One aspect of the invention relates to a new dual-layered construction that provides advantageous oxygen barrier properties. Another aspect of the invention is a multilayer film that has advantageous oxygen and/or moisture barrier properties. The film may be fully-organic. The film may also be primarily water-based. At least some embodiments of the film can be produced using wide-web, roll-to-roll processing. Specific example applications for uses of the film include dried food, pharmaceuticals, liquids, lidstock, cheese, meat, health & beauty, and coffee packaging, among many others. Another aspect of the invention is a water-based, fast curing coating composition that provides a high barrier against oxygen and moisture permeation. In one embodiment, the coating comprises special PVDC copolymer compositions with good oxygen barrier (OTR<1 CC/M<2 >day) and high moisture barrier (MVTR<0.5 G/M<2 >day). As one example, the coating may be used to produce a flexible, high clarity, barrier film for packaging.