32B27/04B32B27/20B32B37/12B32B37/144B65D5/00B65D11/02B65D43/162B65D65/38B65D65/466B65D2301/20B65D2565/385C04B7/527C04B26/02C04B26/026C04B26/28C04B28/00C04B40/00C04B40/006C04B40/0616C04B41/45C04B41/61C08J9/0085C08J9/12C08J2303/00C08L1/28C08L1/286C08L3/00C08L3/02C08L5/02C08L5/12C08L5/14C08L89/06C08L97/02E05D1/02E05Y2900/602B29C44/3402B31B50/32B31B2105/0022Y02W90/10Y02W30/91B01F23/511B29C49/6605C08L2666/02C08L2666/04C04B14/06C04B14/064C04B14/10C04B14/106C04B14/18C04B14/202C04B14/22C04B14/24C04B14/28C04B14/303C04B14/386C04B14/42C04B14/46C04B22/124C04B24/00C04B24/008C04B24/02C04B24/06C04B24/14C04B24/34C04B2103/408C04B18/24C04B18/248C04B18/26C04B24/085C04B24/383C04B20/0048C04B16/02C04B22/002C04B26/00
Inventor ANDERSEN, PER JUSTHODSON, SIMON K.
Owner EARTHSHELL SPE
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