The invention discloses a preparation method of a high-temperature-resistant and high-wear-resistant bio-based waterproof
moisture-permeable membrane for shoes, which comprises the following steps: step 1, preparing a high-temperature-resistant and high-wear-resistant bio-based
polyurethane membrane
casting solution, namely mixing bio-based
polyurethane resin, wear-resistant high-specific-heat particles, a pore-
foaming agent, a modifier, a
coupling agent and an auxiliary agent, and uniformly stirring to obtain the high-temperature-resistant and high-wear-resistant bio-based
polyurethane membrane
casting solution; a uniform membrane
casting solution is formed; 2,
film coating is conducted through a template method, specifically, the high-temperature-resistant
nanofiber skeleton is fixed to a base material, the fixed
nanofiber skeleton is filled with the film casting solution, and pre-crosslinking treatment is conducted on the film casting solution through
ultraviolet light irradiation; 3, gradient coagulating bath synergistic phase separation pore forming is carried out, specifically, the film layer subjected to
ultraviolet light irradiation treatment is sequentially immersed into at least two coagulating baths, the first coagulating bath is used for activating
covalent bond reaction of active groups on the surface of the film layer and inhibiting the phase separation rate, and the second coagulating bath is used for activating
covalent bond reaction of the active groups on the surface of the film layer; the second coagulating bath is used for quickly desolvating, inducing phase separation and forming a through microporous structure; and 4, carrying out post-curing treatment on the film layer to lock the through micropore structure and complete residual crosslinking. By adopting the technical scheme, the high
temperature resistance and
wear resistance of the bio-based waterproof
moisture-permeable film can be improved.