PE (polyurethane) protective film glue and preparation method thereof

A technology of protective film and glue, applied in the direction of adhesive, film/sheet adhesive, adhesive type, etc., can solve the problems of water-based adhesive adhesion, bonding strength and drying time that are not as good as solvent-based adhesives, etc. The effect of fast drying time, strong adhesion and strong bond strength

A technology of protective film and glue, applied in the direction of adhesive, film/sheet adhesive, adhesive type, etc., can solve the problems of water-based adhesive adhesion, bonding strength and drying time that are not as good as solvent-based adhesives, etc. The effect of fast drying time, strong adhesion and strong bond strength

CN102206476AInactive Publication Date: 2011-10-05BOLEX SHENZHEN ADHESIVE PROD
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0065] The formula used to prepare PE protective film glue is as follows:

[0066] Butyl acrylate (BA) 25

[0067] Methyl methacrylate (MMA) 45

[0068] Methyl acrylate (MA) 12

[0069] Acrylic (AA) 5

[0070] Hydroxyethyl acrylate (HEA) 20

[0071] Isooctyl acrylate (EHA) 120

[0072] Polyoxyethylene octyl phenyl ether (OP-10) 1.5

[0073] Sodium lauryl sulfate (SLS-046) 0.5

[0074] Sodium dodecylbenzene sulfonate 0.2

[0075] Deionized water 280

[0076] Ammonium persulfate 0.8

[0077] Polyisocyanates 2.3.

[0078] The preparation method is as follows:

[0079] S100. Preparation of seed emulsion: butyl acrylate, methyl methacrylate, methyl acrylate, and isooctyl acrylate that account for 30% of each weight in the formula, sodium lauryl sulfate and ten Add sodium dialkylbenzene sulfonate, initiator, and deionized water into the reactor, increase the temperature to 85°C, and keep it for 20 minutes;

[0080] S200. P...

Embodiment 2

[0087] The formula used to prepare PE protective film glue is as follows:

[0088] Butyl acrylate (BA) 40

[0089] Methyl methacrylate (MMA) 30

[0090] Methyl acrylate (MA) 20

[0091] Acrylic (AA) 10

[0092] Hydroxyethyl acrylate (HEA) 10

[0093] Isooctyl acrylate (EHA) 140

[0094] Octyl phenyl polyoxyethylene ether (OP-10) 0.9

[0095] Sodium Lauryl Sulfate (SLS-046) 1.0

[0096] Sodium dodecylbenzene sulfonate 0.7

[0097] Deionized water 350

[0098] Ammonium persulfate 1.5

[0099] Polyisocyanates 3.

[0100] The preparation method is as follows:

[0101] S100. Preparation of seed emulsion: butyl acrylate, methyl methacrylate, methyl acrylate, and isooctyl acrylate that account for 20% of each weight in the formula, sodium lauryl sulfate and ten Add sodium dialkylbenzene sulfonate, initiator, and deionized water into the reactor, increase the temperature to 80°C, and keep it for 30 minutes;

[0102] S200. Prepar...

Embodiment 3

[0109] The formula used to prepare PE protective film glue is as follows:

[0110] Butyl acrylate (BA) 55

[0111] Methyl methacrylate (MMA) 25

[0112] Methyl acrylate (MA) 30

[0113] Acrylic (AA) 15

[0114] Hydroxyethyl acrylate (HEA) 23

[0115] Isooctyl acrylate (EHA) 130

[0116] Polyoxyethylene octyl phenyl ether (OP-10) 0.5

[0117] Sodium Lauryl Sulfate (SLS-046) 1.5

[0118] Sodium dodecylbenzene sulfonate 1.5

[0119] Deionized water 300

[0120] Ammonium persulfate 0.6

[0121] Polyisocyanates 1.

[0122] The preparation method is as follows:

[0123] S100. Preparation of seed emulsion: butyl acrylate, methyl methacrylate, methyl acrylate, and isooctyl acrylate that account for 20% of each weight in the formula, and sodium lauryl sulfate and ten Add sodium dialkylbenzene sulfonate, initiator, and deionized water into the reactor, raise the temperature to 80°C, and keep it for 25 minutes;

[0124] S200. Prep...

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Abstract

The invention discloses PE (polyurethane) protective film glue and a preparation method thereof. The PE protective film glue consists of the following components in parts by weight: monomers: 20-60 parts of butyl acrylate, 25-45 parts of methyl methacrylate, 12-32 parts of methyl acrylate, 5-15 parts of acrylic acid, 10-24 parts of hydroxyethyl acrylate, 120-140 parts of enthyl hexyl acrylate; emulsifying agents: 0.5-1.5 parts of polyoxyethylene octyl phenyl ether, 0.5-1.5 parts of sodium dodecyl sulphate, 0.5-1.5 parts of sodium dodecyl benzene sulfonate; a solvent: 280-350 parts of deionized water; and an initiating agent: 0.6-1.5 parts of ammonium persulfate. The PE protective film glue provided by the invention is the water-based adhesive and has the advantages of environment friendliness, no pollution, strong adhesive force and adhesive strength, and short drying time. A PE protective film coated with the PE protective film glue provided by the invention can be used for a vehicleprotective film, the protective films of all home appliances and so on. The effects of non-degumming and no residue glue can be realized.

Description

Technical field [0001] The invention relates to the field of chemistry and chemical engineering, in particular to a PE protective film glue and a preparation method thereof. Background technique [0002] Protective film is a film-like material with protective function on the surface of other materials. It is mainly made of polyolefin film as substrate, rubber or acrylate polymer as adhesive, and processed by coating and drying methods. The product is mainly used for surface protection of various products with high requirements on surface conditions, such as car protective film, protective film for all home appliances, etc., to prevent surface scratches, pollution and wear during handling, processing, storage and installation. Etc., so as to keep the good appearance of the article, and improve the grade and yield of the product, so the market for protective film is very huge. [0003] The biggest feature of the protective film, especially the surface protective film for outdoor use...

Claims

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Application Information

Patent Timeline
05 Oct 2011
Publication
CN102206476A
IPC
C09J133/12; C09J133/08; C09J7/02; C08F220/18; C08F220/14; C08F220/28; C08F2/30; C08F2/26
Inventors
黄伟