The invention relates to a composite chemical
nickel and
phosphor plating method, characterized by comprising the following steps: 1) the pH value of the chemical
nickel and
phosphor plating solution containing
nickel sulfate with the concentration being 26 to 30 g / l,
sodium hypophosphite with the concentration being 23 to 27 g / l,
sodium citrate with the concentration being 38 to 42 g / l and
sodium acetate with the concentration being 23 to 27 g / l is adjusted to be 9 to 10,
neodymium(III)
sulfate octahydrate is mixed with the chemical nickel and
phosphor plating solution uniformly at the addition amount is 0.4 to 0.8 g / l, the above solution is plated on the pretreated
neodymium iron
boron magnet under the effect of the ultrasonic wave for 10 to 60 minutes to obtain a nickel and phosphor plating layer with the
crystal grain size of 5 to 8 nm; 2) the pH value of the chemical nickel and phosphor plating solution containing nickel
sulfate with the concentration being 22 to 26 g / l,
sodium hypophosphite with the concentration being 28 to 32 g / l,
sodium citrate with the concentration being 43 to 47 g / l and
sodium acetate with the concentration being 28 to 32 g / l is adjusted to be 4.2 to 5.6, the plated
neodymium iron
boron magnet in the step(1) is placed into the chemical nickel and phosphor plating solution in the step(2) for plating for 30 to 120 minutes, the amorphous nickel and phosphor plating layer is obtained. Compared with the prior art, the plating layer has
high adhesion and good
corrosion resistance, the thickness of the plating layer can be reduced and the loss of the magnetic property can be lowered.