156results about "Electrolye immobilisation" patented technology

Non-aqueous alkali metal (e.g., Li)/oxygen battery cells constructed with a protected anode that minimizes anode degradation and maximizes cathode performance by enabling the use of cathode performance enhancing solvents in the catholyte have negligible self-discharge and high deliverable capacity. In particular, protected lithium-oxygen batteries with non-aqueous catholytes have this improved performance.

An electrolyte composition comprising a compound represented by the following general formula (1):wherein R represents a substituent containing a -(CR1R2-CR3R4-O)n- bond (in which R1 to R4 are independently a hydrogen atom or an alkyl group, n being an integer of 2 to 20); Q represents an atomic group forming an aromatic cation having a 5- or 6-membered ring structure with a nitrogen atom, which may have a substituent; and X- represents an anion. A photoelectric conversion device comprising the electrolyte composition and a photo-electrochemical cell composed thereof are also provided.

Disclosed are ionically conductive composites for protection of active metal anodes and methods for their fabrication. The composites may be incorporated in active metal negative electrode (anode) structures and battery cells. In accordance with the invention, the properties of different ionic conductors are combined in a composite material that has the desired properties of high overall ionic conductivity and chemical stability towards the anode, the cathode and ambient conditions encountered in battery manufacturing. The composite is capable of protecting an active metal anode from deleterious reaction with other battery components or ambient conditions while providing a high level of ionic conductivity to facilitate manufacture and/or enhance performance of a battery cell in which the composite is incorporated.

The present invention provides a electrochemical element, wherein a multi-component composite film comprising a) polymer support layer film and b) a porous gellable polymer layer which is formed on either or both sides of the support layer film of a), wherein the support layer film of a) and the gellable polymer layer of b) are unified with each other without an interface between them.

A polymer gel electrolyte includes an electrolyte solution composed of a plasticizer with at least two carbonate structures on the molecule and an electrolyte salt, in combination with a matrix polymer. Secondary batteries made with the polymer gel electrolyte can operate at a high capacitance and a high current, have a broad service temperature range and a high level of safety, and are thus particularly well-suited for use in such applications as lithium secondary cells and lithium ion secondary cells. Electrical double-layer capacitors made with the polymer gel electrolyte have a high output voltage, a large output current, a broad service temperature range and excellent safety.

A rechargeable battery or cell is disclosed in which the electrode active material consists of at least one nonmetallic compound or salt of the electropositive species on which the cell is based, and the electrolyte or electrolyte solvent consists predominantly of a halogen-bearing or chalcogen-bearing covalent compound such as SOCl2 or SO2Cl2. Also disclosed are cell component materials which include electrodes that consist primarily of salts of the cell electropositive species and chemically compatible electrolytes. These latter electrolytes include several newly discovered ambient temperature molten salt systems based on the AlCl3-PCl5 binary and the AlCl3-PCl5-PCl3 ternaries.

A bipolar battery comprises a bipolar electrode in which a positive electrode is provided on one surface of a collector and a negative electrode is provided on the other surface of the collector, a gel electrolyte sandwiched between the positive electrode and the negative electrode, and a sealing layer which is provided between the collectors and surrounds a periphery of a single cell including the positive electrode, the negative electrode, and the gel electrolyte.

A method of forming an electrochemical cell is disclosed. The method comprises contacting a negative pole layer and a positive pole layer one with the other or with an optional layer interposed therebetween. The pole layers and the optional layer therebetween are selected so as to self-form an interfacial separator layer between the pole layers upon such contacting.

The invention relates to a method for the preparation of a polymer electrolyte electrochemical cell using an electrolyte precursor, said precursor comprising one or more solvents, one or more salts and a polymer which dissolves in the solvent at a first temperature (T_dissol) and which is capable of forming a gel on subsequent cooling following heating to a second temperature (T_gel). T_dissol being lower than T_gel, which method comprises: (a) heating the electrolyte precursor to T_dissol; (b) optionally cooling the electrolyte precursor, (c) incorporating the electrolyte precursor into the electrochemical cell; (d) heating the electrochemical cell to T_gel; (e) cooling the polymer electrochemical cell to ambient temperature to bring about gelling of the polymer electrolyte. Preferably the polymer is a homopolymer or copolymer from the group of monomers of vinyl fluoride, vinylidenefluoride, trifluoroethylene, tetrafluoroethylene and hexafluoropropylene.

Provided are an all-solid state primary film battery, and a method of manufacturing the same. The all-solid state primary film battery includes: a first polymer current collector film including a first polymer film and a first conductive layer; a first electrode layer formed on the first conductive layer; a second polymer current collector film that includes a second polymer film and a second conductive layer; a second electrode layer formed on the second conductive layer; and a polymer electrolyte layer including aqua-based electrolytic solution, and is formed between the first electrode layer and the second electrode layer.

Alkaline batteries are disclosed that advantageously include separators comprising at least one porous layer of fine fibers having a diameter of between about 50 nm and about 3000 nm that provide improved combinations of reduced thickness, dendritic barrier against short-circuiting and low ionic resistance as compared with known battery separators. The fine fibers show improved wet-ability in the alkaline electrolytes.

A flat, flexible electrochemical cell is provided. The within invention describes various aspects of the flat, flexible electrochemical cell. A printed anode is provided that obviates the need for a discrete anode current collector, thereby reducing the size of the battery. An advantageous electrolyte is provided that enables the use of a metallic cathode current collector, thereby improving the performance of the battery. Printable gelled electrolytes and separators are provided, enabling the construction of both co-facial and co-planar batteries. Cell contacts are provided that reduce the potential for electrolyte creepage in the flat, flexible electrochemical cells of the within invention.

A gel-type polymer electrolyte, wherein said polymer comprises (A) an ethylene-unsaturated carboxylic acid copolymer or a derivative thereof and (B) a polyalkylene oxide having a hydroxyl group at one terminal thereof or a derivative thereof, which are bonded together by an ester bond. The gel-type polymer electrolyte has a high ionic conductivity, and makes it possible to provides a cell which has excellent charge/discharge characteristics at low temperatures as well as at high temperatures.

A high-strength, heat-resistant and high-safety electrolytic-solution-supporting polymer film which can be applied to secondary batteries typified by lithium and lithium ion secondary batteries and which has an ionic conductivity of at least 5x10-4 S/cm at 25° C., a puncture strength of at least 300 g and a mechanical heat resistance of at least 300° C.

An alkaline dry battery including a zinc negative electrode prepared by dispersing zinc alloy powder containing 0.015 wt % or less of indium and 0.008 wt % to 0.02 wt % both inclusive of aluminum into a gelled alkaline electrolyte containing 0.5 wt % to 3 wt % both inclusive of a cross-linked water-absorbing polyacrylate polymer, a separator made of a single nonwoven fabric sheet or a stack of multiple nonwoven fabric sheets and has a thickness of 360 μm to 880 μm both inclusive and a positive electrode containing manganese dioxide.

A solid polymer electrolyte for an electrochemical cell is prepared by a sol-gel process in which an active metal ion conducting liquid electrolyte, e.g. a lithium-ion electrolyte, containing a salt which is stable in the presence of water, e.g. lithium bisperfluoroethanesulfonimide, LiN(SO2C2F5)2, is admixed in aqueous solution with an alkoxide, e.g. silica alkoxide, to form a liquid precursor which is added to the electrochemical cell between the anode and cathode thereof and allowed to solidify in situ to form the solid electroyte.

The invention discloses a gel electrolyte, a preparation method thereof, a battery using the gel electrolyte and a preparation method thereof. The gel electrolyte comprises a nonaqueous solvent and a gelator, wherein the nonaqueous solvent comprises lithium salts, and the gelator comprises polyethyleneglycol compounds with unsaturated double bonds, ester monomers with unsaturated double bonds, silane coupling agents and thermal initiators. The gel electrolyte is in double-ingredient package, wherein the weight ratio of the ingredient A and the ingredient B of the gel electrolyte is 1/1. The stirred uniform liquid is injected into a dried battery to be placed for 16 to 24 hours, so the gel electrolyte is sufficiently distributed inside the battery, and a gel electrolyte battery is obtained through in-situ thermal polymerization. Compared with the prior art, the invention uses a simple gel electrolyte preparation method, improves the safety performance for using the gel electrolyte battery on the premise of not changing the preparation technology and not controlling the preparation cost of the battery using the gel electrolyte, and ensures that a lithium battery has good electrochemical performance.

An open, liquid-state electrochemical cell that can be used as a primary or rechargeable power source for various miniaturized or portable electronic devices. The cell is composed of flexible and thin layers of anode, cathode and electrolyte materials with the electrolyte layer being exposed to open air. The electrolyte with an open configuration avoids the accumulation of gases upon storage of the cell. The electrolyte includes (a) a deliquescent material for keeping the open cell wet at all times and (b) an ion conductive material for transporting ions across the electrolyte layer. The electrolyte does not include a water-soluble polymer. The invention also provides a multi-cell battery that contains cells exhibiting the above-described features. The cell or battery, along with an electronic component, may be attached to a flexible substrate to make a functional device.