149 results about "Perfluoroethylene" patented technology

A compound of the formula (1): FSO2CFXCF2O(CFXCF2O)nCF-(CF2Y)COF in which X is a fluorine atom, a chlorine atom or a trifluoromethyl group, Y is a fluorine atom, a chlorine atom, a bromine atom or an iodine atom, and n is a number of 0 to 5, preferably 0, 1 or 2, is converted to a compound of the formula (2): MOSO2CFXCF2O(CFXCF2O)2CF(CF2Y)COOM1 in which X, Y and n are the same as defined above, and M and M1 independently represent an alkali metal atom or an alkaline earth metal atom, and then a compound of the formula (2) is pyrolyzed at a temperature of 150 to 250° C. to obtain a compound of the formula (3): ASO2CFXCF2O(CFXCF2O)nCF=CF2 in which A is MO-, a hydroxyl group or a fluorine atom, and X and n are the same as defined above.

A method of making a curable fluoroelastomer is disclosed. The method comprises the steps ofpreemulsifying at least one perfluorovinylether in water, andcopolymerizing the preemulsified perfluorovinylether with a gaseous fluorinated monomer in the presence of a cure site monomer. The method provides a fluoroelastomer having a glass transition temperature of less than -10° C. Also disclosed is a fluoroelastomer that consists essentially of a perfluorovinylether of formula (I) as defined below, a cure site component, perfluoromethylvinylether, and tetrafluoroethylene and/or chlorotrifluoroethylene.

The invention relates to a high-temperature resistant PTC electroconductive composition, which comprises 20 to 70 percent of organic polymers, 25 to 75 percent of electroconductive filler, 1 to 30 percent of inorganic filler and 0.1 to 10 percent of additive, wherein the preferred melting point of the organic polymers is more than 150 DEG C; the organic polymers are one or more crystalline or semi-crystalline polymers and made of one or more of nylon 11, nylon 12, polyvinylidene fluoride, soluble poly(tetrafluoroethylene), ethylene-tetrafluoroethylene copolymers, perfluoroethylene-propylene, ethylene-chlorotrifluoroethylene and copolymers thereof. The invention also provides a high-temperature resistant PTC device containing the composition and a manufacturing method thereof. The high-temperature resistant PTC device containing the composition has low resistance, high PTC strength and superior resistance stability, so that the high-temperature resistant PTC device can be used for overcurrent protection of circuits in high-temperature environments such as automobile motors and the like. Moreover, the high-temperature resistant PTC device is simple and convenient to manufacture and has high efficiency.

Fluoroelastomers are disclosed which have a glass transition temperature less than −10° C. The elastomers contain copolymerized units of a perfluorovinylpolyether that is derived from a trimer or tetramer of hexafluoropropylene oxide.

The invention relates to a method for producing hexafluoropropane oxide and coproducing perfluorovinyl ether, which comprises the following steps of: performing reaction of oxidizing hexafluoropropylene to synthesize the hexafluoropropylene oxide to obtain mixed gas, introducing the mixed gas into a coarse fractionating tower, and rectifying and purifying the separated heavy component to obtain hexafluoropropylene oxide; making the separated light component enter a rectifying tower to remove non-condensable gas to obtain mixed gas of fluorophosgene and perfluacetylfluoride, and introducing the hexafluoropropylene oxide for polymerization to obtain a corresponding perfluoroalkylpolyether mixture; in the presence of sodium carbonate, performing cracking reaction at the temperature of between 150 and 300 to obtain a perfluorovinyl ether mixture; and separating by using the rectifying tower to respectively obtain three kinds of perfluorovinyl ether, namely PMVE, PEVE, PPVE. The method fulfills the aim of producing the hexafluoropropane oxide, and fully utilizes a byproduct, namely perfluorovinyl ether with high added-value generated by the reaction, and has the advantages of reasonable process and industrial application.

The fuser members of this invention include a core member that includes a rigid outer surface. An adhesion promoter layer comprising silane or epoxy silane coupling is disposed on the outer surface of the core member. A resilient layer comprising an elastomer is disposed on the adhesion promoter layer. A tie layer is disposed on the resilient layer, the tie layer being made of fluoropolymers, fluoroelastomers, fluorocarbon thermoplastic copolymers and mixtures thereof. A primer layer, disposed on the tie layer, comprising perfluoroalkoxy resin and trifluoroethylene-perfluoroethyl vinyl ether-perfluoroethylene vinyl phosphate or a mixture of perfluoroalkoxy resin and trifluoroethylene-perfluoroethylvinyl ether; and an outer layer of fluoropolymer resin made from polytetrafluoroethylene, polyperfluoroalkoxy-tetrafluoroethylene, polyfluorinated ethylene-propylene and blends thereof is disposed on the primer layer.

The invention discloses an insulating wire cable of irradiation cross-linking modified ethane-perfluoroethylene polymer (X-ETFE) with metal screening layer and protecting layer, which is characterized by the following: the insulating thickness is 0.01-0.25 mm, which improves insulating wire heatproof grade; the product satisfies the aviation cable need under kinds of terrible climates.

The multicomponent mixed work medium throttling refrigerating agent applicable to 200-240 k temp. zone includes four groups of substances, respectively are: first group includes tetrafluoromethane, nitrogen trifluoride or mixture; second group includes ethylene, ethane, fluoroform, xenon, fluromethane, perfluoroethylene, fluoroethylene, perfluoroethane or their any two, three and several kinds or mixture of all them; fourth group includes 1-butylene, isobutane, 2-methyl butane, 1-pentene, 3-methyl-1-butylene, 2-methylpentane, 2-butylene, cyclobutane, isobutylene, n-butane, pefluorobutane, n-pentane, perfluoropentane or their two, three, several kinds ormixture of all the them; and third group includees propylene, propane, perfluoropropane, 1,1,1-trifluoroethane, 1,1,-bifluoroethane.

The invention discloses a microemulsion polymerization method of perfluoroethylene and hexafluoropropene copolymer, which uses monomer medium liquefied hexafluoropropene as organic phase, adds monomer medium liquefied hexafluoropropene, emulsifier and co-emulsifier into water, to form O/W type microemulsion, feeds perfluoroethylene and hexafluoropropylene initial mixture gas and complement mixture gas, uses oil-soluble free radical initiator to initialize reaction, after the reaction, heats to separate and recover liquefied hexafluoropropene, discharges water, heats obtained polymer powder, to remove non-decomposed initiator, decomposition product, and residual water and foreign materials. The product powder of the invention has uniform and small size, non block. And the invention uses liquefied hexafluoropropene as organic phase to avoid organic solvent pollution on product and environment.

This invention discloses a method for condensing and washing perfluoroethylene-perfluoropropylene copolymer prepared by emulsion polymerization. The method comprises: (1) adding 1-10 deg.C deionized water to perfluoroethylene-perfluoropropylene copolymer emulsion, stirring, demulsifying, and washing the precipitate with 40-80 deg.C deionized water for 2-6 times (1-5 min for each time). The method can largely increase the equipment productivity, lower the consumption of pure water, save the raw materials, and shorten the treatment period.

The invention belongs to the technical field of perfluorinated resin, and particularly relates to a preparation method of Perfluorovinyl ether sulfonyl fluoride. A CF2=CF(OCF2CFX)mO(CF2)nSO2F productis directly generated from perfluorovinyl ether sulfonate CF2=CF(OCF2CFX)mO(CF2)nSO2OM by a one-step reaction under the action of a fluorinating reagent CHClFCF2N(C2H5)2,CF3CHFCF2N(C2H5)2. The preparation method has the advantages of simple process, easiness in operation, low reagent cost, avoidance of the production of waste acid gas and waste liquid as well as the increase of multi-step wastageand by-products; reaction steps are reduced, and the use of high-toxicity and high-risk reagents is avoided at the same time, and the yield can be up to 80 percent or more.

A perfluoroelastomer compound having improved processability comprising a perfluoroolefin, a perfluorovinyl ether and a halogen-containing cure site, where the polymer contains substantially no ionizable moieties; and processes for making such copolymers; and articles made therefrom.

The invention discloses a fluorine-containing material preparation method, and an application of a fluorine-containing material prepared through using the method. The fluorine-containing material preparation method comprises the following steps: adding deionized water to a reaction kettle, and reserving 1/3-1/2 of the space of the reaction kettle; adding parts of polymerization monomers to the reaction kettle, sequentially adding 0.01-1 part by weight of an emulsifier, 0.015-0.3 parts by weight of a pH adjusting agent and 0.001-0.02 parts by weight of an initiator to every 100 parts of deionized water, and reacting; maintaining the oxygen content in the reaction kettle to be smaller than 30ppm, the pressure to be 2.5-4.5MPa and the temperature to be 30-65DEG C in the reaction process, and adding other polymerization monomers until the reaction ends, wherein 50-70 parts by weight of the polymerization monomers are totally added; and processing a dispersion obtained after the reaction to form the fluorine-containing material, wherein the polymerization monomers comprise at least two of vinylidene fluoride, trifluorochloroethylene, tetrafluoroethylene, hexafluoropropene, perfluorovinyl ether and monoolefin. The characteristic viscosity of the fluorine-containing material prepared through the fluorine-containing material preparation method is greater than 7.5g/100ml, and the number-average molecular weight is greater than 1,200,000.

The invention is a solid acid compound catalyst whose component is: 10-80% sulfuric acid or phosphoric acid, 1-10% fluosulfonic acid resin and oxide of silicon, aluminum, titanium or zirconium; the fluosulfonic acid resin the polymer of perfluoroethylene and sulfonated perfluoroethylene, its average molecular weight is 300-500 thousands, the sulfonating rate is 1-5%. The mol rate of carbon element and fluorin element is 1:2. The catalyst blends the liquid acid and solid acid into a compound evenly, it maintains the nature of the liquid acid and the solid acid, and it has higher acid intensity and acid center quantity, the distribution of the acid center is even, the liquid acid will not be lost in the reaction.

This invention relates to one high temperature macromolecule PTC heat sensitive resistance, which is made of conductive macromolecule materials by press, wherein, the materials is added with heat fluro-resin and the layer silicon salt clay through surface process; the formula is as: macromolecule polymer for 30 to 60 percent; carbon for 30 to 55 percent; heat fix fluro-resin for 0.5 to 20 percent; layer silicon salt for 25 to 25 percent; process aid for 0.1 to 10 percent; the macromolecule polymer is of polyvinylidene fluoride, melt politef, ethene perfluoroethylene polymer, nylon 11 and 12, fluorinated ethylenepropylene copolymer and chlorotrifluoroethylene.

The invention relates to a condensation and washing method of perfluoroethylene propylene resin. The condensation and washing method comprises the following steps: 1) adding room-temperature de-ionized water into perfluoroethylene propylene emulsion and adjusting the emulsion ratio to be 1.03 to 1.20; starting to stir and carrying out physical emulsion breaking on the emulsion for 15 to 60 min under the condition of 500 to 2000 r/min; 2) adding a condensation agent ammonium bicarbonate with the resin solid content of 1 to 5 percent into the emulsion and continually stirring until the perfluoroethylene propylene emulsion is completely broken; 3) repeatedly washing perfluoroethylene propylene, which is separated through the emulsion breaking, by utilizing the room-temperature de-ionized water until the detection is qualified. The method provided by the invention is used for carrying out the emulsion breaking and can be used for completely separating out the resin in the perfluoroethylenepropylene emulsion; compared with other methods, the subsequent dosage of washing water is not increased. The method provided by the invention is simple in steps and environmentally friendly, and industrialized large-scale production is facilitated.

The present invention discloses a chip type light derivatizer for aflatoxins and sulfonamides. An ultraviolet light-emitting diode (LED) having a center wavelength between 280 and 380 nm as an excitation light source, high-transparent quartz, ultraviolet-transmitting glass, PDMS (Polydimethylsiloxane) or perfluoroethylene propylene copolymer (FEP) is used as a chip substrate, a rectangular or trapezoidal groove path having a width of 10 to 500 mu m, a depth of 10 to 260 mu m, and a length of 5 to 500 mm is fabricated on the chip substrate as a derivation reaction tank, the groove path is in linear or comb-like or sine-wave shaped arrangement, the volume of the derivation reaction tank is 5nL to 75mu L, and is only 1/13 to 1/100000 of the volume of the derivation reaction tank of a conventional derivatizer. The chip type light derivatizer improves the fluorescence intensity of aflatoxin B1 by 6.5 times, and is suitable for post-column light derivation of chip capillary electrophoresis,chip microfluidic analysis, capillary liquid chromatography, microcolumn liquid chromatography, ultrahigh pressure liquid phase chromatography and normal liquid chromatography, and micro flow injection analysis/small flow injection analysis.