Gel electrolyte, preparation method thereof, battery using gel electrolyte and preparation method thereof
A gel electrolyte and battery technology, which is applied in the manufacture of electrolyte batteries, non-aqueous electrolyte batteries, electrolytes, etc., can solve problems such as low initial voltage and discharge capacity, arbitrary shape restrictions, and poor electrical performance. Achieve superior electrical performance, improve performance, and improve overall electrical performance
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Embodiment 1
[0022] The weight percentage content of each constituent of gel electrolyte is:
[0023] Triethylene glycol dimethacrylate: 1.2wt%
[0024] Methyl methacrylate: 8wt%
[0025] γ-(methacryloyloxy)propyltrioxysilane: 1.2wt%
[0026] Azobisisobutyronitrile: 0.06wt%
[0027] Azobisisobutyronitrile: 0.06wt%
[0028] Non-aqueous solvent containing lithium salt: 0.9M LiPF 6 and 0.1M LiB(C 2 o 4 ) 2 , EC / DMC=3:7, weight ratio: 89.54%.
[0029]The pre-prepared non-aqueous solvent containing lithium salt is divided into two parts, and then the initiator azobisisobutyronitrile is added to one part and stirred evenly to obtain the gel electrolyte component A for lithium batteries; at the same time, various monomers, Add another portion of the coupling agent and stir evenly to obtain component B of the gel electrolyte solution for lithium batteries. Finally, mix the gel electrolyte component A and the gel electrolyte component B in a ratio of one to one by weight. The mixed solutio...
Embodiment 2
[0034] The weight percentage content of each constituent of gel electrolyte is:
[0035] Triethylene glycol dimethacrylate: 3wt%
[0036] Methyl methacrylate: 1wt%
[0037] γ-(Methacryloyloxy)propyltrioxysilane: 2.5wt%
[0038] Azobisisobutyronitrile: 0.06wt%
[0039] Non-aqueous solvent containing lithium salt: 1.0M LiClO4, PC / EMC / DEC=4:3:3, weight ratio: 93.44%. This is a single battery, no mixing salts.
[0040] The pre-prepared non-aqueous solvent containing lithium salt is divided into two parts, and then the initiator azobisisobutyronitrile is added to one part and stirred evenly to obtain the gel electrolyte component A for lithium batteries; at the same time, various monomers, Add another portion of the coupling agent and stir evenly to obtain component B of the gel electrolyte solution for lithium batteries. Finally, mix the gel electrolyte component A and the gel electrolyte component B in a ratio of one to one by weight. The mixed solution is a colorless or lig...
Embodiment 3
[0048] The weight percentage content of each constituent of gel electrolyte is:
[0049] Triethylene glycol dimethacrylate: 2.3 wt%
[0050] Methyl methacrylate: 0.8wt%
[0051] γ-(methacryloyloxy)propyltrioxysilane: 1.9wt%
[0052] Azobisisobutyronitrile: 0.04wt%
[0053] Non-aqueous with lithium salt: 0.9M LiPF 6 and 0.1M LiB(C 2 o 4 ) 2 , EC / EMC / DEC=4:3:3, weight ratio: 94.96%.
[0054] The pre-prepared non-aqueous solvent containing lithium salt is divided into two parts, and then the initiator azobisisobutyronitrile is added to one part and stirred evenly to obtain the gel electrolyte component A for lithium batteries; at the same time, various monomers, Add another portion of the coupling agent and stir evenly to obtain component B of the gel electrolyte solution for lithium batteries. Finally, the gel electrolyte component A and the gel electrolyte component B are mixed in a weight ratio of one to one. The mixed solution is a colorless or light yellow transparen...
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