The invention provides a preparation method of a
lithium-rich
manganese-based composite positive
electrode material coated with
lithium ferric chloride and an application of a
solid-state battery, a
lithium ferric chloride coating layer is obtained in situ on the surface of the lithium-rich
manganese-based positive
electrode material through
spray drying, and compared with a common
coating layer, the lithium
ferric chloride coating layer has the advantages that the coating layer is more uniform; the
solid electrolyte has the advantages of good compatibility, excellent
conductivity and
ion conductivity and the like, and is a novel
halide positive
electrode material researched and developed for adapting to the
solid electrolyte, so that the interface incompatibility between the positive electrode and the solid
electrolyte is reduced. In addition, the excellent
conductivity of lithium ferric chloride can reduce the use of a conductive agent on the positive electrode side, reduce
ion and
electron diffusion tortuosity and improve the
diffusion coefficient. Meanwhile, the synthesis method is simple and effective, the cost is low, and the prepared composite positive
electrode material can be used as an integrated all-solid-state positive
electrode material and is suitable for large-scale production.