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54 results about "Arrhenius equation" patented technology

In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates. The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and reverse reactions. This equation has a vast and important application in determining rate of chemical reactions and for calculation of energy of activation. Arrhenius provided a physical justification and interpretation for the formula. Currently, it is best seen as an empirical relationship. It can be used to model the temperature variation of diffusion coefficients, population of crystal vacancies, creep rates, and many other thermally-induced processes/reactions. The Eyring equation, developed in 1935, also expresses the relationship between rate and energy.

Calculation method for remaining shelf life of fruits and vegetables

InactiveCN104749329AEffectively predict storage timeImprove storage and transportation valueTesting foodChemical reaction kineticsArrhenius equation
The invention discloses a calculation method for the remaining shelf life of fruits and vegetables and provides a calculation method for determining the remaining shelf life of fruits and vegetables by the hardness index. The calculation method comprises the following steps: firstly measuring an initial hardness value Q of the fruits and the vegetables, and simultaneously measuring a transformation relation of the hardness of the fruits and the vegetables with time under different temperatures; establishing a dynamic model of the fruits and the vegetables by adopting a first-order chemical reaction dynamic equation InAt=lnA0-kt, carrying out linear regression fitting on a hardness and time relation of the step, and thus obtaining a hardness-change rate constant ki of the fruits and the vegetables under different temperatures; applying an Arrhenius equation shown in the specification and combining the hardness-change rate constant ki of the fruits and the vegetables under different temperatures and a fitting-equation determination coefficient to obtain a relation curve graph shown in the specification of the fruits and the vegetables, obtaining a curve fitting equation from the obtained relation curve graph and determining the inclination and the intercept of the fitting line, wherein the mass equation of the fresh-eating fruits and vegetables is shown as the specification, the equivalent transformation is shown in the specification, and then the shelf life t of the fruits and the vegetables under the ambient temperature can be calculated.
Owner:TIANJIN UNIV OF COMMERCE

Method for determining stationary phase of accelerometer based on dual-parameter accelerated degradation data

The invention provides a method for determining the stationary phase of an accelerometer based on dual-parameter accelerated degradation data. The method is based on the assumption that the zero deviation and scale factors of the accelerometer degrade commonly and meet a power degradation law, the assumption that a high-temperature accelerated degradation test of the accelerometer meets the consistency condition of a failure mechanism, and the assumption that an accelerated model is an Arrhenius equation. The method comprises the following steps of: 1, establishing a degradation track model of the zero deviation and the scale factors; 2, estimating the pseudo-stationary phase of the zero deviation and the scale factors; 3, establishing a stationary phase accelerated model of the zero deviation and the scale factors; and 4, establishing a comprehensive reliable model of the stationary phase of the accelerometer, and determining the stationary phase of the accelerometer under the reliability. In the method, the influence of the zero-deviation degradation and the scale factors on the stationary phase of the accelerometer is taken into consideration simultaneously, horizontal information among different test temperatures is utilized fully by an integral maximum likelihood estimation process, so that the condition of the stationary phase of the accelerometer can be better describedunder the condition of dual-parameter common degradation, and the estimation accuracy is improved effectively.
Owner:BEIHANG UNIV

Component level-based asphalt thermal decomposition behavior researching method

The invention relates to a new method for researching the asphalt thermal decomposition behavior by deepening into the asphalt component level, belongs to the field of fire disaster safety and solves the problem that the current asphalt thermal decomposition behavior research is difficultly thorough. The method comprises the steps of: firstly, preparing component test samples, determining component content, testing the thermal decomposition property of asphalt and four components thereof by adopting differential scanning calorimetry-infrared spectroscopy technology, acquiring the thermal decomposition test data of all components in the asphalt, analyzing the thermal decomposition gradient distribution character of all the component and producing smoke ingredient and release rule; secondly, calculating the thermal analysis kinetic parameters of all the components according to the Arrhenius equation, and establishing a thermal decomposition kinetic model; finally, testing the microstructure, components and content of residues of the thermally-decomposed components by adopting a transmission electron microscope and aphotoelectron spectroscopy instrument, researching the thermal decomposition behavior of all the components in asphalt, and comparing with the asphalt test sample test results, and revealing the asphalt thermal decomposition mechanism. The method can fundamentally reveal the thermal decomposition behavior of asphalt under the high-temperature environment.
Owner:NANJING FORESTRY UNIV

Leaf spring normal-temperature and high-temperature stress relaxation life predicting method

The invention provides a leaf spring normal-temperature and high-temperature stress relaxation life predicting method. Firstly, a spring sample to be tested is prepared, and the prepared spring sample to be tested is an equal stress sample; then a test device is arranged, side plates are fixed at the front part and the rear part of a base of the test device, two ends of the sample are respectively arranged on the side plates, the base and an upper plate are fixed together through limiters, a pressure sensor is arranged on the upper plate, and a pressure head arranged at the lower end of the pressure sensor applies pressure on the sample; and then a spring stress relaxation experiment is carried out, stress values at different time are acquired to determine the stress relaxation loss condition of a sample material after the regulated experiment time is up, test data is selected according to failure criteria, the data is processed by an empirical formula and an Arrhenius equation, and finally the life of the sample at the normal temperature is determined. According to the method disclosed by the invention, sample bending deflection which is not easy to measure is converted into an electrical signal which is easy to measure, the work efficiency is improved, the method is simple, and the obtained life prediction result is accurate.
Owner:BEIHANG UNIV

Asphalt aging performance prediction method based on isothermal thermal analysis kinetics

The invention discloses an asphalt aging performance prediction method based on isothermal thermal analysis kinetics, belongs to the technical field of road asphalt pavement durability, and solves problems that an asphalt aging process cannot be predicted accurately and more practical asphalt aging performance prediction cannot be provided for pavement management and maintenance work when attenuation of a macroscopic performance index of the asphalt is adopted to speculate a pavement performance degradation degree at present. The asphalt aging performance prediction method provided by the invention comprises the following steps: firstly, selecting an asphalt sample, testing with a thermal analyzer, simulating thermal-oxidative aging of the asphalt to obtain TG and DTG data and a char yieldof the asphalt; secondly, selecting a reaction mechanism function corresponding to the asphalt aging process according to a chemical structure, a functional group and thermal stability change of theasphalt aging process to establish an isothermal thermal analysis kinetics model of the asphalt; finally, using an aging-time equivalence principle to analyze equivalence of the asphalt aging processand time, calculating an isothermal aging shift factor by an Arrhenius equation to predict the asphalt aging performance, thereby providing a basis for decision-making of an asphalt pavement maintenance scheme.
Owner:NANJING FORESTRY UNIV

Method for calculating thickness of oxide film of martensite heat-resistant steel under supercritical high-temperature steam

The invention relates to a method for calculating the thickness of an oxide film of martensitic heat-resistant steel under supercritical high-temperature steam. The method is particularly suitable for9% Cr martensitic heat-resistant steel. According to the method, a parabola model of metal oxidation kinetics is utilized; mathematical correction is carried out on the Arrhenius equation on the basis of the parabola model; a large number of actual operation results of a power plant and simulation experiment data are comprehensively taken into consideration; an oxide film thickness calculation formula of the 9% Cr martensitic heat-resistant steel in a high-temperature steam environment with a temperature of 23-35MPa is obtained by using a step-by-step linear fitting method and a function curve fitting method; and according to the formula, the influence of time and temperature on the thickness of the oxide film is comprehensively taken into consideration, and the thickness of the oxide film of the 9% Cr martensite heat-resistant steel under the condition can be calculated by substituting steam temperature and running time into the formula. The formula breaks through the limitation thatmost oxidation kinetic models only consider the influence of a single factor, and overcomes the defects that traditional oxide skin thickness measurement method is long in test period, high in cost,complex in operation and unstable in precision, or need to cut a steel pipe and the like.
Owner:GUODIAN SCI & TECH RES INST +1

Bushing insulation oil paper temperature correction and activation energy prediction method based on dielectric modulus

The invention relates to the technical field of electrical equipment fault diagnosis, and discloses a bushing insulation oil paper temperature correction and activation energy prediction method based on dielectric modulus, comprising the following steps: obtaining an expression of a dielectric model M (omega); preparing experimental samples with different moisture contents, and performing frequency domain dielectric spectrum testing on the samples at different temperatures to obtain an FDS curve corresponding to a complex dielectric constant; converting the FDS curve corresponding to the complex dielectric constant imaginary part to obtain an FDS curve corresponding to M ''(omega); positioning the peak frequency fp of the FDS curve corresponding to the M "(omega) by using a least square method, and obtaining the change rule of the fp along with the temperature and the moisture; defining a translation factor, and obtaining a rule that the translation factor changes along with temperature and moisture; introducing a classical Arrhenius equation into activation energy calculation, and obtaining an activation energy calculation formula related to the translation factor; and establishing an activation energy prediction model. According to the invention, the influence of temperature and moisture in the oil-paper insulation system on activation energy is considered, and the method is of great significance to aging evaluation of on-site bushings.
Owner:GUANGXI UNIV

Method for accurately forecasting quality change of quickly-frozen lotus root slices

InactiveCN106093324AAccurate prediction of quality changesTesting starch susbtancesChemical analysis using titrationHardnessBusiness forecasting
The invention discloses a method for accurately forecasting the quality change of quickly-frozen lotus root slices, and belongs to the field of agricultural product processing and storage. According to the method, respective quality change kinetic models are constructed according to the change-with-time rules of the VC, the color and the hardness of the quickly-frozen lotus root slices under different temperature storage conditions (-5 DEG C, -15 DEG C and -25 DEG C); all indexes are fitted by adopting the Arrhenius equation, thus determining quality change forecasting models of the quickly-frozen lotus root slices, i.e.: FORMULA I and FORMULA II respectively, wherein f(t) represents a quality index value of a sample at the time t, f(t0) represents an initial quality index value of the sample, t represents the storage duration (d), and T represents the absolute temperature (K). An experiment shows that the relative errors between actually measured values and forecast values of each index at different temperatures are less than 8 percent, and the accuracy is higher; furthermore, the relevant coefficients are all greater than 0.9, and the relevancy is good. The models can accurately forecast the quality of the quickly-frozen lotus root slices in a storage process, so that a basis is provided for actual production and application.
Owner:JIANGSU ACADEMY OF AGRICULTURAL SCIENCES

Method for improving shelf life of saltwater-freshwater bdellovibrio sp. microbial preparation

The invention discloses a method for improving shelf life of a saltwater-freshwater bdellovibrio sp. microbial preparation. The method comprises the following steps: preparing the bdellovibrio sp. microbial preparation; mixing the bdellovibrio sp. microbial preparation with a protection agent belonging to different kinds and / or with different concentration, so as to obtain a mixed solution; placing the mixed solution at different temperature to perform accelerated testing; sampling regularly, and detecting the live bacteria concentration of the bdellovibrio sp. microbial preparation in the mixed solution; and utilizing Arrhenius equation and recorded data to calculate out the shelf life of the bdellovibrio sp. microbial preparation, and determining the effect of the protection agent by comparing the shelf life. According to the method, by comparing the quality-guaranteeing effect of different protection agents on the bdellovibrio sp. microbial preparation, a protection agent with best quality-guaranteeing effect is screened out, and the shelf life of the bdellovibrio sp. microbial preparation is obviously prolonged; and also the activity of thalline in the bdellovibrio sp. microbial preparation can be effectively kept for a long time. The provided protection agent is wide in raw material selection scope and cheap in price, and is suitable for popularization and usage.
Owner:SOUTH CHINA UNIV OF TECH

Life prediction method fusing field data and two-stage accelerated degradation data

The invention discloses a life prediction method fusing field data and two-stage accelerated degradation data, and the method comprises the steps: determining a transformation point position of a degradation process according to the accelerated degradation data of a motor insulation material test sample under different thermal stresses through SIC and a residual sum of squares minimum criterion; constructing a motor insulation performance degradation model based on a two-stage random process under the action of thermal stress, obtaining a relationship between a model parameter and a change point distribution parameter and a temperature according to an Arrhenius equation, and extrapolating a probability density function and a model parameter of a change point position of a product in a degradation process at a normal temperature; utilizing on-site degradation data of a to-be-tested motor insulating material, using a CUSUM control chart for identifying a change point, and determining the probability of occurrence of the change point in combination with a probability density function of the change point; and taking the accelerated degradation data as prior information of model parameters, obtaining a posterior estimation value of the model parameters based on a Bayes method according to the field degradation data, obtaining a cumulative distribution function of product life under the sense of first arrival time, and realizing real-time life prediction of motor insulation.
Owner:ZHEJIANG UNIV

A method for predicting that storage life of a data product

PendingCN109359375AIncrease the amount of information availableImproving the Accuracy of Pseudo-Failure Life EstimationDesign optimisation/simulationSpecial data processing applicationsStress levelProduct base
A method for predict that storage life of a data product is provided. The accelerated degradation data of the product under various stress levels obtained from on-line and off-line tests. A storage life evaluation method of data products based on on-line data and off-line data is proposed. The pseudo-life of the data products under various accelerated stress levels is obtained by this method, andthe storage life of the data products under normal stress is evaluated by combining the temperature accelerated model. Making full use of on-line test data and adopting equivalent off-line performanceparameter data to effectively increase the amount of available information in the process of pseudo-failure life estimation and improve the precision of pseudo-failure life estimation. The temperature factor is introduced to transform the on-line test data into equivalent off-line data effectively, and the product life assessment can be completed more effectively by making full use of the data obtained from the test. The linear activation energy theory is introduced to make the selection of acceleration model more reasonable. The modified three-parameter Arrhenius equation is selected as acceleration model.
Owner:BEIJING INST OF STRUCTURE & ENVIRONMENT ENG +1

Leaf spring normal-temperature and high-temperature stress relaxation life predicting method

The invention provides a leaf spring normal-temperature and high-temperature stress relaxation life predicting method. Firstly, a spring sample to be tested is prepared, and the prepared spring sample to be tested is an equal stress sample; then a test device is arranged, side plates are fixed at the front part and the rear part of a base of the test device, two ends of the sample are respectively arranged on the side plates, the base and an upper plate are fixed together through limiters, a pressure sensor is arranged on the upper plate, and a pressure head arranged at the lower end of the pressure sensor applies pressure on the sample; and then a spring stress relaxation experiment is carried out, stress values at different time are acquired to determine the stress relaxation loss condition of a sample material after the regulated experiment time is up, test data is selected according to failure criteria, the data is processed by an empirical formula and an Arrhenius equation, and finally the life of the sample at the normal temperature is determined. According to the method disclosed by the invention, sample bending deflection which is not easy to measure is converted into an electrical signal which is easy to measure, the work efficiency is improved, the method is simple, and the obtained life prediction result is accurate.
Owner:BEIHANG UNIV
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