The invention discloses an OFDM encryption method based on a composite chaotic system and exclusive-OR operation. According to the method, Logistic mapping, Sine mapping and tent mapping are combined;a new composite discrete chaotic system is constructed; a chaotic sequence generated by the new system is used to carry out double encryption on a complex symbol after QAM mapping of the OFDM communication system; firstly, bitwise exclusive OR operation is adopted, secondly, a scrambling matrix is adopted for scrambling, after first encryption, a constellation diagram obtained after QAM mapping is changed into 49 constellation points from original 16 points, and an obvious confusion effect is achieved; and after the second encryption, the constellation points after the first encryption are further disrupted, inverse operation is performed at a receiving end according to the same chaotic sequence for decryption, and the bit error rate after decryption is within an acceptable range. According to the encryption scheme, the size of the disturbance matrix can be dynamically adjusted according to the size of the sent data, the flexibility is high, and violent attacks can be effectively prevented.