The invention relates to solar cell positive silver paste suitable for high-temperature sintering. The paste comprises, by weight, 70-90% of silver powder, 1-3% of glass powder, 5-15% of solvent, 3-10% of organic binding agents and 0.01-2% of sintering accelerant, wherein the silver powder is of a spherical shape, the particle size of the silver powder is not larger than 5 micrometers, and the preference particle size of the silver powder is 1-3 micrometers. Compared with the prior art, an elementary substance containing rhodium or ruthenium or iridium or compounds containing rhodium or ruthenium or iridium serve as the sintering accelerant, the sintering accelerant can effectively restrain excessive sintering of the silver powder at a high temperature, crystalline of silver is prevented from being diffused to a junction area, generation of branch junctions is prevented, and the rate of finished products of battery pieces is increased. The sintering temperature of the paste is 800-900 DEG C, taking the 15 micrometers sintering thickness as an example, electric conductivity of the positive silver paste is 2m*omega/sq, the positive silver paste has excellent weldability, and adhesive force between a (2*2mm<2>) silver layer and a silicon substrate can reach more than 3N.