Nano C-S-H seed crystal early strength agent for building concrete and preparation method thereof

A C-S-H, concrete technology, applied in the field of concrete additives, can solve the problems affecting the quality and quality of concrete components, and achieve the effects of no electrochemical corrosion phenomenon, accelerated reaction process, and no influence on later strength.

Inactive Publication Date: 2018-08-31
CHENDU NEW KELI CHEM SCI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] According to the above, the traditional calcium salt, chloride salt and other inorganic early strength agents in the existing scheme have a significant effect and can increase the turnover rate of the formwork, but they introduce a large amount of impurities that can participate in or promote electrochemical reactions to the concrete, which is harmful to key reinforcements (such as steel bars) etc.) cause large electrochemical corrosion, which seriously affects the quality of concrete components. The present invention proposes a nano C-S-H seed crystal early strength agent for building concrete and a preparation method, which can effectively solve the above technical problems

Method used

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  • Nano C-S-H seed crystal early strength agent for building concrete and preparation method thereof
  • Nano C-S-H seed crystal early strength agent for building concrete and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] (1) Add acrylic monomers, silane coupling agent, and modified polyoxyethylene ether to the redox system composed of ammonium persulfate, vitamin C and dodecyl mercaptan, and obtain a molecular weight of 10,000 by polymerization reaction High molecular polymer and formulated into polymer solution; acrylic monomers are acrylic acid and methacrylic acid; silane coupling agent is vinyl trimethoxysilane; modified polyoxyethylene ether is allyl alcohol polyoxyethylene ether ( APEG); The mass concentration of the polymer solution is 16%;

[0033] In the reaction system, in parts by weight: 36 parts of acrylic monomer, 4 parts of silane coupling agent, 13 parts of modified polyoxyethylene ether, 3 parts of ammonium persulfate, 4 parts of vitamin C, and dodecyl mercaptan 40 copies;

[0034] (2) Prepare sodium metasilicate into solution A with a mass concentration of 48%, and calcium nitrate into solution B with a mass concentration of 35%;

[0035] (3) Place the polymer solution prep...

Embodiment 2

[0038] (1) Add acrylic monomer, silane coupling agent, and modified polyoxyethylene ether into the redox system composed of ammonium persulfate, vitamin C and dodecyl mercaptan, and obtain a molecular weight of 4000 by polymerization reaction High molecular polymer and formulated into polymer solution; acrylic monomer is methacrylic acid; silane coupling agent is vinyl triethoxy silane; modified polyoxyethylene ether is prenol polyoxyethylene ether ( TPEG); The mass concentration of the polymer solution is 12%;

[0039] In the reaction system, in parts by weight: 30 parts of acrylic monomer, 3 parts of silane coupling agent, 11 parts of modified polyoxyethylene ether, 2 parts of ammonium persulfate, 3 parts of vitamin C, and dodecyl sulfide 49 parts of alcohol;

[0040] (2) Prepare sodium metasilicate into solution A with a mass concentration of 45%, and calcium nitrate into solution B with a mass concentration of 30%;

[0041] (3) Place the polymer solution prepared in step (1) on...

Embodiment 3

[0044] (1) Add acrylic monomer, silane coupling agent, and modified polyoxyethylene ether into the redox system composed of ammonium persulfate, vitamin C and dodecyl mercaptan, and obtain a molecular weight of 20,000 by polymerization reaction High molecular polymer and formulated into polymer solution; acrylic monomer is methyl acrylate; silane coupling agent is γ-aminopropyl triethoxysilane; modified polyoxyethylene ether is polyethylene glycol monomethyl Ether (MPEG); the mass concentration of the polymer solution is 20%;

[0045] In the reaction system, in parts by weight: 42 parts of acrylic monomer, 5 parts of silane coupling agent, 15 parts of modified polyoxyethylene ether, 4 parts of ammonium persulfate, 5 parts of vitamin C, and dodecyl sulfide 31 parts of alcohol;

[0046] (2) Sodium metasilicate is formulated into solution A with a mass concentration of 50%, and calcium nitrate is formulated into solution B with a mass concentration of 40%;

[0047] (3) Place the polym...

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Abstract

The invention relates to the field of concrete additives, and discloses a nano C-S-H seed crystal early strength agent for building concrete and a preparation method thereof. The preparation method comprises the following steps that (1) acrylic monomer, a silane coupling agent, modified polyoxyethylene ether are added into ammonium persulfate, vitamin C and dodecyl mercaptan to prepare a polymer solution; (2) sodium metasilicate is prepared into a solution A of which mass concentration is 45-50%, and calcium nitrate is prepared into a solution B of which mass concentration is 30-40%; (3) the solution A and the solution B are added into the polymer solution, and the uniform and stable nano C-S-H seed crystal early strength agent for the building concrete is prepared through reaction. Compared with an ordinary early strength agent, the nano C-S-H seed crystal early strength agent for the building concrete has the advantages that the grain size of the particles is small, the distributionis uniform, the reaction process of the cement hydration can be accelerated, the early strength is significantly improved, no electrochemical corrosion phenomenon exists, the production efficiency isgreatly improved, the late strength of concrete members is not affected, and the production and application can be promoted.

Description

Technical field [0001] The invention relates to the field of concrete additives, and discloses a nano C-S-H seed early strength agent for construction concrete and a preparation method thereof. Background technique [0002] Concrete early strength agent is one of the main varieties of concrete admixtures. So far, the early strength admixtures developed at home and abroad mainly include: inorganic salt early strength agents such as chloride, sulfate, nitrite, and silicate; organic early strength agents such as triethanolamine, calcium formate and urea; A variety of composite early-strength additives, such as early-strength water reducer, early-strength antifreeze and early-strength pumping agent. [0003] In the construction process of concrete, it takes a long time from the setting and hardening caused by hydration to the expected strength. Adding an early strength agent can significantly increase the early strength of the concrete, thereby shortening the curing time. The early s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/42C08F283/06C08F220/06C08F220/14C08F220/18C08F230/08C04B103/12
CPCC04B40/0039C08F283/065C04B2103/12C04B22/00C04B22/085C04B24/42C08F220/1804C08F220/1802C08F230/08
Inventor 陈庆曾军堂
Owner CHENDU NEW KELI CHEM SCI CO LTD
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