The present application relates to the technical field of organic photoelectric material, in particular to a stretchable
polymer based on diarylfluorene derivative and a preparation method and application thereof.The stretchable
polymer based on diarylfluorene derivative has a
structural unit as shown in formula (I), wherein R1 is selected from a
fluorine-substituted
alkyl chain with 4-20 carbon atoms, and R2 is selected from an
alkyl chain or a
fluorine-substituted
alkyl chain with 4-20 carbon atoms.The present application designs and synthesizes a
fluorene monomer substituted by diaryl at the 9th position by using 2,7-dibromofluorenone as
raw material through Bayer-Villiger rearrangement and
Grignard reaction, introduces a
fluorine-substituted alkyl chain at the 4th position of the
fluorene unit, effectively enhances the chain entanglement between polymers and constructs a crosslinked
network structure, and provides a
polymer with excellent flexibility, stretchability and stable photoelectric performance.