The invention discloses a method for monitoring organic coating material carrier density. The invention includes the following steps: measure electrode base material is stainless steel stick which is sealed with epoxy resin, after the working surface is polished, cleaned and dried, the working surface is painted with organic coating material, the thickness of the painted film is controlled at 25 microns plus or minus 2 microns, and the working surface is constant temperature dried at 35 DEG C, then the membrane coated electrode is obtained; the membrane coated electrode is dipped in 5% sodium salt solution at room temperature, the saturated calomel is used as the assistant electrode, the platinum electrode is the reference electrode, the membrane coated electrode potential U and the capacitance Csc are measured; the relationship curve between the Csc-2 and U is drawn, and the Mott-Schottky relation schema is obtained; according to the Mott-Schottky relational expression, the Mott-Schottky relation schema is extrapolated to the crossing point of the potential axis, then the flat-band potential Ufb is obtained, at the same time the space charge density ND is calculated by slope, which is the carrier density.