The invention relates to the technical field of laminated photovoltaic modules, in particular to a four-junction
perovskite-
perovskite-
perovskite-
crystalline silicon laminated photovoltaic module and a preparation method thereof.The photovoltaic module comprises a first junction perovskite sub-
cell layer, a second junction perovskite sub-
cell layer, a third junction perovskite sub-
cell layer and a fourth junction
crystalline silicon bottom
cell layer; the first perovskite sub-
cell layer and the second perovskite sub-
cell layer form perovskite / perovskite laminated cell photovoltaic glass, and the third perovskite sub-cell layer and the fourth
crystalline silicon bottom cell form a perovskite / crystalline
silicon laminated
solar cell piece; according to the four-junction structure, solar
radiation energy is utilized to the maximum extent by absorbing
ultraviolet-visible-
infrared full spectrums in a graded mode, the theoretical
photoelectric conversion efficiency can exceed 50%, and the efficiency ceiling of a traditional photovoltaic module is broken through; a precise
band gap matching design is adopted, three
layers of perovskite respectively cover
ultraviolet-visible-near
infrared bands, and a
narrow band gap crystalline
silicon bottom cell efficiently absorbs
infrared light, so that
photon energy waste is thoroughly reduced, and the problem of insufficient spectrum utilization of a traditional double-junction
assembly is solved.