37results about "Hydrogen production carbon capture" patented technology

The invention provides a method for generating power with a gas turbine which utilizes pressure swing reforming under conditions that facilitate CO2 capture. First a synthesis gas stream at a first pressure is produced in a pressure swing reformer. Next the synthesis gas stream is subjected to a high temperature water gas shift process to produce a CO2 containing hydrogen enriched stream from which hydrogen and CO2 each are separated. The separated hydrogen in turn is combusted with air to produce a gas turbine and the separated CO2 is easily sequestered.

The integrated processes of the dry reforming or partial oxidation upstream of the carbon nanotube-producing reactor are described allowing the carbon monoxide to be produced on an as-needed basis, negating the need to transport carbon monoxide to the production site or store large quantities of carbon monoxide on-site. The apparatuses allowing to carry out such integrated processes are also provided. Carbon dioxide emissions may be eliminated from the carbon nanotube production process. This may be achieved by recycling the carbon dioxide byproduct and mixing it with the feed to the partial oxidation process.

This invention relates to a process and apparatus for the production of pure hydrogen by steam reforming. The process integrates the steam reforming and shift reaction to produce pure hydrogen with minimal production of CO and virtually no CO in the hydrogen stream, provides for CO2 capture for sequestration, employs a steam reforming membrane reactor, and is powered by heat from the convection section of a heater.

A process for the production of a synthesis gas containing hydrogen and carbon monoxide utilizes ground coke having a predetermined ash content in combination with a refinery residual hydrocarbon oil feedstream for gasification in the combustion chamber of a tubular wall membrane partial oxidation gasification reactor in the presence of a predetermined amount of oxygen; the coke and residual oil can be mixed to form a single feedstream or introduced into the reactor as separate feeds. Optionally, the product synthesis gas is introduced as the feedstream to a water-gas shift reactor to enhance the hydrogen content of the final product stream.

Method for the productioii of ammorsia, and optionally urea, from a flue gas effluent from an oxygen-fired, process, wherein the production of ammonia and optionally urea includes a net power production. Also provided is a method to effect cooling in an oxygen-fired process with air separation unit exit gases utilizing either closed or open cooling loop cycles.

A process and system for producing a synthetic hydrocarbon having a desired H / C ratio is disclosed. Organic material is biochemically digested in a two stage biodigester for separately producing a hydrogen containing biogas substantially free of methane in a first stage and a methane containing biogas in a second stage. The methane containing biogas is reformed in a first reformer to generate hydrogen gas and carbon monoxide gas, which are then combined in a mixer with the hydrogen containing biogas into a syngas in amounts to achieve in the syngas an overall H / C ratio substantially equal to the desired H / C ratio. The syngas is reacted with a catalyst in a second reformer, a Fischer-Tropsch (FT) reactor, to produce the hydrocarbon. Using a two stage biodigester allows for the generation of separate hydrogen and methane streams, a more economical generation of the FT syngas and reduced fouling of the FT catalyst.

An apparatus for producing hydrogen having compressor motor speed control. The apparatus includes a hydrogen generator for producing a product comprising hydrogen and a compression unit for compressing the product. The hydrogen generator can include a fuel processor having an oxidizer and a reformer. The compression unit has an induction motor and means for regulating the speed of the motor. The means for regulating the speed of the motor can include a variable frequency drive or soft start device having a plurality of switches and an adjustable ramp timer. A downstream unit including one or more of a purification unit, a second compression unit, and a storage unit is disposed downstream of the compression unit. A method for producing hydrogen is provided that includes generating a product comprising hydrogen in a hydrogen generator, compressing the product in a compression unit having an induction motor and regulating the speed of the motor in response to transient operations of the hydrogen generator.

In at least one embodiment of the present invention, a method of heating a FCC unit having a regenerator and a reactor for over CO2 reduction is provided. The method comprises compressing syngas to define compressed syngas. CO2 is separated from the compressed syngas to provide a first stream of gas comprising CO2. The first stream of gas is expanded with a second stream of gas comprising O2 to define a feed gas. The feed gas and an injected hydrocarbon feed are introduced to the regenerator having spent catalyst from the reactor. The regenerator is at gasification conditions to burn the injected hydrocarbon feed and coke from the spent catalyst producing the syngas and heat for operating the reactor at reaction temperatures.

A process, preferably continuous, for producing hydrogen gas comprising contacting in the liquid phase at least one oxidizable organic substance in the presence of a mixture comprising at least one conductive catalyst and an aqueous alkaline carbonate electrolyte, wherein at least one bicarbonate composition produced by reaction of the electrolyte is regenerated and the at least one oxidizable organic substance comprises a oxygenated hydrocarbon, for example methanol and / or dimethyl ether. In a preferred embodiment the alkaline electrolyte is regenerated using steam. Various advantageous reaction schemes are described, utilizing, e.g., co-current and countercurrent stream flow and alternative tower sequence arrangements.

Methods and apparatuses for separating CO2 and sulfur-containing compounds from a synthesis gas obtained from gasification of a carbonaceous feedstock. The primary separating steps are performed using a sour pressure swing adsorption (SPSA) system, followed by an acid gas enrichment system and a sulfur removal unit. The SPSA system includes multiple pressure equalization steps and a rinse step using a rinse gas that is supplied from a source other than directly from one of the adsorber beds of the SPSA system.

Provided is a hydrogen production apparatus enabling reduction of energy needed for separation and collection of CO2 in the hydrogen production. The hydrogen production apparatus includes a reformer, a heating device heating the reformer, a transformer, a hydrogen separation device separating and taking out hydrogen from transformed gas, a CO2 separation device separating and taking out CO2 from off-gas from which hydrogen was separated by the hydrogen separation device, a heat collecting device collecting heat of the reformed gas, heat of the transformed gas, and waste heat from the heating device, and a heat medium supply device supplying the heat medium having absorbed heat collected by the heat collecting device to the CO2 separation device. The absorption liquid having absorbed CO2 in off-gas is heated by the heat medium heated with collected heat, thereby releasing CO2.

A method and apparatus for the oxy-combustion of fuel in an internal combustion engine (ICE) used to power a vehicle converts the free energy available onboard the vehicle in the form of waste heat from the engine exhaust gas stream and coolant system into electrical and / or mechanical energy which energy is used to separate oxygen from air to eliminate or significantly reduce the volume of nitrogen entering the ICE's combustion chamber, and thereby reduce NOx pollutants released into the atmosphere and increase the concentration of CO2 in the engine exhaust stream for capture using an integrated system to compress and increase the density of the captured CO2 for temporary on-board storage until it is discharged at a recovery station, e.g., during vehicle refueling.

The present invention relates to a hydrogen separation membrane which coats granular ceramic onto the surface of a porous metal support and which coats a hydrogen permeation metal thereon so as to inhibit diffusion between the support and a hydrogen separation layer, and to a method for manufacturing same. As a result, the metal support can be modularized with ease, the hydrogen permeation layer can be made thinner to increase the amount of hydrogen permeation, the use of a separation material can be minimized, and the hydrogen separation membrane can have higher competitiveness.

A method and system for capturing and isolating carbon dioxide and hydrogen gases from a high temperature synthesis gas stream containing a substantial amount of CO and sulfur compounds for use as a “clean” supplemental fuel, comprising the steps of reducing the temperature of the high temperature synthesis gas stream, removing substantially all of the sulfur compounds present in the synthesis gas, converting a first portion of CO to carbon dioxide in a first high temperature water-gas shift reaction, converting a second portion of CO to carbon dioxide using a second low temperature water-gas shift reaction, converting a third portion of CO to carbon dioxide using a third low temperature water-gas shift reaction and then separating out substantially all hydrogen present in the treated synthesis gas stream.

A method and a system for treating waste gases (4) from plants (32, 33) for pig iron production, wherein a first sub-stream (51) of the waste gas is subjected to an at least partial conversion of CO into CO2 after the addition of water and / or water vapor (10) and the waste gas (4) is then subjected to CO2 capture. To be able to set a variable H2 / CO ratio in the waste gas, a further sub-stream (52) of the waste gas is not subjected to a conversion of CO into CO2, but is subjected to CO2 capture separately from the first sub-stream (51).

A novel system and method for storing hydrogen in a salt cavern and supplying therefrom is provided. Hydrogen product withdrawn from a hydrogen pipeline may be chilled prior to being introduced into a cavern in order to cool at least a portion of the walls of the salt cavern so that one or more layers of the localized portion of the walls attains a stabilized state whereby contaminant release from the walls is suppressed. The present invention anticipates and strategically plans for contaminant intrusion form a salt cavern in order to reduce the degree of contaminant intrusion from a salt cavern while also allowing the stored hydrogen to have more absorption capacity for water vapor by virtue of entering the salt cavern in a sufficiently drier state. Alternatively, or in addition thereto, a crude hydrogen stream may be withdrawn from the cavern and chilled prior to introducing to the hydrogen pipeline.

A hydrogen generation method including steps as follows: adding a nitrogen-substituted derivative of an alkyldithiolate ruthenium complex as a biomimetic hydrogenase photocatalyst into a solution, adding an organic acid into the solution, adding a P-ligand into the solution, adding an electron donor into the solution, and irradiating the solution with light in order to generate hydrogen.