80results about "Magnesium organic compounds" patented technology

The present invention relates to a display device comprisinga plurality of OLED pixels comprising at least two OLED pixels, the OLED pixels comprising an anode, a cathode, and a stack of organic layers, wherein the stack of organic layersis arranged between and in contact with the cathode and the anode, andcomprises a first electron transport layer, a first hole transport layer, and a first light emitting layer provided between the first hole transport layer and the first electron transport layer, anda driving circuit configured to separately driving the pixels of the plurality of OLED pixels,wherein, for the plurality of OLED pixels, the first hole transport layer is provided in the stack of organic layers as a common hole transport layer shared by the plurality of OLED pixels, and the first hole transport layer comprises(i) at least one first hole transport matrix compound consisting of covalently bound atoms and(ii) at least one electrical p-dopant selected from metal salts and from electrically neutral metal complexes comprising a metal cation and at least one anion and / or at least one anionic ligand consisting of at least 4 covalently bound atoms,wherein the metal cation of the electrical p-dopant is selected from alkali metals; alkaline earth metals, Pb, Mn, Fe, Co, Ni, Zn, Cd; rare earth metals in oxidation state (II) or (III); Al, Ga, In; and from Sn, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo and W in oxidation state (IV) or less, a method for preparing the display device and a chemical compound for use therein.

The present disclosure relates to a solid component for producing an olefin polymerization catalyst, its production method, and its use. The solid component contains (i) a magnesium compound represented by the following formula (1), (ii) a Lewis base (LB), and (iii) optionally a metal component other than magnesium, where LB is a compound represented by the general formula (II) or an amide compound represented by the general formula (II'). The solid component produced in the present invention has a good particle morphology, and a catalyst produced by using the solid component as a support is less likely to be crushed and has better stereostructure orientation in olefin polymerization, particularly propylene polymerization or copolymerization. [Formula 1] JPEG2023546624000060.jpg41169

Primary, secondary (1°,2°) alkylethylenediamine- and alkylpropylenediamine- appended variants of metal-organic framework are provided for CO2 capture applications. Increasing the size of the alkyl group on the secondary amine enhances the stability to diamine volatilization from the metal sites. Two-step adsorption / desorption profiles are overcome by minimizing steric interactions between adjacent ammonium carbamate chains. For instance, the isoreticularly expanded framework Mg2(dotpdc) (dotpdc4- =4,4"-dioxido-[1,1':4',l"-terphenyl]-3,3"-dicarboxylate), yields diamine-appended adsorbents displaying a single CO2 adsorption step. Further, use of the isomeric framework Mg-IRMOF-74-II or Mg2(pc-dobpdc) (pc-dobpdc4- = 3,3-dioxidobiphenyl-4,4-dicarboxylate, pc = para-carboxylate) also leads to a single CO2 adsorption step with bulky diamines. By relieving steric interactions between adjacent ammonium carbamate chains, these frameworks enable step-shaped CO2 adsorption, decreased water co-adsorption, and increased stability to diamine loss. Variants of Mg2(dotpdc) and Mg2(pc-dobpdc) functionalized with large diamines such as N-(n-heptyl)ethylenediamine have utility as adsorbents for carbon capture applications.

This invention relates to the field of organic synthesis technology, specifically to a highly efficient and stable Grignard preparation and its green preparation method. By weight, it comprises 8-18 parts of a magnesium source, 40-92 parts of a halogenated hydrocarbon, 150-200 parts of a green solvent, 15-20 parts of ethylene glycol dimethyl ether, and 2.3-3.2 parts of a synergistic stabilizer. The green solvent is 2-methyltetrahydrofuran, or a composite solvent with a weight ratio of 2-methyltetrahydrofuran:methyl tert-butyl ether of 150-160:40-50. The synergistic stabilizer is composed of 1.5-2.0 parts of N,N,N',N'-tetramethylethylenediamine and 0.8-1.2 parts of butylated hydroxytoluene, or composed of 1.5-2.0 parts of N,N,N',N'-tetramethylethylenediamine and 1.0 part of phenothiazine. This invention uses a green solvent system to replace traditional toxic and harmful solvents, and combines it with a solvent recovery process to achieve solvent recycling, which greatly reduces waste emissions and makes the production process safer and more environmentally friendly, in line with the development direction of green chemical industry.

The invention relates to a method for synthesizing (R)-3-methylheptanoic acid. According to the method, the application range of steroid sapogenin degradation waste is further expanded. According to the method disclosed by the invention, the (R)-3-methyl-heptanoic acid can be conveniently obtained by taking the (R)-4-methyl-gamma-butyric acid lactone obtained by degrading steroid sapogenin as a raw material. According to the method provided by the invention, the use of highly toxic and controlled reagents is avoided, high-risk reactions such as hydrogenation in the prior art are avoided, and the method is mild in reaction condition and low in synthesis cost. Meanwhile, the utilization rate of steroid sapogenin resources is increased, and waste generated in the utilization process of the steroid sapogenin resources is reduced.

The present invention relates to halogenated alkenylalkoxymethyl ether compounds of the following general formula (1): R 1 CH2OCH2OCH2CH2CH=CH(CH2) a X 1 (1), wherein R 1 represents a hydrogen atom, a n-alkyl group having 1 to 9 carbon atoms, or a phenyl group, X 1 represents a halogen atom, and a represents an integer of 3 to 14. The present invention also relates to a method for producing terminal conjugated alkadien-1-yl acetate compounds of the following general formula (5): CH2=CHCH=CH(CH2) a OAc (5), wherein a is defined as above, and Ac represents an acetyl group, and a method for producing terminal conjugated alkadien-1-ol compounds of the following general formula (6): CH2=CHCH=CH(CH2) a OH (6), wherein a is defined as above.

The present invention relates to a process for the production of an intermediate useful in organic synthesis, in particular for the production of astaxanthin.

A process of manufacturing a functionalized porous material includes: mixing a base porous material comprising a porous structure and a labile ligand with a functionalizing agent to form a slurry, the porous structure having open metal sites and a plurality of pores, wherein the labile ligand is coordinated to the open metal sites, present in the plurality of pores but not coordinated to the open metal sites, or a combination thereof, the labile ligand has a first boiling temperature and the functionalizing agent has a second boiling temperature that is higher than the first boiling temperature; and drying the slurry to form a functionalized porous material comprising the functionalizing agent coordinated to the open metal sites.

The method discloses a green synthesis process of acetylene alcohol double Grignard reagent, and the synthesis process comprises the following steps: dissolving benzyl chloride in an organic solvent to prepare solution A, adding metal magnesium to solution A to initiate a reaction, and preparing an initiation reaction solution; (2) dissolving benzyl chloride and acetylene alcohol substances in an organic solvent to prepare solution B; (2) adding solution B in step (2) to the initiation reaction solution in step (1) dropwise to perform a reaction, and preparing acetylene alcohol double Grignard reagent. The application provides a new synthesis method for synthesizing acetylene alcohol double Grignard reagent by using benzyl magnesium chloride, which can avoid a coupling side reaction between benzyl Grignard reagent and benzyl chloride, and does not need excessive metal magnesium.

The present disclosure provides a composite metal salt having a hexagonal Cd(OH)2 type crystal structure and an X-ray diffraction intensity ratio (orientation H) of the (101) plane to the (001) plane of 60% or less, and being denoted by the following formula (1):wherein “M2+” denotes at least one divalent metal other than Mg; “A” denotes at least one organic ligand; “x” denotes a number in a range of 0≤x<0.2; “y” denotes a number in a range of 0<y<0.05; and “n” denotes an integer of from 1 to 4, or zero.

The present invention provides a (6Z)-6-tridecenyl metal compound (1) wherein M1 represents Li or MgZ1, and Z1 represents a halogen atom or a (6Z)-6-tridecenyl group; also provided is a method for preparing a compound (1) comprising the steps of: preparing a (3Z)-3-decenyl metal compound (3) from a 1-halo-(3Z)-3-decenyl compound (2), where X1 represents a halogen atom, where M2 represents Li or MgZ2, and Z2 represents a halogen atom or a (3Z)-3-decenyl group; a coupling reaction of the compound (3) with a 1, 3-dihalopropane compound (4), where X2 and X3 independently of each other represent a halogen atom, to form a 1-halo-(6Z)-6-tridecene compound (5), where X4 represents a halogen atom; and preparing a (6Z)-6-tridecenyl metal compound (1) from the compound (5).

To provide a method for preparing an in situ metal doped manganese iron oxalate precursor.SOLUTION: Iron source, manganese source, doped metal elements (Mg, Zn, etc.) are weighed according to a stoichiometric ratio, and deionized water is added to the weighed metal to ultrasonically dissolve the weighed metal to obtain a mixed metal solution. The mixed metal solution is added to a prepared oxalic acid solution and subsequently a certain concentration of complexing agent is added to the solution to perform co-precipitation reaction under the protection of inert gas. A resultant suspension of metal doped manganese iron oxalate is recovered and then filtered, washed and dried to obtain a powder of manganese iron oxalate precursor.EFFECT: By using the manganese iron oxalate precursor as the iron and manganese sources, this can effectively avoid the problem of uneven mixing due to the iron and manganese sources. Moreover, lithium manganese iron phosphate synthesized from the manganese iron oxalate precursor after metal doping can significantly improve the electronic conductivity, thereby enhancing the electrochemical properties of lithium manganese iron phosphate.SELECTED DRAWING: Figure 1

The present application relates to an intermediate of fulvestrant and a preparation method thereof. Specifically, the present application relates to a compound as shown in formula V and a preparation method thereof, wherein R 1 is hydrogen or a hydroxyl protecting group. The present application also relates to a preparation method for synthesizing fulvestrant via the compound as shown in formula V, which has the advantages of short reaction steps, mild and safe reaction conditions, high selectivity, simple operation and purification, high synthesis efficiency, and is suitable for large-scale production.

The application discloses a kind of organic metal catalyst based on biguanide-based ligand and its preparation method and application, belong to polymer material field.The organic metal catalyst is by the ligand with biguanide-based structure and magnesium salt coordination and form.The preparation method of the application is simple, condition is mild, the obtained organic metal catalyst is with magnesium as metal center, its toxicity is lower, catalytic activity is high, can successfully catalyze cyclic lactone under solvent or solvent-free condition ring-opening polymerization reaction, and product molecular weight is high, distribution is narrow.

The purpose of the present disclosure is to provide magnesium glycinate which has a high magnesium concentration.　Disclosed is magnesium glycinate which is configured such that, in differential scanning calorimetry analysis, the value S1 / S2 obtained by dividing the area S1 of an endothermic peak that has a starting temperature in the range of 230°C to 255°C by the area S2 of an endothermic peak that has a starting temperature in the range of 330°C to 370°C is 0 to 7 inclusive.

The invention discloses a continuous flow preparation method and a preparation system of a Grignard reagent, and belongs to the technical field of Grignard reagent preparation. The method comprises the following steps: filling magnesium particles with the particle size of 1-10mm in a micro-channel tubular reactor; a halogenated hydrocarbon solution is introduced from the bottom of the microchannel tubular reactor, the Grignard reagent flows out from the top of the microchannel tubular reactor, the retention time of the reaction is 10-45 min, and after the reaction is completed, the Grignard reagent with proper concentration is directly obtained without separating magnesium; the micro-channel tubular reactor is vertically arranged, and filter screens are arranged on a feed port in the bottom and a reaction liquid discharge port in the top of the micro-channel tubular reactor; the magnesium particles are supplemented from the top of the micro-channel tubular reactor. Compared with the prior art, efficiency and safety can be remarkably improved.

The invention relates to the technical field of pesticide intermediates, in particular to a preparation method of a fluralan synthetic intermediate, which comprises the following synthetic route: taking parachloroaniline as an initial raw material, and carrying out acylation reaction on parachloroaniline and pivaloyl chloride in an alkaline solvent to generate a compound 2; performing chlorination reaction on the compound 2 and a chlorinating agent to generate a compound 3; reacting the compound 3 with magnesium in a nitrogen environment to obtain a Grignard reagent intermediate compound 4; reacting the compound 4 with a trifluoroacetic acid derivative to obtain a compound 5; reacting the compound 5 with concentrated hydrochloric acid to obtain a compound 6; generating a compound 7 from the compound 6 under the action of a chlorinating agent; and finally, synthesizing the compound 7 into a compound 8 under the action of a nitrite reagent. The preparation method has the advantages of safe operation, few by-products, mild conditions, easily available raw materials and simple optimization, and is more suitable for industrial large-scale production.

An anode material for a lithium ion battery comprises a carbonaceous silicon composite material. The composite material comprises Si nanoparticles, and nanostructured and microporous graphitic carbon and / or silicon carbide, wherein the graphitic carbon and / or silicon carbide are derived at least in part from carbonized metal organic framework.

The application discloses a magnesium complex taking aspirin or an oxygen-deficiency promoting derivative thereof as a ligand, a preparation method and application thereof in preparation of a medicine for treating coronary heart disease. The structural formula of the magnesium complex is shown in the following formula I-IV: the magnesium carbonate is reacted with nitric acid to obtain magnesium nitrate; the aspirin is reacted with sodium bicarbonate to obtain a neutral sodium salt of aspirin; the neutral sodium salt of aspirin is reacted with the magnesium nitrate according to a molar ratio of 1:1 or 2:1 to obtain the magnesium complex shown in the formula I or II. The aspirin is reacted with p-nitrobenzyl alcohol to obtain an oxygen-deficiency promoting derivative of aspirin; the oxygen-deficiency promoting derivative of aspirin is reacted with the magnesium nitrate according to a molar ratio of 1:1 or 2:1 to prepare the magnesium complex shown in the formula III or IV. The application has a remarkable repairing effect on heart damage caused by myocardial ischemia and the like.

To provide a novel compound as a synthetic intermediate for efficiently preparing 2,7-diacetoxyundecane, and to provide a process for preparing the novel compound, and a process for preparing 2,7-diacetoxyundecane from the novel compound.SOLUTION: There is provided 5-(2-butyl-1,3-dioxolan-2-yl)-1-methylpentyl acetate represented by the following formula (1). There is also provided a process for preparing 2,7-diacetoxyundecane, the process comprising the steps of: eliminating a ketal from the compound in the presence of an acid or a peroxide to prepare 10-acetoxy-5-undecanone; optionally subjecting the 10-acetoxy-5-undecanone to a reduction reaction to form 10-acetoxy-5-undecanol; and subjecting the 10-acetoxy-5-undecanol to an acetylation reaction to form 2,7-diacetoxyundecane.SELECTED DRAWING: None

The invention discloses a solid magnesium ion electrolyte based on a pyridine ligand, which is a compound composed of Mg (C5H5N) x < 2 + > composite cations and [B12H12] 2-anions, and x is greater than or equal to 1 and less than or equal to 6; the number of the pyridine ligands is 6. The preparation method comprises the following steps: step 1, preparing a Mg (H2O) 3B12H12 precursor MBH-W; and step 2, preparation of Mg (C5H5N) 6B12H12MBH-P. The preparation method comprises the following steps: preparing Mg (C5H5N) When the MBH-P-100 is applied as a magnesium ion solid electrolyte, the conductivity of the MBH-P-100 is 10 <-4 > S cm <-1 > under the condition that the working temperature is 140 DEG C; under the conditions that the polarization voltage is 1V, the test time is 4000 seconds and the test temperature interval is 120 DEG C, the electronic conductivity is 10 <-8 > S cm <-1 >.

The invention relates to the technical field of preparation of 2-methylallyl magnesium chloride, in particular to a preparation method of 2-methylallyl magnesium chloride, which comprises the following steps: pretreatment and initial feeding, reaction initiation, continuous reaction and heat preservation, end point judgment and product transfer. Magnesium is activated through a zinc stearate ethanol solution, zinc stearate can form an ultra-thin selective adsorption layer on the surface of magnesium particles, the layer cannot completely isolate the reaction, the reaction rate can be regulated and controlled, the risks of bumping and material flushing caused by too violent local reaction are avoided, and meanwhile, the service life of magnesium particles is prolonged. Ethanol is used as a solvent to assist zinc stearate to be uniformly attached to the surface of magnesium, and the dispersity of magnesium particles can be improved when the ethanol is subsequently mixed with tetrahydrofuran; tert-butyl p-hydroxyanisole is added into 2-methylallyl chloride to serve as a stabilizer, free radicals possibly generated in a reaction system can be captured, and side reactions such as polymerization and oxidation of 2-methylallyl chloride are inhibited.

Metal-organic frameworks are synthesized from either a high concentration synthesis where reaction solutions comprising increased reagent concentrations, or suspensions of reagents which exceed their solubility limit in the reaction solution in a high solids synthesis. In both approaches, the solubility of reagent is maximized by inclusion of a buffer, fixing a nominal pH of the reaction solution to allow metal-organic framework formation. These methods improve yields and scale up of metal-organic frameworks.

The object of the present invention is to provide a storage material for gases other than nitrogen that contains an MOF with a hydroxamic acid group as the binding site. [Solution] A gas storage material containing a metal-organic structure formed by bonding at least one polyvalent metal ion selected from Zn, Co, Ni, Cu, Zr, and Mg with at least one compound selected from those represented by the following formulas (1) to (2), wherein the gas is hydrogen or carbon dioxide. [Formula 1] JPEG2026074203000028.jpg34149

The invention belongs to the field of ethylene carbonate synthesis, and discloses a catalyst for synthesizing ethylene carbonate and a preparation method and application thereof.The catalyst is prepared through simple condensation and coordination reaction with ethylene carbonate as a green solvent and has a definite Schiff base metal complex structure and thioether modification characteristics; the catalyst shows high activity and selectivity close to 100% under mild conditions, meanwhile, the yield of ethylene carbonate is excellent, meanwhile, the catalyst is simple and green in preparation process, low in cost and good in stability, has remarkable industrialization prospects and popularization value, and is suitable for industrial production. The method can be widely applied to resource utilization of carbon dioxide and large-scale production of high-added-value cyclic carbonate.

A simpler method for producing high quality Metal-Organic Frameworks is provided. Particularly, the method for producing a Metal-Organic Framework according to the present invention includes: preparing an agitator equipped with a turbine and a stator surrounding the turbine, preparing a formulation comprising a metal ion donor, a multidentate ligand, and a solvent, and applying shear forces generated between the turbine and the stator to the formulation by rotating the turbine relative to the stator in the agitator.

The present application belongs to the technical field of veterinary drugs, and particularly relates to a preparation method of a key intermediate of Afugan. The present application uses an economic and easily available raw material trifluorotoluene, and through bromination, Grignard reagent method preparation of trifluoroacetone, chlorination, 3-chloro-5-trifluoromethyl trifluorophenyl ethanone can be obtained, the shortcoming of long route in the prior art method is overcome, and the dangerous diazotization process is avoided. The method is simple in operation, mild in condition, and suitable for industrial production.

The present application relates to fluorine-containing aryl borate compounds containing alkyl metal group units and preparation and application thereof in catalyzing olefin polymerization, the chemical structural formula of the fluorine-containing aryl borate compounds is {(F m Ar 1 ) 4‑n [F x Ar 2 -Q-Z-M(R) j ] n B} ‑ N + , which are obtained by introducing alkyl metal group units on the basis of fluorine-containing phenyl borate. Compared with the prior art, the fluorine-containing aryl borate compounds provided by the present application can interact with metallocene compound catalysts as cocatalysts, form catalyst systems and catalyze olefin polymerization, which not only can improve the stability of the catalyst system, but also is beneficial to widening the molecular weight distribution of polyolefins, improving the processing performance and the like.

The present invention relates to a process for producing intermediates useful in organic synthesis, particularly in the production of astaxanthin.