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This invention discloses a high-performance polymer electrolyte based on a functionalized fluorinated ether diluent and its preparation method, relating to the field of electrochemical energy storage materials technology. The high-performance polymer electrolyte comprises: a polymer matrix, a lithium salt, an organic dispersion solvent, and a functionalized fluorinated ether diluent. By introducing a fluorinated ether diluent with a specific structure, this invention synergistically regulates the crystallization behavior of the polymer matrix and the lithium-ion solvation structure, solving core problems in traditional polymer electrolytes such as low ionic conductivity, poor interfacial stability, and lithium dendrite growth. The resulting electrolyte possesses high ionic conductivity, high lithium-ion transference number, and excellent interfacial stability, making it suitable for high-energy-density lithium metal batteries.