The application discloses a
polymer light-emitting
diode containing a full conjugated self-assembled
monolayer and a preparation method thereof, and relates to the technical field of optoelectronic devices. The organic light-emitting
diode comprises, from bottom to top, an
anode, a full conjugated self-assembled
monolayer, a light-emitting layer, a
lithium fluoride layer and a
cathode; wherein the material of the
anode is selected from
indium tin oxide and / or
fluorine-doped
indium tin oxide; and the material of the full conjugated self-assembled
monolayer is a full conjugated
carbazole phosphoric acid derivative of one or more of the following structures: The full conjugated
carbazole phosphoric acid derivative is used as
anode modification material, can form an ultrathin self-assembled film, enhance light
transmittance, can adjust the ITO
work function, reduce the energy difference between the anode and the light-emitting
polymer, improve the hole injection efficiency, and thus improve the light-emitting efficiency. In addition, the full conjugated
carbazole phosphoric acid derivative is simple to synthesize, low in price, soluble in
alcohol-based environmentally-friendly non-halogenated organic solvents, and suitable for carrying out liquid-phase process film forming, and is green and environmentally-friendly.