The invention provides two
fluorene-benzothiadiazole multi-
chain type bola
liquid crystal compounds, a preparation method thereof and application of the
fluorene-benzothiadiazole multi-
chain type bola
liquid crystal compounds in solar cells. Relates to the fields of
liquid crystal materials and organic solar cells. The two types of molecules contain
bifunctional functional groups of
fluorene and benzothiadiazole at the same time, and can be self-assembled to form complex
honeycomb columnar phase and cubic phase liquid crystals by adjusting the lengths of conjugated linking groups and
alkyl side chains. Fn of a short
side chain forms a triangular
honeycomb hexagonal columnar liquid
crystal (Cohex / p6mm), F18 of a long
side chain observes a network cubic intermediate phase Cub / pm3n in a high-temperature interval, and the F18 of the long
side chain is a Cohex / p6mm liquid
crystal phase at a low temperature. The TFn of the short side chain can also form a Cohex / p6mm liquid
crystal phase, the TF18 of the long side chain can form a square
honeycomb columnar liquid crystal Colsq / P4gm at a low temperature, and the Cohex / p6mm liquid crystal is formed at a high temperature. In addition, the PEDOT: PSS thin film is induced to be modified by utilizing the self-
assembly property of the compounds Fn and TFn, and a PEDOT: PSS / n-Si
heterojunction solar cell device with high efficiency and strong practicability is prepared. The material is expected to be widely applied in the field of organic photoelectric materials.