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154 results about "Undecylenic acid" patented technology

Undecylenic acid is an organic compound with the formula CH₂=CH(CH₂)₈CO₂H. It is an unsaturated fatty acid. It is a colorless oil. Undecylenic acid is mainly used for the production of Nylon-11 and in the treatment of fungal infections of the skin, but it is also a precursor in the manufacture of many pharmaceuticals, personal hygiene products, cosmetics, and perfumes. Salts and esters of undecylenic acid are known as undecylenates.

Water-based fracturing fluid thickening agent and synthetic method thereof

The invention belongs to the field of chemical engineering, and particularly relates to a water-based fracturing fluid thickening agent and a synthetic method thereof. The thickening agent comprises substances in parts by weight as follows: acrylamide, methacrylamide, undecylenic acid, 2-acrylamide-2-methylpropane sulfonate, methacryloyloxyethyl trimethyl ammonium chloride, dodecafluoroheptyl methacrylate, vinyl pyrrolidone, modified corn starch, an initiator and water. The synthetic method of the thickening agent comprises steps as follows: various co-monomers and modified starch are prepared in deionized water in proportion; the PH value and the temperature of the solution are adjusted; high-purity nitrogen is fed for oxygen removal; the compound initiator is added to initiate a reaction. The thickening agent is a multifunctional high-molecular polymer which is easily soluble, free of pollution and damage, good in sand carrying property and particularly good in temperature resistance and anti-shearing sand carrying property. The thickening agent has main characteristics of wide use temperature range as well as high temperature resistance and shearing resistance, has characteristics that the thickening agent is high in sand carrying property, free of residues, causes no damage to reservoir and the like, and can be used as an excellent substitute for guanidine gum.
Owner:YANTAI RUNXING ENVIRONMENTAL PROTECTION TECH DEV

Normal temperature cured type tetrafluoroethylene fluorocarbon coating resin and preparation thereof

ActiveCN101323653ATypical soft smellGood flexibilityCoatingsCarboxylic acidCarbon atom
The invention relates to a fluorocarbon coating resin, in particular to a room temperature cured tetrafluoroethylene series fluorocarbon coating resin which is synthesized by solution polymerization with tetrafluoroethylene monomer and vinyl ester of tertiary carboxylic acid as the main comonomers; the matching of raw materials is as follows: 25 percent to 40 percent of tetrafluoroethylene, 25 percent to 35 percent of vinyl ester of tertiary carboxylic acid, 5 percent to 8 percent of hydroxyalkyl olefine aether, 25 percent to 35 percent of organic solvent and 0.5 percent to 1 percent of evocating agent; the R<1> and R<2> of the vinyl ester of tertiary carboxylic acid are alkyl groups and the total number of carbon atoms is 5 to 9. The preparation method of the room temperature cured tetrafluoroethylene fluorocarbon coating resin comprises the steps of: adding the vinyl ester of tertiary carboxylic acid, hydroxyalkyl olefine aether, undecylenic acid and organic solvent into a dissolving tank, opening the valve of tetrafluoroethylene monomer tank when the temperature reduces to minus 20 to minus 5 DEG C, adding tetrafluoroethylene monomer and raising the temperature of a polymerizing pot by a control system for copolymerization. Due to the alternating copolymerization of the tetrafluoroethylene and the vinyl ester of tertiary carboxylic acid, the room temperature cured tetrafluoroethylene series fluorocarbon coating resin of the invention greatly improves weather resisting property of coatings and prolongs the service life of coatings.
Owner:JINAN HUALIN CHEM

Process for preparing undecylenic acid by scission of castor oil

InactiveCN101289383AAvoid physical and mental harmConstant responseOrganic compound preparationCarbonyl compound preparation by oxidationBenzoyl peroxideWater vapor
The invention relates to an engineering plastic process for producing nylon-11 by caster oil and particularly relates to a method for cracking the caster oil to produce undecylenic acid, which belongs to the process flow and solves the existing problems of lead pollution and easy coking in the technology that the caster oil is cracked by the technique of cauldron-typed lead melter. The method is as follows: the caster oil and a catalyst of benzoyl peroxide solution are mixed and preheated to 150-200 DEG C, the quality proportion of which is 1000:3-7:1100-1300 with over heated water vapor of 500-600 DEG C, which enters into a loading tube from the mouth of the loading tube, enters into the top of the cracking stove body from the outlet of the loading tube, and enters into a reacting space along a screw panel; the cracking stove body at the upper part of a tower-typed cracking stove is heated to 500-600 DEG C by an electric heater to crack to produce undecylenic acid and heptaldehyde products. The engineering plastic process for producing nylon-11 by caster oil has the advantages of permanent reaction, strongly continuous operability, ,which is suitable for the production of industrialized settings and can improve the operating environment, can overcome the hurt to body and spirit of the operator by the lead pollution, and has low possibilities of coking, high yield and simple setting producing technologies.
Owner:山西宏远科技股份有限公司

Preparation and application for silicon quantum dots

InactiveCN103232845ASave raw materialsRealization of fluorescent labeling of silicon quantum dotsNanoopticsBiological testingEtchingFluorescence
The invention discloses preparation for silicon quantum dots, and a fluorescence labelling method for dopamine molecules by virtue of the silicon quantum dots, which belong to the field of nanotechnology. The method comprises the following steps of: preparing porous silicon at first, obtaining a silicon quantum dot precursor via chemical etching, and obtaining the silicon quantum dots after ultrasonic treatment, wherein the silicon quantum dot precursor can be reacted with hydrofluoric acid to generate surface Si-H, and then sequentially reacted with undecylenic acid, N-hydroxysuccinimide and dopamine, and finally ultrasonically treated to obtain the dopamine molecules which are fluorescence-labelled by the silicon quantum dots. Compared with the prior art, in the method disclosed by the invention, silicon slices are used as raw materials, and a chemical etching method is adopted, so that fluorescence labelling for the dopamine molecules by the silicon quantum dots can be realized at a low temperature and under the normal pressure; and because a chemical modification reaction is performed on the surface of the silicon quantum dot precursor, separation between the product and reactants can be realized via solvent soaking and washing, thus simplifying the separation operation. The method can also be used for fluorescence labelling for other biomolecules containing primary amine group by the silicon quantum dots.
Owner:ANHUI UNIVERSITY OF TECHNOLOGY

External medicament for treating tinea manuum and tinea pedis

The invention discloses an external medicament for treating tinea manuum and tinea pedis. The external medicament consists of an effervescent tablet A and a gel B, and the main ingredients comprise clove basil oil, cinnamon oil, litsea cubeba oil, eucalyptus oil, a light yellow sophora root extract, salicylic acid, undecylenic acid and the like; and the external medicament has the functions of clearing away heat and toxic materials, killing bacteria, diminishing inflammation, drying dampness and killing insects. The medicament provided by the invention is different from a treatment scheme in the past for treating tinea manuum and tinea pedis only, firstly, the effervescent tablet A is used to quickly kill pathogenic bacteria on the surface of skin to keep the skin clean and environment, and achieve an effect of no recurrence by forcibly killing the bacteria. An epidermal tissue structure of the surface layer infected by diseases, so that a thickened and keratinized skin structure becomes loose to form a channel conducive to smooth penetration of the medicament; on the premise of dredging the channel of medicament penetration, the gel B is used to quickly and thoroughly remove and kill the pathogenic bacteria in the skin; and the combination of the two agents is multi-layered and three-dimensional, achieves both prevention and treatment of symptoms and root causes, and the treatment method is unique and the curative effect is reliable.
Owner:安徽世龙生物医药科技有限公司

Method for preparing 11-bromo-undecanoic acid by direct freezing crystallization and device therefor

The invention discloses a method for preparing 11-bromo-undecanoic acid by direct freezing crystallization and a device for preparing 11-bromo-undecanoic acid, and relates to a method for preparing the 11-bromo-undecanoic acid. The preparation device comprises a burdening kettle, an addition tower, a crystallization kettle and a filter press, wherein the burdening kettle is connected with the addition tower; the addition tower is connected with the crystallization kettle; the crystallization kettle is connected with the filter press; and the filter press is connected with the top part of the burdening kettle. During work, the preparation method comprises the steps of: mixing undecylenic acid and toluene in a mass ratio of 1:(3-4) at a temperature of -5-0 DEG C in the burdening kettle; allowing the mixed liquid with hydrogen bromide in a mole ratio of 1:1.05 at a temperature of 0-30 DEGC in the addition tower to react so as to generate an addition liquid; putting the addition liquid in the crystallization kettle, carrying out freezing crystallization at a temperature of -4 DEG C to -16 DEG C, a revolving speed of 8 round/min and a vacuum degree of -0.02MPa to -0.03MPa; and filtering crystal in the filter press. The device disclosed by the invention has the advantages of a simple structure, strong continuity and operability and is suitable for industrial production. The preparation method has the advantages of a short process flow, constant reaction, high product purity and good economic benefits.
Owner:山西宏远科技股份有限公司

Undecane to pentadecane dicarboxylic acid di(2,2,6,6-tetramethylpiperidinyl)ester and use thereof

The invention relates to the synthesis and the usage of the novel hindered amine light stabilizer undecylenic to pentadecanedioic acid (2, 2, 6, 6-tetramethyl piperidino) diester. The invention utilizes undecylenic acid, dodecanedioic acid, tridecanedioic acid, tetradecanoic acid and pentadecanedioic acid produced through microorganism fermentation paraffinic oil as the raw material, the undecylenic to pentadecanedioic acid diesters are synthesized firstly, then the ester exchange reaction is performed to produce the finished product, secondly, the catalytic agent adopts sodium methoxide, sodium ethoxide or sodium amide which has higher activity, is easy to prepare and segregate, and is suitable for the use in industry, the related reaction condition is bland, the technology is simple, and the invention is easy to realize industrialization. The invention has very good light protection performance, and the addition into lubricating oil hydrogenised base oil can obviously improve the light stability quality. The invention can replace the prior Tinuvin770 sebacic acid (2, 2, 6, 6-tetramethyl piperidino) diester product. The structure formula of the invention is shown in the following (I), wherein, n is equal to 11 or 12 or 13 or 14 or 15.
Owner:XINJIANG TECHN INST OF PHYSICS & CHEM CHINESE ACAD OF SCI
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