The invention belongs to the field of additive manufacturing, and discloses a 4D printing method of an intelligent structure with a large deformation function and a product. The method comprises the following steps that (a) a three-dimensional structure of the intelligent structure to be printed is constructed, wherein the intelligent structure to be printed is of a porous gradient network structure, and comprises three layers with the volume fractions of pores sequentially reduced from top to bottom in the vertical direction; (b) a three-dimensional model of the intelligent structure is set up; (c) memory alloy powder is selected as raw materials, and the 3D printing technology is adopted for printing the three-dimensional model; and (d) the printed intelligent structure is subjected to heat preservation, cooling and external field irrigation, the deforming intelligent structure is obtained and subjected to performance testing, and the needed intelligent structure is selected according to performance needs. By means of the 4D printing method, the obtained product responds to the changing external environment immediately, the expectant optimal state is kept all the time, meanwhile,the 4D printing method is not limited by the structure complexity, and the requirements of the mechanical property and the fatigue property are met.