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37results about How to "Efficient removal ability" patented technology

Preparation method and applications of ferrous sulfide/biological carbon composite material

The present invention discloses an efficient ferrous sulfide / biological carbon composite material and a preparation method thereof, and applications of the ferrous sulfide / biological carbon composite material in repair of heavy metal pollution water bodies. According to the present invention, biological carbon is adopted as a carrier, a ferrous sulfate solution and the biological carbon are mixed, sodium carboxymethyl cellulose is added as a stabilizer and a dispersant, a sodium sulfide solution is added to the system in a dropwise manner under the nitrogen protection, and vigorous stirring is performed to make the generated ferrous sulfide nanoparticles uniformly grow on the surface of the biological carbon, such that the disadvantage that the ferrous sulfide nanoparticles are easily agglomerated is substantially improved so as to increase the effective contact area between the ferrous sulfide nanoparticles and the pollutant, and the adsorption ability and the oxidation reduction ability of the ferrous sulfide and the biological carbon are integrally combined so as to improve the pollutant removal ability; the preparation method has advantages of simple and rapid process, low production cost, environmental protection and no secondary pollution; and the efficient ferrous sulfide / biological carbon composite material can strongly repair the Cr(VI) polluted water body, can effectively reduce the biological toxicity of the Cr(VI) on wheat seeds, and has wide application prospects in the fields of repair of organic pollution and inorganic pollution in environments.
Owner:NANKAI UNIV

Nano zero-valent iron composite material with superstrong reducibility and photocatalytic performance

The invention belongs to the technical field of high-toxicity pollutant treatment, and relates to a preparation method of a nano zero-valent iron composite material with superstrong reducibility and photocatalytic performance and application of the nano zero-valent iron composite material as a reducing agent and a photocatalyst to removal of organic and inorganic high-toxicity pollutants in a water body. The material is composed of a zero-valent iron core and a single crystal FeS1-x / Fe3O4 mixed shell. The preparation method is simple and green, and the utilization rate of raw materials is high. The core zero-valent iron is prevented from being eroded by water molecules and dissolved oxygen in water due to a good core-shell structure; a proper hydrophobic FeS1-x / Fe3O4 shell can be used forefficiently adsorbing and enriching pollutants in water; the good conductivity of the Fe3O4 shell ensures that electrons of the core zero-valent iron can be quickly transferred to pollutants adsorbedon the surface of the material. The material has the unique photocatalytic performance, and can accelerate reduction, oxidation and thorough mineralization of pollutants under irradiation of visible light or sunlight.
Owner:RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI

Activating and expanding culture system and activating and expanding culture method for sewage treatment active microorganisms

The invention relates to the field of sewage treatment, and discloses an activating and expanding culture system for sewage treatment active microorganisms. The system comprises a reactor main body, the reactor main body comprises a sedimentation tank, a primary activation tank and a secondary activation tank, the reactor main body is also provided with a monitoring probe, a heating and heat preservation device, a refrigeration device, an aeration device, a material storage tank, a feeding device and a single chip microcomputer control system; the monitoring probes are arranged in the first-stage activation tank and the second-stage activation tank and are used for monitoring temperature, dissolved oxygen and pH (Potential of Hydrogen); starting and stopping of the heating insulation device and the refrigeration device are adjusted by temperature parameter feedback; the aeration device is mounted at the bottoms of the primary activation tank and the secondary activation tank, and the start and stop of the aeration devices are adjusted by dissolved oxygen parameters; the storage tank is mounted at the tops of the first-stage activation tank and the second-stage activation tank; and the feeding device is arranged among the storage tank, the primary activation tank and the secondary activation tank. According to the invention, effective enrichment and proliferation of target microorganisms are realized through automatic adjustment of expanding culture conditions.
Owner:CHONGQING TECH & BUSINESS UNIV

Preparation method and application of porous hydrogel adsorbent based on astragalus mongholicus waste residue

The invention discloses a preparation method of a porous hydrogel adsorbent based on astragalus mongholicus waste residue. The preparation method comprises the following steps: taking traditional Chinese medicine astragalus mongholicus waste residue as a precursor, performing NaClO2 bleaching, KOH alkali washing and high-power ultrasonic treatment to obtain a uniformly dispersed cellulose nanofiber precursor solution; adding the cellulose nanofiber precursor solution into a mixed solution of N-N'methylene bisacrylamide, acrylic acid and ammonium persulfate, uniformly shaking, and carrying out polymerization reaction at a preset temperature to form blocky gel; and washing the blocky gel, placing the blocky gel in a dimethyl sulfoxide solution containing epoxy chloropropane for reaction, transferring the reacted product into a sodium hydroxide aqueous solution containing triethylene tetramine for reaction, and finally obtaining the amino functional modified porous hydrogel adsorbent. The traditional Chinese medicine waste residues are subjected to resource utilization, and the synthesized gel adsorbent can be further applied to adsorption removal of heavy metals and is excellent in adsorption performance, low in cost, high in stability, high in ion interference resistance and good in reusability.
Owner:SHANGHAI JIAOTONG UNIV +1

Method for removing halogenated organic pollutants in water by using metal ion doped Fe (OH) 2

The invention discloses a method for removing halogenated organic pollutants in water by using metal ion doped Fe (OH) 2, which comprises the following steps: preparing a Fe < 2 + > solution and an alkali solution in an oxygen-free environment, slowly dropwise adding the Fe < 2 + > solution into the alkali solution, and standing to obtain a Fe (OH) 2 stock solution for later use; then preparing adivalent transition metal ion solution in an oxygen-free environment for later use; sequentially adding the Fe (OH) 2 stock solution and the divalent transition metal ion solution into a reaction container in an oxygen-free environment, and regulating the pH value in the reaction container to be neutral by utilizing hydrochloric acid to obtain a decontamination solution; and finally, adding the aqueous solution containing the halogenated organic pollutants into the decontamination solution, oscillating and mixing, and carrying out decontamination reaction to finish removal of the halogenated organic pollutants in the water. According to the method, Fe (OH) 2 and metal ions are used for forming a reduction system, HOCs can be completely dehalogenated in a short time, and the efficient removal capacity is achieved; and the method is simple and convenient, convenient to implement and cost-saving.
Owner:WUHAN UNIV

Efficient response optical coupling denitration catalyst and preparation method thereof

PendingCN112675868ARealize high value-added applicationsFacilitating Light-Coupled Low-Temperature Denitrification PerformanceDispersed particle separationMetal/metal-oxides/metal-hydroxide catalystsRare-earth elementIndustrial waste
The invention discloses an efficient response optical coupling denitration catalyst and a preparation method thereof, and belongs to the technical field of blast furnace slag application. The preparation method of the product comprises the following steps: uniformly mixing the titanium-containing blast furnace slag with the rare earth element oxide, the transition metal oxide and a certain amount of sodium hydroxide, heating to melt, reconfiguring a silicate phase while solid-dissolving transition group elements into a perovskite phase, and stripping the silicate phase through acid leaching treatment, thereby finally obtaining the perovskite-based functional material. The obtained product is the optical coupling low-temperature denitration catalyst with efficient response activity. According to the catalyst prepared by the method disclosed by the invention, the removal rate of NOx can reach 100% and the N2 selectivity can reach 92% under a low-temperature condition (140 DEG C) in a manner of adding a light source, so that the denitration catalyst capable of efficiently responding under the low-temperature condition is prepared at low cost in a short process; and the method disclosed by the invention has great significance in high-added-value application of the titanium-containing blast furnace slag and continuous and efficient removal of NOx in industrial waste gas.
Owner:安徽工业大学科技园有限公司

A method of doping fe(oh) with metal ions 2 Method for Removing Halogenated Organic Pollutants in Water

The invention discloses a metal ion doping Fe(OH) 2 The method for removing halogenated organic pollutants in water is to first configure Fe in an oxygen-free environment 2+ solution and lye, and the Fe 2+ The solution was slowly added dropwise to the lye, and after the addition was completed, it was left to stand to obtain Fe(OH) 2 The stock solution is for standby; then the divalent transition metal ion solution is configured in an oxygen-free environment for standby; then in an oxygen-free environment, Fe(OH) is added to the reaction vessel in turn 2 The stock solution and the divalent transition metal ion solution are neutralized by using hydrochloric acid to adjust the pH in the reaction vessel to obtain a decontamination solution; finally, the aqueous solution containing halogenated organic pollutants is added to the decontamination solution and shaken and mixed to carry out the decontamination reaction, that is, It can complete the removal of halogenated organic pollutants in water. The present invention utilizes Fe(OH) 2 The metal ions form a reduction system, which can completely dehalogenate HOCs in a short time, and has high-efficiency removal capability; the method of the invention is simple and convenient, easy to implement, and cost-saving.
Owner:WUHAN UNIV
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