The invention discloses a preparation method of a small-pore-
diameter narrow-distribution
polytetrafluoroethylene microporous membrane. By mixing of dispersible
polytetrafluoroethylene resin, solventoil and a surface
active agent and adopting the processes of
ageing, blank manufacture, pushing and squeezing, calendaring, oil removal, longitudinal pulling treatment, horizontal pulling treatment,
sintering and
sizing and the like, the
polytetrafluoroethylene microporous membrane with the
pore diameter being 10-50nm and the bubble-point
pore diameter being less than 80nm is manufactured; the surface
active agent is added into a formula, and by the action of the surface
active agent, the wettability of the
solvent oil is obviously improved, and the wrapping degree of the
solvent oil to the polytetrafluoroethylene resin is obviously improved, so that the formation degree of micropores in the drawing and expanding processes is greatly reduced; under the action of same shearing force, the formed micropores are more and smaller, so that the microporous membrane with small
pore diameter and narrow distribution is obtained; the preparation method is easy in industrial production, can utilize the existing
manure equipment only in need of proper process adjustment, and has strong practicability and wide applicability.