The invention relates to the technical field of
lithium batteries, and particularly discloses a
silicon-carbon negative
electrode active material based on a
fluidized bed method and a preparation method thereof. Comprising
silicon carbon and a Mo < x > O < y > P < z > layer; the Mo < x > O < y > P < z > layer coats the
silicon carbon; wherein 0 < x < 1, 0 < y < 1.6, and 0 < z < 1. The silicon-carbon negative
electrode active material prepared by the invention has excellent
cycling stability and rate capability, and the MoxOyPz with excellent
structural stability is uniformly coated on the silicon-carbon surface, so that direct contact between
sulfide solid electrolyte and a silicon-carbon negative
electrode can be effectively prevented, generation of high-resistance substances is inhibited, and increase of battery polarization and deterioration of rate are avoided; li < + > can be received in the first lithiation process to form a rapid
transmission channel, and Li < + > transmission is accelerated; due to the excellent
structural stability of MoxOyPz, the MoxOyPz can bear
volume expansion and shrinkage in the silicon-carbon lithiation
lithium removal process, so that the material and the electrode keep complete and stable in structure.