The present application relates to the technical field of
cathode interface materials, in particular to a non-conjugated
acceptor-
acceptor type
pyrene diimide polymer, a preparation method thereof, a
cathode interface material and a
semiconductor device. The non-conjugated
acceptor-acceptor type
pyrene diimide polymer comprises a
pyrene diimide unit and a conjugated acceptor unit polymerized with the pyrene diimide in a non-conjugated manner, and the conjugated acceptor unit is selected from the pyrene diimide unit or other
electron-deficient acceptor units; the
ultraviolet-visible light absorption range of the other
electron-deficient acceptor units is 250-650 nm. When the non-conjugated acceptor-acceptor type pyrene diimide
polymer is used as a
cathode interface material, it not only has a lower LUMO level, but also increases the
ultraviolet-visible light absorption range, thereby widening the light absorption range of the
solar cell device and improving the short-circuit
current density of the
solar cell device.