The invention discloses
manganese ion doped enhanced up-conversion
red light emitting
scandium aluminate and a synthesis method thereof, and belongs to the technical field of up-conversion luminescent materials. The molecular formula of the up-conversion
luminescent material provided by the invention is Ba (2-x) MnxSc (0.67) Yb (0.3) Er (0.03) AlO5 (x = 0-0.5), and the preparation method is a high-temperature
solid phase method. The
radius of
manganese ions is much smaller than that of
barium ions, so that the
manganese ions easily enter a main substrate Ba2ScAlO5 and influence a
crystal field, and
oxygen vacancies are generated in the material. Defects formed by the
oxygen vacancies can increase the
energy transfer efficiency of the material, so that the
sensitization and emission capabilities of
rare earth ions are improved, and the
luminescence characteristic of the material is improved. The obtained Ba1. 6Mn0. 4Sc0. 67Yb0. 3Er0. 03AlO5 has the maximum
red light emission intensity at the
red light wavelength of 664nm under the excitation of 980nm
near infrared laser, and compared with the red
light emission intensity of Ba2Sc0. 67Yb0. 3Er0. 03AlO5 obtained in a contrast, the red
light emission intensity of the Ba1. 6Mn0. 4Sc0. 67Yb0. 3Er0. 03AlO5 is improved by nearly 27.4 times. The manganese
ion doped
scandium barium aluminate up-conversion
luminescent material prepared by the invention has excellent single red up-conversion
luminescence, and meanwhile, the preparation method is simple, good in
controllability, high in yield and more energy-saving and environment-friendly in preparation process, and is suitable for industrial popularization.