The invention belongs to the field of photovoltaic encapsulation adhesive films and preparation thereof, and particularly relates to a silane grafted POE photovoltaic encapsulation adhesive film and apreparation method thereof. The silane grafted POE adhesive film comprises the following components in parts by mass: 100 parts of ethylene-octene copolymer resin, 0.3-3 parts of silane grafted monomer, 0.05-0.25 parts of an initiator, 5-20 parts of modified resin, 0.05-0.25 parts of co-grafted monomer, 0.5-4 parts of a compatilizer, 0.05-0.3 parts of an ultraviolet light stabilizing agent, 0.05-0.3 parts of an ultraviolet absorber and 0.1-0.6 part of an antioxidant. The prepared adhesive film for POE photovoltaic encapsulation can be simultaneously applied to a flexible thin-film photovoltaic assembly and a traditional crystalline silicon photovoltaic assembly, the problems of air bubbles, no-melting and poor thermal creep resistance in an ageing process can be solved, the laminating time of the assemblies is shortened, the packaging defective percentage is reduced, the production efficiency of the assemblies is improved, and the production cost is reduced.