8 results about "Thiobarbituric acid" patented technology

This invention discloses a microfluidic method for preparing fish oil microspheres based on viscosity control and its application, belonging to the field of functional food preparation technology. The method involves constructing three viscosity systems (3.47–15.19 mPa·s) by compounding concentrated fish oil and castor oil at a specific volume ratio. Using a 3% polyvinyl alcohol aqueous solution as the continuous phase, water-in-oil fish oil microspheres are prepared under constant pressure in a cross-shaped microfluidic chip. By controlling the viscosity of the oil phase, the microsphere particle size can be precisely controlled within the range of 53.89–72.34 μm, with a coefficient of variation ≤5% and regular morphology. The obtained microspheres exhibit excellent particle size stability under pH 5–7 and 0–2% NaCl conditions. The high-viscosity microspheres show significantly lower acid values ​​and thiobarbituric acid reactant values ​​compared to the low-viscosity group under storage conditions of 4–60℃, with an oxidation stability improvement of over 30%. In vitro digestion experiments show that the low-viscosity microspheres reach peak free fatty acid release rate after 120 min, while the high-viscosity group exhibits a sustained-release effect. This invention achieves simultaneous optimization of fish oil microsphere particle size, stability, and digestive behavior, providing a theoretical basis and precise process parameters for the structured design of ω-3 polyunsaturated fatty acid functional foods.

The invention provides a nitrite quantitative detection method based on surface enhanced Raman spectroscopy, relates to the technical field of surface enhanced Raman spectroscopy, and constructs a self-correcting SERS substrate through a three-phase liquid-liquid interface co-assembly technology. In the experiment process, a sample to be detected is mixed with a thiobarbituric acid solution, the mixture is adjusted to be acidic, NO2 <-> and thiobarbituric acid are subjected to an S-nitrosation reaction, and S-nitroso mercaptan is generated. And then, immersing the self-correcting SERS substrate into a reaction solution, so that the substrate adsorbs the generated S-nitroso mercaptan, and further, a Raman signal is enhanced. After soaking is completed, the substrate is taken out and dried, finally, a Raman signal is collected through a Raman spectrometer, and the concentration of NO2 <-> is accurately analyzed through the change of the signal intensity. According to the technical scheme, rapid and high-sensitivity detection of NO2 <-> is achieved, good selectivity and anti-interference capacity are achieved, and the method is widely suitable for detection requirements of multiple fields such as environment monitoring and food safety.

The application discloses an oil oxidation type time-temperature indicator, which comprises a sealed container which is partially or wholly transparent, vegetable oil and a thio-barbituric acid color developing agent which are packaged in the sealed container. The application mixes the vegetable oil and the thio-barbituric acid color developing agent to prepare an oxidation indicator, and the oxidation degree of food containing the same vegetable oil can be indicated by using the color developing reaction of the vegetable oil oxidation product and the thio-barbituric acid color developing agent, and the color change is irreversible. The oxidation indicator is packaged in the sealed container which is partially or wholly transparent, so that the oil oxidation indicator with small volume, convenient use and direct indication is prepared. The problem that the color change of the existing time-temperature indicator for food containing vegetable oil is not obvious or reversible is solved.

A dental ceramic blank comprising at least one organic compound, characterized in that the blank has an open-pore ceramic framework, wherein the open-pore ceramic framework is selected from an open-pore dental ceramic framework comprising zirconia, aluminum oxide, a mixed oxide comprising zirconia, and / or silicon carbide, wherein the open-pore ceramic framework contains 2 to 50 wt.% of at least one organic compound selected from a) comprising at least one polymerizable monomer and / or a mixture of polymerizable monomers, thermal initiators comprising peroxide and / or an azo compound or a redox system comprising a peroxide, and a reducing agent selected from ascorbic acid, an ascorbic acid derivative, barbituric acid or a barbituric acid derivative, sulfinic acid, a sulfinic acid derivative or a redox system (aa) barbituric acid or thiobarbituric acid or a barbituric acid or thiobarbituric acid derivative and (bb) at least one copper salt or copper complex and (cc) at least one compound with an ionic halogen atom, particularly preferably a redox system comprising 1-benzyl-5-phenylbarbituric acid, copper acetylacetonate and benzyldibutylammonium chloride, and / or b) a polymer of the aforementioned monomers polymerized in the blank with respect to the overall composition of the dental ceramic blank.

The invention provides a triploid rainbow trout refrigeration and fresh-keeping method by combining plant extracts with a low-temperature plasma technology, and belongs to the technical field of rainbow trout refrigeration and fresh-keeping. Hawthorn, pericarpium citri reticulatae and fried semen raphani are mixed according to the mass ratio of 2: 1: 2 to prepare a composite plant fresh-keeping agent; according to a sequence of soaking for 20 minutes with plasma activated water, soaking for 10 minutes with a composite plant preservative, and then carrying out dielectric barrier discharge treatment for 2 minutes, a flavonoid compound and organic acid are used for removing strong oxidizing substances generated by plasma treatment, and an anti-oxidation protection layer is formed; the soaking time of the composite plant preservative is dynamically adjusted according to the thiobarbituric acid value, and the technical problem that the preservation effect is reduced due to the fact that low-temperature plasma treatment accelerates lipid oxidation of the triploid rainbow trout is solved.

The application discloses a method for improving the determination accuracy of the content of malondialdehyde in a biological sample, which comprises adding a buffer solution, a protease solution and a thiobarbituric acid (TBA) into a malondialdehyde standard solution, and determining the absorbance of the malondialdehyde standard solution; subsequently, a standard curve is constructed, and the actual concentration of the malondialdehyde in the biological sample is calculated through the measured absorbance of the biological sample solution. The sample processing process of the method is simple, the Buffer A buffer solution and the protease used can release the MDA combined with the protein, can not only avoid the adsorption interference of the protein precipitation on the red complex of the MDA and the TBA and the extraction limitation of the supernatant, but also can detect the protein combined state MDA, can significantly improve the detection limit of the sample, is good in selectivity, improves the accuracy of the detection result, and can be used for the trace detection of clinical precious samples.

The invention discloses a nondestructive testing method and system for quality of Jinhua ham. The nondestructive testing method comprises the following steps: acquiring a 900-1700nm hyperspectral image of the Jinhua ham; performing bone-meat separation on the image and extracting meat position region spectral data; extracting core characteristic wave band information related to the internal quality from the meat position spectrum; carrying out preprocessing and multi-dimensional feature extraction on the core wave band spectrum to obtain a fusion feature set; and inputting the fusion feature set into a pre-established multi-task learning model, and synchronously outputting prediction results of the free fatty acid content, the peroxide value POV and the TBARS value. The method realizes nondestructive, rapid and synchronous detection of the key oxidation indexes of the Jinhua ham, is high in detection precision and good in stability, and has a remarkable industrial application value.

The invention discloses a method for obtaining a high-oxidation-resistance sesame grease body through microwave pretreatment and application of the high-oxidation-resistance sesame grease body. The method comprises the following steps: carrying out microwave pretreatment on a sesame raw material at the power of 700W for 5-12min, pulping, centrifuging and washing. According to the method, through accurate regulation and control, moderate modification of interface protein is realized, so that the interface protein content (such as 7min: 90.08%) of the oil body is kept at a functional level after the oil body is treated for 5-12min, the emulsion stability (ESI) is optimized, and the elasticity (storage modulus G ') of an interface film is remarkably enhanced. Meanwhile, the method efficiently activates an endogenous anti-oxidation system, and after accelerated oxidation of a 5-min pretreatment group for 20 days, the peroxidation value (PV), the thiobarbituric acid value (TBARS) and the carbonyl value increase the slowest, the sulfydryl is retained to the maximum, and excellent oxidation stability is shown. The obtained sesame oil body is an excellent natural embedding medium and can be widely applied to food systems such as seasoning sauce and dairy products.