Hydrogenation catalyst of containing phosphor with alumina being as carrier, and preparation

Abstract

This invention provides a method for preparing hydrogenation catalyst containing phosphorus supported by aluminum oxide. The catalyst is composed of nickel oxide 1-10 wt.%, molybdena oxide and tungsten oxide 10-50 wt.%, phosphorus oxide 1-10 wt.%, and aluminum oxide. The molar ratio of tungsten oxide to molybdena oxide is 2.6-30. The method comprises introducing nickel oxide, molybdena oxide, tungsten oxide and phosphorus oxide into aluminum oxide carrier. The catalyst has such advantage as high hydrogenation activity.

Description

technical field

[0001] The invention relates to a hydrogenation catalyst and its preparation, more specifically to a phosphorus-containing hydrogenation catalyst with alumina as a carrier and its preparation. Background technique

[0002] Under the hydrogenation reaction conditions, the contact of the hydrocarbon feedstock with the catalyst may occur including: hydrogenation, hydrodesulfurization, hydrodenitrogenation, hydrodemetallization, hydrodearomatization, hydroisomerization, hydrodewaxing, hydrogenation Reactions such as hydrocracking and moderate hydrocracking. The catalysts therein are generally formed by the carrier supporting metal components of Group VIB and Group VIII. The hydrogenation active metal component is usually selected from Co or Ni-Mo or Co or Ni-W, and the carrier is usually selected from alumina, silica-alumina and their modified products. These catalysts can be prepared by impregnating the support with an aqueous solution ...

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