This invention discloses a positive
electrode paste for lead-acid batteries with high cycle stability and its preparation method, belonging to the field of
electrochemical energy storage technology. Rice
husk ash is acid-treated to obtain a wet
filter cake. The wet
filter cake is refluxed with
silane coupling agent KH-550 to obtain functionalized rice
husk ash. The functionalized rice
husk ash,
pyrrole, and
ammonium persulfate are mixed and stirred to obtain a composite conductive agent.
Aniline, o-
aminobenzoic acid, and
ammonium persulfate are mixed and stirred to obtain a conductive
copolymer. The conductive
copolymer is mixed with N-methylpyrrolidone to obtain a dispersion, and
glycerol is added and stirred to obtain a modified precursor solution. Lead
powder, mixed conductive agent,
polypropylene short fibers,
stannous sulfate,
sulfuric acid solution, deionized water, and the precursor solution are mixed to obtain the positive
electrode paste. This method improves the
structural stability and
electronic conductivity of the positive
electrode active material, effectively inhibits the shedding of active material and interface peeling during
cycling, and extends the cycle life of the battery under high-rate
partial charge conditions.