Polyimide solvent cast films having a low coefficient of thermal expansion and method of manufacture thereof

a technology of solvent cast film and thermal expansion coefficient, which is applied in the direction of chemistry apparatus and processes, synthetic resin layered products, transportation and packaging, etc., can solve the problem of film failing the tes

Inactive Publication Date: 2008-02-21
SABIC INNOVATIVE PLASTICS IP BV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0019]In still another embodiment, a solvent cast film comprises: a polyimide comprising structural units derived from a dianhydride selected from the group consisting of 3,4′-oxydiphthalic dianhydride, 3,3′-oxydiphthalic dianhydride, 4,4′-oxydiphthalic dianhydride, and a combination thereof, and a diamine selected from the group consisting of 4,4′-diaminodiphenylsulfone, m-phenylenediamine, p-phenylenediamine, and a combination thereof, wherein the polyimide has a glass transition temperature from 190° C. to 400° C.; wherein the film has less than 15 molar % of a member selected from the group consisting of biphenyltetracarboxylic acid, dianhydrides of biphenyltetracarboxylic acid, esters of biphenyltetracarboxylic acid, and combinations thereof, and further wherein the film has a coefficient of thermal expansion of less than 60 ppm/° C., wherein the film has a coefficient of thermal expansion that is within +20 ppm/° C. of the coefficient of thermal expansion of copper, silicon, aluminum, gold, si

Problems solved by technology

When these layers don't expand and contract at the same rate issues regarding the adherence, and orienta

Method used

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  • Polyimide solvent cast films having a low coefficient of thermal expansion and method of manufacture thereof
  • Polyimide solvent cast films having a low coefficient of thermal expansion and method of manufacture thereof
  • Polyimide solvent cast films having a low coefficient of thermal expansion and method of manufacture thereof

Examples

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examples

[0220]Without further elaboration, it is believed that the skilled artisan can, using the description herein, make and use the present invention. The following examples are included to provide additional guidance to those skilled in the art of practicing the claimed invention. These examples are provided as representative of the work and contribute to the teaching of the present invention. Accordingly, these examples are not intended to limit the scope of the present invention in any way. Unless otherwise specified below, all parts are by weight and all temperatures are in degrees Celsius.

Materials

[0221]ODPA is a dianhydride monomer also known as 4,4′-oxydiphthalic anhydride which can be made as described in U.S. Pat. No. 6,028,203, U.S. Pat. No. 4,870,194, or U.S. Pat. No. 5,021,168.

[0222]BPDA is a dianhydride monomer also known as 3,3′,4,4′-biphenyltetracarboxylic dianhydride, which is commercially available from Chriskev Company, with offices in Leawood, Kans.

[0223]PMDA is a dian...

examples 1-72

Film Casting Procedure and Experimental for Examples 1-72:

[0235]Inventive formulations 1-72 were prepared using the compositions specified in Table 1. The amounts of each monomer were calculated at a stoichiometry of 1 amine for every anhydride with no correction for purity, (corrections for purity can affect the final molecular weight of the polymer and could affect the final performance of the article). A Microsoft Excel spreadsheet calculator was constructed that calculates the grams of each monomer based upon the total grams polymer desired and the monomer feeds of dianhydride and amine. The skilled artisan will appreciate that there are many different ways of ascertaining the correct amount by weight of each ingredient to be used in making the films according to the present invention. It is within the ability of the skilled artisan to calculate the weight amount of ingredients based on the overall stoichiometry and the final percent solids of the reaction mechanism enunciated h...

example 73

Detailed Film Casting Example:

[0241]On an analytical balance, 0.5937 g (0.001914 mol) of 4,4′-oxydiphthalic anhydride and 0.4752 g (0.001914 mol) of 4,4′-diaminodiphenylsulfone were weighed out to be with in 0.0005 g of the desired weight. The monomers were transferred to a 20 mL scintillation vial, rinsing the weigh paper with 2.0 mL of dimethylacetamide, to ensure complete transfer of the monomers. The remaining solvent (5.47 mL of dimethylacetamide) was transferred by volumetric pipette to give a solution of 12.5 weight % solids. The vial was rendered inert by flowing nitrogen through the vial for one minute and then quickly capping the vial. The sample was then placed on the shaker overnight to form a poly(amic acid) solution.

[0242]Glass slides (Fisherbrand precleaned microscope slides) were cleaned with hexanes. The solution (2.0 mL) was then filtered through a 0.45 micrometer syringe tip filter onto a glass slide. The solution coated glass slide was then placed on a hotplate e...

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Abstract

A solvent cast film comprises a polyimide comprising structural units derived from polymerization of a dianhydride component comprising a dianhydride selected from the group consisting of 3,4′-oxydiphthalic dianhydride, 3,3′-oxydiphthalic dianhydride, 4,4′-oxydiphthalic dianhydride, and combinations thereof, with a diamine component wherein the polyimide has a glass transition temperature of at least 190° C.; wherein the film has a coefficient of thermal expansion of less than 60 ppm/° C., a thickness from 0.1 to 250 micrometers, and less than 5% residual solvent by weight; wherein the polyimide has less than 15 molar % of structural units derived from a member selected from the group consisting of biphenyltetracarboxylic acid, a dianhydride of biphenyltetracarboxylic acid, an ester of biphenyltetracarboxylic acid, and a combination thereof.

Description

CROSS REFERENCE TO RELATED APPLICATION[0001]This application claims priority to copending U.S. Provisional Application Ser. No. 60 / 805,821, filed Jun. 26, 2006, which is incorporated herein by reference in its entirety.FIELD OF THE INVENTION[0002]The present invention is directed to a solvent cast film comprising a polyimide and methods for the manufacture of such films. The film is formed by polymerization of a dianhydride component and a diamine component, and has a Tg of between 180° C. and 450° C., specifically 190° C. or greater, and wherein the film has: a) a CTE of less than 70 ppm / ° C., specifically less than 60 ppm / ° C.; b) a thickness of 0.1 micrometers and 250 micrometers, specifically 5 to 250 micrometers; and, c) contains less than 5% residual solvent by weight.BACKGROUND OF THE INVENTION[0003]Thermoplastic sheets and films have a broad range of applications. For instance, thermoplastic films and sheets can be found in automotive applications, electronic applications, m...

Claims

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Application Information

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IPC IPC(8): C08G69/26B32B5/00C08K3/34
CPCB82Y30/00C08G73/1007C08J5/005C08J5/18C08J2379/08H05K2201/068H05K1/0373H05K2201/0154H05K2201/0209H05K2201/0257H05K1/0346
Inventor CHAN, KWOK PONGHAGBERG, ERIKMULLEN, TARA J.ODLE, ROY RAY
Owner SABIC INNOVATIVE PLASTICS IP BV
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