Deep cycle battery lead paste preparation method with characteristic of easy 4BS generation

A deep-cycle battery and manufacturing method technology, applied in battery electrodes, lead-acid battery electrodes, circuits, etc., can solve problems such as difficulty in generating 4BS, achieve the effects of reducing energy consumption, ensuring battery life, and improving battery life

Active Publication Date: 2017-11-07
TIANNENG BATTERY GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The purpose of the present invention is to provide a kind of preparation method of the deep cycle battery lead paste that is beneficial to generate 4BS, can obtain a certain amount of 4BS while not changing the formula of power battery lead paste, prolong the service life of lead storage battery, solve the existing problem Difficult problem of generating 4BS in technology

Method used

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  • Deep cycle battery lead paste preparation method with characteristic of easy 4BS generation
  • Deep cycle battery lead paste preparation method with characteristic of easy 4BS generation
  • Deep cycle battery lead paste preparation method with characteristic of easy 4BS generation

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Put 100Kg of lead powder into the vacuum paste machine, add 75g of fiber to the lead powder, dry stir for 3 minutes, add 11.5L of water within 1 minute, stir for another 3 minutes, then add 10.5kg of acid (the specific gravity of the acid is 1.4g / ml), adjust the angle of the acid nozzle, add 85% of the acid within 3 minutes, control the total time of acid addition within 12 minutes, and set the highest temperature to 80°C, keep the vacuum and stir for another 5 minutes , and then add 1.5kg of sulfuric acid mixture (antimony trioxide and stannous sulfate to the remaining sulfuric acid to obtain, consisting of 1.3kg of dilute sulfuric acid with a density of 1.15g / ml, 100g of antimony trioxide, and 100g of stannous sulfate ) within 2 minutes into the primary mixed acid lead paste for 4 minutes of stirring reaction, and then lower the temperature to less than 45°C to obtain deep cycle battery lead paste 1.

[0031] The formed product was observed under a scanning electron ...

Embodiment 2

[0035] Put 100Kg of lead powder into the vacuum paste machine, add 75g of fiber to the lead powder, dry stir for 5 minutes, add 11.7L of water within 1 minute, stir for another 5 minutes, then add 10kg of acid (the specific gravity of the acid is 1.4g / ml ), adjust the angle of the acid feed nozzle, add 85% of the acid within 5 minutes, control the total time of acid addition within 10 minutes, and set the highest temperature to 65°C, keep the vacuum and stir for another 7 minutes, Then add 1.5kg of sulfuric acid mixture (to obtain by adding antimony trioxide and stannous sulfate to the remaining sulfuric acid, composed of 1.3kg of dilute sulfuric acid with a density of 1.3g / ml, 100g of antimony trioxide, and 100g of stannous sulfate) Mix it into the primary mixed acid lead paste within 1 minute for a stirring reaction for 5 minutes, and then lower the temperature to less than 45°C to obtain deep cycle battery lead paste 2.

[0036] The formed product was observed under a scann...

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Abstract

The invention discloses a deep cycle battery lead paste preparation method with a characteristic of easy 4BS generation, and belongs to the technical field of lead storage battery production. The preparation method comprises: (1) carrying out dry mixing on lead powder and additives excluding diantimony trioxide and stannous sulfate, adding water, carrying out wet mixing, adding sulfuric acid accounting for more than 80% of the total acid amount, carrying out a stirring reaction, and controlling the reaction temperature at 65-85 DEG C to obtain a first acid mixing lead paste; and (2) adding diantimony trioxide and stannous sulfate to the remaining sulfuric acid to obtain a sulfuric acid mixed solution, mixing the sulfuric acid mixed solution into the first acid mixing lead paste, carrying out a stirring reaction, and cooling to achieve a temperature of less than 45 DEG C to obtain the deep cycle battery lead paste. According to the present invention, the acid adding is performed twice in the method, and the 4BS-inhibiting components such as diantimony trioxide and stannous sulfate are added at the late stage, such that the power battery lead paste formula is not affected, and a certain amount of the 4BS can be effectively obtained.

Description

technical field [0001] The invention relates to the technical field of lead storage battery production, in particular to a preparation method for deep-cycle battery lead paste which is beneficial to the generation of 4BS. Background technique [0002] In the production process of lead-acid batteries, mixing paste is a key process of the battery process, and its quality directly affects the performance of the battery, especially the life of the battery and the initial performance of the battery, and the initial performance and life of the battery are directly related to the lead-acid battery. Consumer needs. [0003] In order to further improve the life of the battery, a common practice is to form a certain amount of tetrabasic lead sulfate (4BS) through high temperature during paste mixing / curing, thereby strengthening the skeleton of the positive active material to improve the life of the battery. Tetrabasic lead sulfate (4BS) has the advantages of large crystal size, tigh...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/57H01M4/62H01M4/20
CPCH01M4/20H01M4/57H01M4/62Y02E60/10
Inventor 李桂发马铭泽毛书彦郭志刚邓成智刘玉崔海涛李雪辉孔鹤鹏
Owner TIANNENG BATTERY GROUP
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