The invention provides a solvent-based fluorocarbon resin, belonging to the synthesis process of the fluorocarbon resin. The fluorocarbon resin comprises the following components by mass percent: 38.56% of a chlorotrifluoroethylene monomer, 10.44% of methyl isobutyl ketone, 24.38% of dimethylbenzene, 0.832% of azodiisobutyronitrile, 1.024% of undecylenic acid, 2.894% of allyl alcohol and 21.87% of vinyl acetate, wherein, CTFE is the abbreviation for the chlorotrifluoroethylene monomer, and MIBK is the abbreviation for methyl isobutyl ketone. The synthesis process comprises the following steps: preparing, adding raw materials to a polymerization kettle, vacuumizing the polymerization kettle, adding the trifluorochloroethylene chlorotrifluoroethylene monomer raw material to the polymerization kettle, stirring and heating, and finally discharging the fluorocarbon resin. The fluorocarbon resin has durability, weatherability and chemical resistance, and shows special surface properties such as remarkable non-stick property, low surface tension, low friction property, water repellency, oil repellency and the like; and various coatings prepared by the fluorocarbon resin have outstanding high adhesive force and outstanding environmental aging resistance.