The invention relates to a bio-based
thermoplastic long-chain
polyamide elastomer and a preparation method and application thereof, and belongs to the technical field of
vegetable oil functional
polymer materials. Aiming at the defects of high
hardness, complex preparation process and low bio-based content of the existing
polyamide elastomer, the
elastomer is prepared by taking long-chain
binary acid containing a bio-based S28s diacid
monomer and a S28so diacid
monomer as raw materials, matching with short-chain
diamine,
diamine with side groups, polyether amine and a catalyst and carrying out melt polycondensation through a one-
step method; wherein the S28s and the S28so are synthesized from 10-
undecylenic acid and a corresponding
sulfur-containing
monomer through a
sulfur-
alkene click reaction, and the S28so is preferably matched with polyether amine with the number-average molecular weight of 400-900. The bio-based content of the elastomer is larger than or equal to 60%, the
shore hardness is 25-40 D, the highest elastic
recovery rate can reach 84.3%, pre-salification is not needed in the process, and the elastomer can be used for
spinning preparation of elastic fibers, automobile engine sealing rings or high-end running shoe sole foaming materials and has the advantages of greenness, high performance and industrialization value.