The invention discloses a low-emission long glass fiber reinforced polypropylene composite and a preparation method thereof. The low-emission long glass fiber reinforced polypropylene composite is concretely prepared from the following raw materials in percentage by weight: 28-88 percent of polypropylene, 10-60 percent of long glass fiber, 0.2-2 percent of an anionic layered compound, 1-6 percent of a compatibilizer, 0.2-2 percent of a heat stabilizer and 0.1-2 percent of a processing aid. Compared with prior art, according to the low-emission long glass fiber reinforced polypropylene composite disclosed by the invention, as the anionic layered compound is added in the raw material formula, on one hand, low-molecular volatiles generated during polypropylene composite processing can be adsorbed, acidic groups can also be fixed, degradation of the polypropylene is delayed, and the generation of the low-molecular volatile is reduced; on the other hand, the anionic layered compound and an antioxygen can have the synergistic effect, so that the heat-oxygen age stability time of a long glass fiber reinforced polypropylene material is prolonged; the preparation method is simple in method, safe in operation and uniform in dispersion of alkali-free continuous long glass fibers in the polypropylene and is capable of effectively preventing a glass fiber bundle from occurring on the surface of an injection product and greatly improving the quality of the polypropylene composite.