The invention relates to preparation of a
lignin-based monatomic hard carbon material, the hard carbon material and a secondary battery, and belongs to the related technical field of secondary batteries.
Lignin is dispersed in water, alkali liquor is added, then a
mixed solution is added, and the
mixed solution is a
mixed solution of
metal salt and a pore forming agent; then carrying out water bath reaction and aging, centrifuging, and discarding supernatant to obtain an intermediate; dispersing the intermediate in water, adding a
metal atom anchoring agent, uniformly stirring, and freeze-
drying; the mixed material is pre-carbonized in a
nitrogen atmosphere,
metal atoms are anchored, and pre-carbonized
powder is obtained; the pre-carbonized
powder is subjected to acid
pickling to remove metal particles; and carbonizing the acid-washed
powder to obtain the monatomic hard carbon material. According to the invention, addition of metal atoms is anchored by
doping non-metallic elements, so that excessive removal of the metal atoms in the
pickling process is prevented, disorder of the material is effectively improved, active sites of the material are increased, overall dynamics of the material is improved, and rate capability is enhanced.