The invention relates to a preparing method of catalysts, and particularly relates to a preparing method of cobalt catalysts in [Formula 1], as well as a method for converting carbon dioxides to forming gases by using the method. In [Formula 1] (a) Co/(d)Z, [in Formula 1, Z denotes a spinel carrier formed by A, B, and O; A denotes more than one substance selected from the group formed by Mg, Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd, and Sn; B denotes more than one substance selected from the group formed by A1, Ga, In, Ti, V, Cr, Mn, Fe, Ni, and Co; a denotes the weight of Co, D denotes the weight of spinel carrier Z; with respect to the d accounting for 100 by weight, a accounts for 1-100 by weight.] Compared with the catalysts in the prior art, the activity degree of hydrocarbon and carbon dioxide continuously maintain in the same conversion speed to maintain higher activity and stability.