The invention relates to a method and a device for removing organic
sulfur in
methyl tertiary butyl ether (MTBE). The method and the device are utilized for high-
sulfur content MTBE refinement. The method and the device realize normal-pressure low-temperature extraction rectification desulphurization of a high-
sulfur content MTBE product. A technical scheme of the invention comprises the following steps that 1, a sulfur-containing MTBE product is heated by a
heat exchanger and then is fed into a rectifying
tower from a lower part of the rectifying
tower; 2, an extractant is fed into the
heat exchanger, is heated and then is fed into the rectifying
tower from an upper part of the rectifying tower, wherein a rectifying tower temperature is in a range of 70 to 80 DEG C and the heated sulfur-containing MTBE product and the heated extractant countercurrently contact with each other so that countercurrent contact extraction desulphurization is realized; 3, the desulfurated MTBE product is output from the top of the rectifying tower, is subjected to cooling condensation to form liquid in the
heat exchanger and then is output; and 4, the sulfur-containing extractant obtained by the step 2is output from the bottom of the rectifying tower, is heated by the heat exchanger, is fed into a flash tank, is distilled at a temperature of 80 to 85 DEG C so that the residual desulfurated MTBE product is distilled off, then is fed into an actifier column, and countercurrently contacts with dry air in the actifier column so that countercurrent contact gas stripping regeneration is realized. Through the method and the device, good desulphurization effects are realized; a high product yield is obtained; and an extractant can be regenerated for recycle. The method is convenient for operation,has low costs and low
energy consumption, and can be utilized for high-
sulfur content MTBE product refinement.