30 results about "Dodecylmercaptan" patented technology

The application belongs to the technical field of lithium ion battery adhesives, and particularly relates to a hyperbranched network polyacrylic acid resin special for silicon-carbon negative electrodes, a preparation method and application thereof. The hyperbranched network polyacrylic acid resin special for silicon-carbon negative electrodes comprises, by mass fraction, 3-10 parts of water-based acrylic acid resin, 4-10 parts of monomer A, 2-6 parts of monomer B, 2-6 parts of monomer C, 60-80 parts of solvent, 0.1-0.2 parts of chain extender, 1-8 parts of crosslinking agent and 0.5-1 part of silane coupling agent. The monomer A is an acrylic ester monomer, the monomer B is an acrylamide monomer, the monomer C is at least one selected from an allyl amine monomer and an acrylonitrile monomer, and the chain extender is at least one selected from dodecyl mercaptan and 2-mercaptoethanol. The polyacrylic acid resin has high viscosity and peeling strength, and the prepared lithium ion battery negative electrode material has high discharge specific capacity and cycle performance.

The invention relates to an electroplated coating protective agent and a preparation method thereof, and belongs to the technical field of electroplated coating protective agents, and the protective agent comprises the following raw materials: main salt, auxiliary salt, a composite complexing agent, 1-docosanethiol, a sealing agent, absolute ethyl alcohol and deionized water. The succinic acid, the N-sodium lauroyl sarcosinate and the citrazinic acid are used as the composite complexing agent, and starting from different aspects of activating the surface of the coating, accelerating the growth of the protective film layer and increasing the compactness of the protective film layer, the prepared protective agent can effectively improve the corrosion resistance effect of the coating; and the added 1-docosanethiol is used for reducing the defect area of the protective film layer and further effectively improving the corrosion resistance of the protective film. Besides, chromic nitrate is used as a main salt, cerous sulfate and sodium molybdate are used as auxiliary salts, and sodium silicate is used as a sealing agent, so that the prepared protective agent can effectively have remarkable salt spray resistance, and meanwhile, the appearance quality of a formed film layer can also be improved.

The invention discloses a method for improving the selectivity of electrocatalytically reducing acetylene into 1, 3-butadiene by using a copper hydroxide hydrophobic nano array, which comprises the following steps: soaking a copper mesh in a mixed solution of NaOH and (NH4) 2S2O8 to obtain a Cu (OH) 2 self-supporting nano array, and then soaking in an ethanol solution of 1-dodecyl mercaptan to obtain a Cu (OH) 2 hydrophobic self-supporting nano array modified by 1-dodecyl mercaptan. A hot press is adopted to tightly press the dried hydrophobic self-supporting nano array and carbon paper to form a working electrode, a cathode chamber and an anode chamber are separated through an anion exchange membrane, electrolyte is composed of a KOH solution, and a peristaltic pump is used to enable a liquid phase to continuously circulate. According to the method, acetylene is subjected to electrocatalytic reduction to obtain 1, 3-butadiene by adopting a three-electrode system, and high-selectivity conversion of acetylene into 1, 3-butadiene is realized.

The present invention relates to the field of quantum dot reflective film technology, disclosing a high-stability quantum dot reflective film for display and its preparation method. The film comprises a three-layer structure, A / B / A. The raw materials for layer A include a matrix resin and an antistatic agent; the raw materials for layer B include a matrix resin and fluorescent quantum dot composite microspheres. The fluorescent quantum dot composite microspheres comprise fluorescent quantum dots whose surfaces have been passivated with tert-dodecyl mercaptan and a cycloolefin polymer coating the surfaces. The method first passivates surface defects of the fluorescent quantum dot material with alkyl mercaptan, then uses a cycloolefin polymer as a secondary shell material. The composite particles are mixed with the matrix resin. The resulting quantum dot reflective film exhibits high fluorescence efficiency and wide color gamut display capabilities, while also exhibiting superhydrophobicity and anti-oxidative chemical stability.

The present invention relates to a process for the production of specialty mercaptans from C4 oligomerization product. The oligomer product from the commercial C4 oligomerization process is separated in desired fractions of C8 and C12 olefins and these streams are further used as feed stock for the production of the specialty mercaptans such as tert octyl mercaptan (TOM) & tert dodecyl mercaptan (TDM). These fractionated oligomer stream (C8 and C12) from the C4 oligomerization process reacts with hydrogen sulfide in presence of pretreated cation exchange resin catalyst using appropriate inhibitors such as amine precursors, nitriles and metals to produce respective sulfur compounds tert-octyl mercaptan (TOM) and tert dodecyl mercaptan (TDM).

Discloses an aqueous antimicrobial coating composition comprising: (A) a polymer obtained by a multistage polymerisation and composed of: 75% to 95% of a first-stage polymer and from 5% to 25% of a second-stage polymer; wherein the first-stage polymer comprises: monoethylenically unsaturated functional monomers carrying at least one functional group selected from a carboxyl, carboxylic anhydride, sulfonic acid, amide, sulfonate, phosphoric acid, phosphonate, phosphate, or hydroxyl group (e.g. acrylic acid, acrylamide); <1.0% of a monomers bearing imidazole, benzotriazole, or benzimidazole; and monoethylenically unsaturated nonionic monomers (e.g. alkyl acrylate); wherein the second-stage polymer has MW=8000 to 30000 g / mol and comprises: residues of C6-C24 alkyl thiol (e.g. dodecyl mercaptan); monomers bearing imidazole, benzotriazole, or benzimidazole (e.g. vinyl imidazole); and monomers of alkyl acrylate; wherein the monomers bearing imidazole, benzotriazole, or benzimidazole in a multistage polymer are present at a total concentration of 0.5% to 8%; and (B) 1 to 10000 ppm of a silver, wherein the mol ratio of monomers bearing imidazole, benzotriazole, or benzimidazole to silver is greater than 4; and (C) <500 ppm of coagulum (coagulates having diameter>44 micrometers); and a method of preparing such aqueous antimicrobial composition and a coating composition comprising such aqueous antimicrobial composition and a pigment.

The invention discloses a foaming agent as well as a preparation method and application thereof, and belongs to the technical field of mineral separation. The foaming agent comprises the following raw materials in percentage by mass: 80%-96% of No.2 oil and 1%-22% of lauryl mercaptan. The foaming agent is prepared by the following steps: compounding and modifying No.2 oil, and uniformly mixing the No.2 oil with lauryl mercaptan according to a certain mass ratio, so as to obtain modified No.2 oil; the modified foaming agent not only has the characteristics of good foam brittleness and good flowability, but also can strengthen a collecting agent for sulphide ore, and can achieve the purpose of improving the concentrate grade and the recovery rate at the same time.

The invention discloses a high-efficiency comprehensive recovery and smelting method for low-grade tungsten-molybdenum ore, which belongs to the field of tungsten-molybdenum metallurgy technology, including: grinding the ore to 40-80% of -0.074mm, making a 30-50% concentration slurry; adding sodium carbonate to adjust the pH to 8-10, using dodecyl mercaptan and oleic acid mixed flotation to obtain a tungsten-molybdenum mixed concentrate; passing the concentrate slurry through oxygen pressure oxidation at 120-150°C and 0.5-2.0MPa for 1-5h; filtering the filtrate and extracting and separating it to obtain ammonium molybdate and ammonium tungstate products. This method effectively solves the technical problems of low flotation recovery of tungsten-molybdenum ore, difficulty in obtaining tungsten and molybdenum concentrate products by flotation, and large amounts of tungsten and molybdenum resources being wasted or unable to be effectively developed.

The application relates to the technical field of ABS packaging bottles, and more specifically to an ultraviolet-resistant ABS material, a preparation method thereof and a packaging bottle. An ultraviolet-resistant ABS material comprises the following raw materials in parts by weight: 50-80 parts of styrene, 14-26 parts of acrylonitrile, 12-18 parts of a benzotriazole ultraviolet-resistant absorber, 8-14 parts of butadiene, 0.1-0.9 parts of benzoyl peroxide, 0.1-0.5 parts of tertiary dodecyl mercaptan and 40-60 parts of toluene; the benzotriazole ultraviolet-resistant absorber comprises the following raw materials in mole: 1-3 parts of hydroxyethyl methacrylate, 2-4 parts of toluene-3,5-diisocyanate and 1-3 parts of a polyhydroxy-containing ultraviolet-resistant absorber. The ultraviolet-resistant ABS material has excellent ultraviolet-resistant performance and migration resistance.

The application provides a catalyst for synthesizing tertiary dodecyl mercaptan from triisobutene, a preparation method and use thereof. The method comprises the following steps: preparing a silicon source mixed solution A, preparing a gallium source mixed solution B, and preparing a structure directing agent mixed solution C; adding A into C, stirring, and then adding B to obtain a sol-like substance; adding a cerium source and / or a lanthanum source and an alkyl polyamine solution, stirring to obtain a mixed solution D, and continuously stirring to obtain a powder after drying; and calcining the powder to obtain a unit point rare earth regulated Si-Ga nanomaterial. The catalyst has excellent activity and super-long stability (more than 800 h) in a reaction for synthesizing tertiary dodecyl mercaptan from triisobutene as a raw material, and can be used for industrial production.

The invention discloses a modified polystyrene material, a preparation method and a light diffusion plate using the modified polystyrene material, relates to the technical field of light diffusion plate materials, and belongs to the patent publication number C08L53 / 02. The preparation method of the modified polystyrene material comprises the following steps: mixing a styrene monomer, an alpha-methyl styrene monomer, vinyl functionalized cage type silsesquioxane, benzoyl peroxide and lauryl mercaptan, and carrying out polymerization reaction under the protection of nitrogen to obtain a polystyrene prepolymer; the preparation method comprises the following steps: dispersing lamellar zirconium phosphate nanosheets in absolute ethyl alcohol, adding gamma-(methacryloyloxy) propyltrimethoxysilane and glacial acetic acid, and performing reflux reaction to obtain coupling agent modified zirconium phosphate nanosheets; crushing the polystyrene prepolymer, premixing with the coupling agent modified zirconium phosphate nanosheets, the antioxidant and the lubricant at a high speed, drying, feeding into a double-screw extruder for melt blending, extruding, cooling, pelletizing and drying to obtain the modified polystyrene material. The modified polystyrene material prepared by the invention has excellent heat resistance.

The invention belongs to the technical field of lubricants, and discloses a lubricant containing Guerbet alcohol derivatives and a preparation method and application thereof. The lubricant is prepared from the following components in parts by weight: 2 to 6 parts of Guerbet alcohol derivative, 0.2 to 1 part of sulfurized isobutylene, 0.05 to 0.3 part of tungsten disulfide nanosheet, 0.01 to 0.1 part of surface modified fullerene, 0.5 to 1.5 parts of triisopropanolamine borate, 80 to 95 parts of 2-octyl-dodecyl cyclopentane, 0.3 to 0.8 part of antioxidant and 0.1 to 0.5 part of antirust agent. The Guerbet alcohol derivative is an ester derivative of Guerbet alcohol; the surface modified fullerene is obtained by modifying fullerene by using dodecyl mercaptan and azodiisobutyronitrile. When ester synthesized from isostearyl alcohol is used as an ester derivative of Guerbet alcohol, the lubricant still has good lubricating performance. Furthermore, the high-temperature-resistant and high-pressure-resistant oxidation performance is good.

The application discloses an environment-friendly copper-gallium-chalcogenide zinc sulfide core-shell quantum dot as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing a gallium source, a copper source, oleylamine and 1-dodecyl mercaptan, heating, degassing in a nitrogen environment, adding a sulfur precursor solution, reacting, obtaining a quantum dot solution, heating the quantum dot solution, adding a zinc acetate precursor solution dropwise and stirring to react, continuously heating, adding a zinc stearate precursor solution dropwise and stirring to react, water quenching after the reaction, purifying, and obtaining a copper-gallium-chalcogenide zinc sulfide core-shell quantum dot. The copper-gallium-chalcogenide zinc sulfide core-shell quantum dot material prepared by the method of the application does not add toxic heavy metal materials, is harmless to human bodies and the environment, and has the advantage of high light condensation efficiency, and can effectively solve the problems of existing quantum dot materials.

The invention provides a high-adsorption and high-conductivity gold coating for a PI substrate and a preparation method of the high-adsorption and high-conductivity gold coating, and belongs to the technical field of electronic functional materials. The preparation method comprises the following steps: synthesizing tert-dodecylmercaptan gold, and mixing the tert-dodecylmercaptan gold with a first organic solvent to obtain an organic gold coating; and the pretreated PI substrate is coated with the organic gold coating and annealed, and the gold coating is obtained. According to the method, mercaptan molecules are effectively used as a bifunctional bridge to cooperatively create an organic-inorganic hybrid interface with high bonding strength and good stability, the inherent defect of poor adhesion of a pure gold coating is overcome, the sheet resistance of the prepared gold coating is lower than 0.3 omega / sq, the adhesion reaches the 5B level, the resistance is not obviously changed in an environmental adaptability test, the adhesion is still the 5B level, and the prepared gold coating has a good application prospect. And high conductivity, strong substrate adhesion and excellent environmental stability of the gold coating are realized.

The invention discloses an electrode material for a hydrogen production electrolytic cell and a preparation method thereof, and relates to the technical field of hydrogen production, and the preparation method comprises the following steps: uniformly mixing and stirring nickel salt, ferroferric oxide, ethylene glycol and lauryl mercaptan; adding ammonia water, uniformly mixing, carrying out hydrothermal reaction, washing and drying to obtain nickel / ferroferric oxide; the preparation method comprises the following steps: adding nickel / ferroferric oxide and a binder into a solvent, stirring for 4-6 hours, and carrying out spray drying to obtain modified nickel / ferroferric oxide; and carrying out heat treatment on the modified nickel / ferroferric oxide in an inert atmosphere to obtain the electrode material. The prepared electrode material has high activity, and the hydrogen production efficiency is effectively improved.

The invention belongs to the technical field of solar cells, and particularly relates to a perovskite solar cell with N-dodecyl mercaptan-copper clusters cooperatively implanted into a perovskite layer and a hole transport layer, and the perovskite solar cell is characterized in that an N-dodecyl mercaptan-copper cluster colloidal solution is prepared by adopting a liquid-phase pulse laser irradiation technology; the passivated perovskite solar cell is prepared through the steps of preparing a perovskite substrate, taking n-dodecyl mercaptan-copper clusters as a co-doped additive, simultaneously implanting a perovskite layer and a hole transport layer, sequentially depositing an electron transport layer, spin-coating the perovskite layer and the hole transport layer, and finally, evaporating a metal electrode to obtain the passivated perovskite solar cell. The n-dodecyl mercaptan-copper cluster is implanted into the perovskite layer and the hole transport layer at the same time, a defect passivation and charge transfer channel is constructed, the energy levels of the perovskite layer and the hole transport layer are improved, the hole mobility is effectively improved, extraction and transport of hole carriers are promoted, and the high-efficiency passivated perovskite solar cell is obtained. The implantation mode is convenient, and the preparation process is simple.

This invention discloses a method for preparing an ultrathin zinc indium sulfide / zinc selenide heterojunction photocatalyst: Step 1, a certain amount of ZnCl2, InCl3·4H2O and oleylamine are mixed and subjected to a first deoxygenation treatment. A mixed solution of 1-dodecanethiol and tert-dodecylmercaptan is rapidly injected under nitrogen conditions and reacted at a certain temperature for a certain time to obtain ultrathin zinc indium sulfide nanosheets. After centrifugation and washing, the nanosheets are redissolved in a certain amount of n-hexane. Step 2, zincacetate, oleic acid and 1-octadecene are mixed and subjected to a second deoxygenation treatment. The mixture is then heated to a certain temperature under nitrogen conditions, reacted for a certain time, and cooled. A certain amount of the solution obtained in step S1 is rapidly injected and subjected to a third deoxygenation treatment. The mixture is then heated under nitrogen conditions, and a certain amount of a mixed solution of Se and TOP is slowly injected at a certain rate. The mixture is then kept at a certain temperature and reacted for a certain time. After the injection process is completed, the reaction is allowed to continue. Finally, the solution is cooled to room temperature and centrifuged to obtain ZIS / ZnSeHNSs.

The invention discloses a catalyst for synthesizing tert-dodecyl mercaptan as well as a preparation method and application of the catalyst, and relates to the technical field of tert-dodecyl mercaptan. According to the technical scheme, the preparation method comprises the following steps: S1, adding an aromatic hydrocarbon additive into a reaction kettle, adding anhydrous aluminum chloride and ferric chloride in batches while stirring, and uniformly mixing; s2, the reaction kettle is sealed with nitrogen, anisole or anisole homologues are dropwise added under the condition of temperature-controlled stirring for 0.5-1 h, after dropwise adding is completed, the temperature-controlled stirring reaction continues under the condition of nitrogen sealing for 0.1-0.5 h, the temperature is recovered to the room temperature, and the catalyst for tert-dodecyl mercaptan synthesis is obtained. According to the present invention, the catalyst can be prepared under the mild condition, the selectivity is more than 95% when the catalyst is used for synthesizing the tert-dodecyl mercaptan, and the synthesized tert-dodecyl mercaptan product is suitable for the high molecular polymerization process of ABS, SBR, butyronitrile latex and other products.

The application relates to the chemical technology field and discloses a kind of tert-dodecyl mercaptan reaction liquid separation methods.The separation method is by using specific sulfonyl substance as extractant, with the tert-dodecyl mercaptan reaction liquid to be separated together in extractive rectification column to carry out extractive rectification, so that high-purity tetramer propylene can be obtained at the top of the extractive rectification column;The extractive rectification column kettle liquid is rectified and separated, and high-purity tert-dodecyl mercaptan can be obtained.

The application discloses a modified polystyrene material, a preparation method and application of a light diffusion plate, relates to the technical field of light diffusion plate materials, and belongs to the patent publication C08L53 / 02. The preparation method of the modified polystyrene material comprises the following steps: mixing styrene monomers, alpha-methyl styrene monomers, a vinyl-functionalized cage silsesquioxane, benzoyl peroxide and dodecyl mercaptan, performing a polymerization reaction under nitrogen protection to obtain a polystyrene prepolymer; dispersing zirconium phosphate nanosheets in anhydrous ethanol, adding gamma-(methacryloyloxy) propyl trimethoxysilane and glacial acetic acid, and performing a reflux reaction to obtain zirconium phosphate nanosheets modified by a coupling agent; crushing the polystyrene prepolymer, pre-mixing the polystyrene prepolymer with the zirconium phosphate nanosheets modified by the coupling agent, an antioxidant and a lubricant at a high speed, drying the mixture, feeding the mixture into a double-screw extruder for melt blending, extruding, cooling, cutting and drying, and thus obtaining the modified polystyrene material. The prepared modified polystyrene material has excellent heat resistance.

The invention belongs to the field of RAFT reagent synthesis, and particularly relates to a preparation method of a reversible addition fragmentation chain transfer reagent. Comprising the following steps: by taking dodecyl mercaptan as a starting raw material, generating thiolate under the action of alkali; and reacting the obtained thiolate with carbon disulfide (CS2) to generate trithiocarbonate. And reacting the obtained trithiocarbonate with trichloromethane and acetone under the catalysis of alkali, and finally acidifying to obtain 2-[dodecyl sulfenyl (thiocarbonyl) sulfenyl]-2-methyl propionic acid, namely the RAFT reagent. Tetrabutylammonium bromide is specifically selected as a phase transfer catalyst, and the catalyst system provided by the invention can realize higher product yield.

The invention discloses a production method of seed glue for styrene-butadiene latex, and relates to the technical field of preparation of seed glue, and the production method comprises the following steps: preparing a monomer mixture, a premix mixture, an emulsifier mixture and an initiator mixture according to a formula proportion; transferring the prepared backing material into a reaction kettle, introducing nitrogen into the reaction kettle for 5 minutes to replace air, keeping an emptying valve to be opened, and starting a stirrer; opening a steam valve at the bottom of the reaction kettle and a jacket steam valve, synchronously heating until the kettle temperature and the jacket water temperature reach 84 + / -1 DEG C, and simultaneously finishing the preparation of an ammonium persulfate solution; dropwise adding styrene, manually controlling dropwise adding of dodecyl mercaptan, and continuously polymerizing for 3 hours; and after the monomer is dropwise added, preserving heat, cooling, replenishing the defoaming agent, sampling, detecting to be qualified, and transferring to obtain the seed glue for styrene-butadiene. By optimizing the formula proportion of the styrene, the surfactant, the sodium bicarbonate, the ammonium persulfate and the lauryl mercaptan required by synthesis and related process conditions, the energy consumption is reduced, the cost is reduced, and the effect is improved.

The invention belongs to the technical field of chemical separation, and discloses a reduced pressure rectification system and a tert-dodecyl mercaptan reduced pressure azeotropic rectification method. The system consists of a separation unit, a condensation recovery unit, a vacuum control unit and a tail gas absorption unit, the separation unit comprises a heater, a rectifying still and a built-in rectifying packed column; the condensation recovery unit comprises a flow divider, a condenser, a collection tank and a non-condensable gas absorption tank; the vacuum control unit is connected with a vacuum pump through a buffer tank; the tail gas absorption unit comprises two stages of liquid caustic soda absorption tanks; the rectification method comprises the following steps: a TDM multistage rectification purification step: adding an entrainer into a crude product system containing tetra-polypropylene and TDM, and passing through the crude product system; and carrying out multi-stage reduced pressure rectification on the tower bottom product, and purifying TDM stage by stage. The vacuum distillation system is simple in structure, the TDM heat sensitivity risk is effectively reduced by combining vacuum distillation with azeotropic distillation, and environment-friendly treatment is achieved through two-stage tail gas absorption. And finally obtaining a high-purity TDM product of which the purity is greater than or equal to 98.5 wt% and the carbon number (C11-C13 is greater than or equal to 85 wt%).

The invention provides a solution for implanting n-dodecyl mercaptan gold nanoclusters into a hole transport layer, and a preparation method and application of the solution, and relates to the technical field of solar cells. Comprising the steps that a metal target material is placed in a mixed solution composed of n-dodecyl mercaptan and acetonitrile, liquid-phase pulse laser irradiates the metal target material, the metal target material is taken out, and an n-dodecyl mercaptan gold nano-cluster colloidal solution is obtained; and uniformly mixing the n-dodecyl mercaptan gold nano-cluster colloidal solution with the hole transport layer solution to obtain the n-dodecyl mercaptan gold nano-cluster implanted hole transport layer solution. The gold nanocluster is used as a core and has high conductivity, the conductivity of the hole transport layer can be effectively improved by nanocrystallizing the gold nanocluster and implanting the gold nanocluster into the hole transport layer, and meanwhile, the energy level structure of the hole transport layer is improved, so that separation and extraction of photon-generated carriers are promoted, charge transport is improved, and the electrical property of the hole transport layer is improved.

The present invention provides a Ni9S8@Au core-shell nanocrystal and a preparation method thereof. The Ni9S8@Au core-shell nanocrystal includes a core and a shell wrapped around the core, wherein the core is Ni9S8 and the shell is Au. The preparation method comprises the following steps: mixing nickel diethyldithiocarbamate with oleylamine, 1-octadecene, and 1-dodecylmercaptan to form a uniform solution; heating the uniform solution to a reaction temperature under a protective atmosphere, reacting to obtain a reaction solution; adding a tri-n-octylphosphine solution of chloroauric acid to the reaction solution, and reacting at the reaction temperature; cooling the obtained reaction solution to room temperature, adding a mixture of a polar solvent and a non-polar solvent, separating a solid product, and drying to obtain the Ni9S8@Au core-shell nanocrystal. Due to the unique structure and potential properties of the Ni9S8@Au core-shell nanocrystal, it has a wide range of application potentials in the fields of catalysis, energy storage, and sensing.

The invention provides a high-molecular organic composite suspending agent and a preparation method thereof, and belongs to the technical field of high-molecular materials, and the suspending agent comprises a high-molecular copolymer, an S-PEGMA copolymer, a PNIPAM-Q-CNC composite microsphere suspension, a zirconium complex-silane coupling agent composite system and the like. The high-molecular copolymer is prepared by reacting components such as a PS-Br initiator, 2-acrylamide-2-methylpropanesulfonic acid and the like with cuprous bromide, pentamethyldiethylenetriamine and lauryl mercaptan. The S-PEGMA copolymer is prepared by reacting dipentaerythritol, methacrylic acid, p-toluenesulfonic acid, hydroquinone and the like and then reacting with polyethylene glycol methacrylate and azodiisobutyronitrile. The preparation method comprises the following steps: hydrolyzing microcrystalline cellulose, modifying with glycidyl trimethyl ammonium chloride to prepare Q-CNC, and reacting with N-isopropylacrylamide, N, N '-methylene bisacrylamide and ammonium persulfate to prepare a PNIPAM-Q-CNC composite microsphere suspension.

The invention relates to the technical field of preparation and separation of tert-dodecyl mercaptan, in particular to a separation method of tert-dodecyl mercaptan and tetra-polypropylene, and aims to improve the yield while improving the separation purity and reduce the energy consumption and investment cost. The invention relates to a method for separating tert-dodecyl mercaptan and tetra-polypropylene, which comprises the following steps: adding an entrainer into a first mixed solution containing the tert-dodecyl mercaptan and the tetra-polypropylene to carry out azeotropic distillation, and respectively collecting a first fraction containing the tetra-polypropylene and the entrainer and a first distillation residue containing the tert-dodecyl mercaptan; wherein the entrainer is prepared from one or more of C6-C12 saturated monohydric fatty alcohol, and the entrainer is prepared from one or more of C6-C12 saturated monohydric fatty alcohol.

The application belongs to the field of materials, and discloses a pH-responsive intelligent oil-water separation copper mesh and a preparation method thereof. The preparation method is as follows: the copper mesh is sequentially ultrasonically cleaned in ethanol and water and dried to remove oil stains and make the surface clean. The dried copper mesh is soaked in a silver nitrate solution for 1h-4h. After being taken out, the copper mesh is soaked in a dodecyl mercaptan and mercapto-undecanoic acid ethanol solution for 24h-48h, then the surface solution is washed clean with ethanol, and finally dried to obtain a pH-responsive intelligent oil-water separation copper mesh. The pH-responsive intelligent oil-water separation copper mesh can realize quick switching between hydrophilicity and hydrophobicity on the surface, selectively recover oil and water, and has strong reusability.

The invention provides application of sulfur and alkyl mercaptan as a composite regulator in preparation of chloroprene rubber from chloroprene monomers. The alkyl mercaptan comprises n-dodecyl mercaptan and / or tert-dodecyl mercaptan; the mass ratio of the sulfur to the alkyl mercaptan is (3-5): 1. The invention also provides a sulfur-mercaptan synergistic regulation mixed regulation type chloroprene rubber synthesis process without chain scission. According to the designed composite regulator system, improvement of processability by sulfur is reserved, branching is inhibited through thiol, PDI is controlled, a chain scission process is not needed, the Mooney viscosity fluctuation of the product prepared from the mixed regulation type CR is smaller than or equal to 5ML (1 + 4) 100 DEG C according to the proportion, and sudden reduction of viscosity is effectively avoided. According to the synthesis method provided by the invention, Mooney viscosity controllability, molecular weight uniformity and stability are considered, and the mixed regulating chloroprene rubber with narrow molecular weight distribution, controllable chain scission and long storage period is obtained.

The application discloses a method for improving the selectivity of electrocatalytic reduction of acetylene to 1,3-butadiene by using copper hydroxide hydrophobic nano array, and the copper net is soaked in a mixed solution of NaOH and (NH4)2S2O8 to obtain Cu(OH)2 self-supporting nano array, and then soaked in an ethanol solution of 1-dodecyl mercaptan to obtain 1-dodecyl mercaptan modified Cu(OH)2 hydrophobic self-supporting nano array. A dry hydrophobic self-supporting nano array is tightly pressed with carbon paper by using a hot press to serve as a working electrode, the cathode chamber and the anode chamber are separated by an anion exchange membrane, the electrolyte is composed of KOH solution, and a peristaltic pump is used to make the liquid phase continuously circulate. The application realizes the high selectivity conversion of acetylene to 1,3-butadiene by using a three-electrode system for electrocatalytic reduction of acetylene to 1,3-butadiene.