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Novel environmental-aging-resistant PP material and preparation method thereof

An environment-resistant and new technology, applied in the field of new environment-resistant aging PP materials and its preparation, can solve the problems of loss of mechanical properties, frosting, increase of TVOC content of materials, etc., reduce precipitation and emission problems, simple production process, easy The effect of industrialization

Inactive Publication Date: 2016-07-20
SHANGHAI PRET COMPOSITES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the existence of a large number of unstable tertiary carbon atoms on the PP main chain, its hydrogen atoms are easily taken away by oxygen under the conditions of light and heat, which triggers the chain degradation reaction of PP materials, resulting in the gradual loss of its mechanical properties.
In general, polypropylene materials with black masterbatch need to add a large amount of antioxidants and light stabilizers to meet the requirements of use, but common low-molecular-weight light stabilizers and ordinary antioxidants 1010, 168, DSTP synergistic systems, in the Under high temperature or ultraviolet light irradiation, the two additives are easy to precipitate on the surface, causing the problem of "frost"
Moreover, the above-mentioned system will also lead to an increase in the TVOC content of the material to a certain extent, which will have adverse effects on the human body and limit its scope of use to a certain extent.

Method used

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  • Novel environmental-aging-resistant PP material and preparation method thereof
  • Novel environmental-aging-resistant PP material and preparation method thereof
  • Novel environmental-aging-resistant PP material and preparation method thereof

Examples

Experimental program
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Embodiment Construction

[0021] In the PP material formulations of Examples and Comparative Examples, PP is M2600R produced by Shanghai Petrochemical Company. The lignin used is wood pulp lignin without any modification treatment and is self-made. PP-g-MAH is self-made, and the grafting rate is 1%. The light stabilizers are 944 and 770 produced by Ciba Company. The main antioxidant is selected from Irganox1010 produced by Ciba Company. The secondary antioxidant is selected from Irganos168 produced by Ciba Company.

[0022] Dry mix various raw materials and additives in a high-speed mixer for 5 to 15 minutes; put the uniformly mixed raw materials into a twin-screw extruder, melt and extrude, cool and granulate to obtain PP materials, and the process is a zone 190~ 200°C, 200-210°C in the second zone, 195-200°C in the third zone, 205-215°C in the fourth zone, the residence time of the whole extrusion process is 1-2 minutes, and the pressure is 12-18MPa.

[0023] Performance evaluation methods and i...

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Abstract

The invention discloses a novel environmental-aging-resistant PP material and a preparation method thereof. The novel environmental-aging-resistant PP material comprises the following raw materials by the weight percentage: 90-97% of PP, 1-5% of xylogen, 1-3% of PP-g-MAH, 0-0.5% of a light stabilizer, 0-0.5% of an antioxidant, and 0-2% of other additives. The novel environmental-aging-resistant PP material has the advantages: 1, the xylogen can be used for partially or completely replacing traditional additives, and can effectively solves PP surface blooming and emission problems; and 2, the prepared PP material is simple in production process, low in cost and easy to industrialize.

Description

technical field [0001] The invention relates to a novel environmental aging-resistant PP material and a preparation method thereof, belonging to the field of polymer modification and processing. Background technique [0002] Polypropylene raw materials are rich in sources and low in price. Its excellent mechanical strength and processability are widely used in various fields such as automobiles, electrical appliances, daily necessities and furniture packaging. Due to the presence of a large number of unstable tertiary carbon atoms on the PP main chain, its hydrogen atoms are easily taken away by oxygen under light and heat conditions, triggering a chain degradation reaction of the PP material, resulting in a gradual loss of its mechanical properties. In general, polypropylene materials with black masterbatch need to add a large amount of antioxidants and light stabilizers to meet the requirements of use, but common low-molecular-weight light stabilizers and ordinary antioxid...

Claims

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Application Information

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IPC IPC(8): C08L23/10C08L97/00C08L51/06C08K13/02B29C47/92B29C48/92
CPCC08L23/10B29C48/92B29C2948/92704C08L2201/08C08L2205/025C08L2205/03C08L2205/035C08L2310/00C08L97/005C08L51/06C08K13/02
Inventor 柒祥芝张鹰张祥福周文
Owner SHANGHAI PRET COMPOSITES
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