Polyphenylene oxide composition used for photovoltaic junction box

The technology of polyphenylene ether and junction box is applied in the field of polyphenylene ether composition, which can solve the problems of poor fluidity, difficult processing and molding, and can not meet the field of solar photovoltaic, and achieves the effect of improving long-term thermal oxygen aging.

Active Publication Date: 2012-04-04
广东瑞能新材料有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polyphenylene ether (PPO) has excellent mechanical properties and electrical properties, but its high melt viscosity and poor fluidity make it difficult to process and shape, so it is generally used in various modified varieties, such as PPO and HIPS, PP Polyphenylene ether alloys such as polyphenylene ether or PA have been widely used, and the performance and use value of the blended and modified varieties of polyphenylene ether far exceed their own performance and use value.
[0003] At present, common MPPO materials such as flame retardant and reinforcement cannot meet the application requirements in the field of solar photovoltaics, that is, water resistance, high flame retardancy, long-term thermal oxygen aging resistance, UV stability, and high electrical properties such as CTI and GWIT.

Method used

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  • Polyphenylene oxide composition used for photovoltaic junction box
  • Polyphenylene oxide composition used for photovoltaic junction box

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The components of the composition of this embodiment are: 75 kg of polyphenylene ether, 25 kg of polystyrene resin, 3 kg of SEBS, 10 kg of TPP, 1 kg of hydrotalcite, 10760.2 kg of antioxidants, and 1680.2 kg of phosphite auxiliary antioxidants. Kg, UV absorber UVA-10.5 kg, light stabilizer HALS-10.5 kg, PE wax 0.3 kg, carbon black 0.5 kg.

[0027] Among them, the viscosity of polyphenylene ether resin is IV0.52dl / g, produced by Asahi Kasei Corporation; the MFR of polystyrene resin (HIPS) is 3g / 10min, produced by BASF; the hydrotalcite is produced by Kyowa Chemical, and the antioxidant is 1076. Produced by Great Lakes Company, phosphite auxiliary antioxidant 168 is produced by Ciba Company, UV absorber UVA-1 is produced by BASF Company, light stabilizer HALS-1 is produced by Ciba Company, PE wax is produced by BASF Company, carbon black Produced for Cabot Corporation.

[0028] The above components are mixed uniformly, and then extruded and pelletized with a twin-screw extrud...

Embodiment 2

[0030] The components of the composition in this embodiment are: 55 kg of polyphenylene ether, 45 kg of polystyrene resin, 2 kg of SEPS, 8 kg of TPP, 1.5 kg of hydrotalcite, 10760.2 kg of antioxidants, and phosphite auxiliary antioxidant 6260.2 Kg, ultraviolet absorber UVA-10.5 kg, light stabilizer HALS-10.3 kg, PP wax 0.2 kg, carbon black 0.3 kg.

[0031] Among them, the viscosity of the polyphenylene ether resin is IV0.40dl / g, produced by Asahi Kasei, Japan; the MFR of polystyrene resin is 5g / 10min, produced by BASF.

[0032] The above components are mixed uniformly, and then extruded and granulated with a twin-screw extruder, and the processing temperature is: 260°C (plasticizing section).

Embodiment 3

[0034] The components of the composition of this embodiment are: 95 kg of polyphenylene ether, 5 kg of polystyrene resin, 5 kg of SEBS-MAH (grafting rate 3%), 12 kg of BDP, 0.5 kg of MgO, and 3300.4 kg of antioxidants. Phosphite auxiliary antioxidant 1680.5 kg, ultraviolet absorber UVA-40.3 kg, light stabilizer HALS-10.5 kg, PE wax 0.3 kg, carbon black 0.6 kg.

[0035] Among them, the viscosity of polyphenylene ether resin is IV0.42, produced by Sabic Company of Saudi Arabia; the MFR of polystyrene resin is 8g / 10min, produced by Chi Mei Company.

[0036] The above components are mixed uniformly, and then extruded and pelletized with a twin-screw extruder, and the processing temperature is: 280°C (plasticizing section).

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Abstract

The invention provides a polyphenylene oxide composition used for a photovoltaic junction box. The composition comprises the following components by weight: 55-95 parts of polyphenylene oxide, 45-5 parts of styrene resin, 2-10 parts of a flexibilizer, 5-20 parts of a phosphate fire retardant, 0.5-2.5 parts of an acid absorbent, 0.2-0.6 part of a hindered phenol main antioxidant, 0.2-0.6 part of a phosphite auxiliary antioxidant, 0.3-1.5 parts of an ultraviolet absorbent, 0.3-1.5 parts of a hindered amine light stabilizer, 0.1-0.5 part of a lubricating agent, and 0.1-1.0 part of toner. With the characteristics of good flame resistance, thermo-oxidative aging resistance, UV (ultraviolet) resistance, excellent electrical performances, the composition of the invention has flame retardancy up to grade UL945VA, RTI (relative temperature index)=110DEG C, CTI (comparative tracking index) PLC ( programmable logic controller)=2, and GWIT (glow wire ignition temperature)=750DEG C, thus satisfying the requirements in ROHS (restriction of hazardous substances) standard. Thus, the composition provided in the invention can be used for electronic and electrical component production of solar photovoltaic junction boxes, etc.

Description

Technical field [0001] The invention relates to a polyphenylene ether composition and its use, belonging to the field of polymer alloys. Background technique [0002] Polyphenylene ether (PPO) has excellent mechanical and electrical properties, but its melt viscosity is high and its fluidity is poor, making it difficult to process and shape. Therefore, various modified varieties are generally used, such as PPO, HIPS, and PP Or PA and other polyphenylene ether alloys have been widely used, and the performance and use value of the blended modified varieties of polyphenylene ether far exceed their own performance and use value. [0003] At present, ordinary flame retardant and reinforced MPPO materials cannot meet the application requirements of the solar photovoltaic field, that is, water resistance, high flame retardancy, long-term thermal and oxygen aging, UV stability, and high electrical properties such as CTI, GWIT and other properties. It is necessary to further improve the pe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L71/12C08L25/06C08K13/02C08K5/521C08K5/13C08K5/524C08K5/17
Inventor 吴全德徐洋吴普逵
Owner 广东瑞能新材料有限公司
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