4 results about "Diethyldithiocarbamic Acid" patented technology

This invention discloses a semi-sandwich structured ruthenium triphenylphosphine dithiocarboxylic acid complex with a simple preparation process and its applications. The complex has the structure shown in Figure (I), with the central ruthenium and... η 5 - Coordination with cyclopentadiene, triphenylphosphine, and dithiocarboxylic acid derivatives, wherein the dithiocarboxylic acid ligands are selected from ethyl xanthic acid, isopropyl xanthic acid, ... N,N Diethyldithiocarbamic acid, morpholine dithiocarbamic acid, and carbazole dithiocarbamic acid. This invention employs a simple one-step method of room temperature preparation and recrystallization purification using a ruthenium precursor and dithiocarbamic acid ligand. This method offers advantages such as readily available raw materials, mild reaction conditions, simple post-processing, and high yield. In vitro tests show that the complexes exhibit excellent anti-proliferative activity against non-small cell lung cancer A549 cells, significantly superior to cisplatin. The complexes demonstrate activity by reducing mitochondrial membrane potential, inducing intracellular reactive oxygen species accumulation, and arresting the cell cycle (G1 phase), leading to late apoptosis in A549 cells.

The invention belongs to the field of rubber materials, and particularly relates to a durable high-resilience rubber composite material and a preparation method thereof. The rubber composite material provided by the invention is prepared from the following raw materials: natural rubber, high trans-1, 4-butadiene-isoprene copolymer rubber, high butadiene rubber, epoxy natural rubber grafted lignosulfonate, tetrapod-like zinc oxide whiskers, nano spherical zinc oxide, stearic acid, an anti-aging agent, a flame retardant, a vulcanizing agent, a first accelerant and a second accelerant. The first accelerant is selected from sulfoxide diethyldithiocarbamate, sulfoxide dibenzyl dithiocarbamate, sulfone dithiocarbamate and sulfone dibenzyl dithiocarbamate, and the second accelerant is selected from sulfoxide diethyldithiocarbamate, sulfoxide dibenzyl dithiocarbamate, sulfone dithiocarbamate and sulfone dibenzyl dithiocarbamate; the second accelerant is 4, 4 '-dithio-dimorpholine, 2-morpholinyl dithio-benzothiazole, N-oxydiethylene-2-benzothiazole sulfenamide, and dibenzoyl morpholine. The invention further discloses a preparation method of the flame-retardant flame-retardant flame-retardant flame-retardant flame-retardant flame-retardant flame-retardant flame-retardant flame-retardant flame-retardant flame-retardant flame-retardant flame-retardant flame-retardant flame retardant. The rubber composite material provided by the invention has excellent high resilience and use durability.

The invention belongs to the technical field of biological medicine and tumor diagnosis and treatment, and particularly relates to manganese diethyldithiocarbamate loaded nanoparticles and a pharmaceutical composition. The nanoparticles loaded with the manganese diethyldithiocarbamate are prepared from an amphiphilic polymer and diethyldithiocarbamate according to the mass ratio of (0.25 to 4) to 1; the manganese diethyldithiocarbamate accounts for more than 50% of the molar mass of the diethyldithiocarbamate; the amphiphilic polymer is one or more of DSPE (Distearoyl Polyethylene)-PEG (Polyethylene Glycol), DSPE-PEG-folic acid, DSPE-PEG-phenylboronic acid and DSPE-PEG-arginyl glycyl aspartic peptide. According to the application, the amphiphilic polymer of the DSPE-PEG and the derivative of the DSPE-PEG and the ethyl dithiocarbamate are adopted to form the nano-particles, and hydrophobic manganese ethyl dithiocarbamate can be wrapped in a hydrophobic micro-area.

The invention discloses a positive electrode electrolyte suitable for a lithium-selenium battery, application of the positive electrode electrolyte and the lithium-selenium battery, and belongs to the field of lithium-selenium batteries. The positive electrode electrolyte comprises a basic electrolyte and organic molecules, wherein the organic molecules are 2-benzothiazole diethyldithiocarbamate, and the concentration of the organic molecules is 0.1 mol / L to 3 mol / L. According to the preparation method disclosed by the invention, organized molecules and Li2Sen generated in a selenium positive electrode discharging process are subjected to nucleophilic reaction, so that selenium is grafted to an organic framework to realize organification, and a shuttle effect of Li2Sen is avoided from the source; meanwhile, an organized product is a good lithium ion conductor, lithium ions can be quickly transferred, and stable circulation of the battery at higher magnification is realized; besides, the organized product has higher discharge voltage, the energy density of the battery is also improved, and the lithium-selenium battery which has high energy density, can be quickly charged and discharged and has excellent cycling stability is finally realized, so that the lithium-selenium battery has a wide application prospect.