379 results about "Methylene bisacrylamide" patented technology

The invention relates to the technical field of oilfield chemistry, and discloses a graft modified cellulose filtrate reducer and a preparation method thereof.The preparation method comprises the following steps that modified hydroxyethyl cellulose, 2-acrylamide-2-methyl propane sulfonic acid, dimethyl diallyl ammonium chloride, alkenylated cardanol and N, N '-methylene bisacrylamide are added into deionized water, stirring is conducted, and a mixture is obtained; the preparation method comprises the following steps: adding cellulose into a reaction kettle, stirring for 10-15 minutes at the temperature of 40-60 DEG C at the speed of 300-400 rpm, dropwise adding ammonium persulfate and sodium hydrogen sulfite into a system, and continuously reacting for 4-6 hours to obtain the grafted modified cellulose filtrate reducer. The filtrate reducer disclosed by the invention has good high temperature resistance and salt resistance.

The invention discloses a hydrogel patch for gastric perforation repair and a preparation method thereof, and belongs to the technical field of biomedical materials. The preparation method comprises the following steps: dissolving acryloyl valine, acrylic acid, methylene bisacrylamide, a compound A and a photoinitiator in an alcohol solvent, and defoaming to obtain a precursor solution; and placing the precursor solution in a mold, carrying out ultraviolet-induced curing, soaking the obtained hydrogel in a hydrochloric acid solution, and replacing the alcohol solvent to obtain the hydrogel patch for gastric perforation repair. The hydrogel patch provided by the invention has the advantages of strong acid corrosion resistance, good biocompatibility, low swelling ratio, stable adhesion performance in a fluctuating pH environment and the like. The tough and stable adhesion performance ensures that the hydrogel can be permanently and reliably adhered to a gastric perforation part in a dynamic gastric acid environment, and a stable platform is provided for drug delivery, so that the surgical operation time is expected to be shortened, and wound healing is promoted.

The invention relates to the technical field of functional polymer composite materials, and provides diatomite modified composite super absorbent and rapid absorbent resin and a preparation method thereof. The preparation raw materials of the diatomite modified composite high-water-absorption and rapid-water-absorption resin provided by the invention comprise acrylic acid, acrylamide, sodium hydroxide, N, N '-methylene bisacrylamide, ammonium persulfate and modified diatomite. The diatomite is modified by the silane coupling agent, the agglomeration problem of the diatomite is solved, the compatibility with organic monomers is improved, and the modified diatomite, acrylic acid and acrylamide are utilized to construct an organic-inorganic synergistic three-dimensional porous network structure, so that the resin has ultrahigh water absorption rate, rapid water absorption performance and good water retention stability. Meanwhile, the preparation method disclosed by the invention does not need nitrogen protection, has the advantages of simple process, controllable raw material cost and easiness in industrial mass production, and is suitable for multiple fields such as water-saving agriculture, soil moisturizing, landscaping and the like.

The invention discloses a preparation method and application of a photo-thermal dual-response membrane material, and relates to the field of membrane materials. When the photo-thermal double-response membrane material is prepared, a photo-thermal material firstly reacts with 4-(triethoxysilyl) aniline and then reacts with 2, 4, 6-trihydroxy-1, 3, 5-benzenetricarboxaldehyde and p-phenylenediamine, and a modified photo-thermal material is prepared; the preparation method comprises the following steps: sequentially reacting benzaldehyde with 2-hydroxyacetophenone and 3-N, N-dimethylamino methacryloyl chloride to prepare a photo-initiation monomer; the preparation method comprises the following steps: mixing N-isopropylacrylamide, a photo-initiation monomer, N, N '-methylene bisacrylamide and a modified photo-thermal material, combining with a hydrophobic substrate membrane, preparing a membrane, and finishing the surface by using 2-bromo-1-[3, 5-di (tert-butyl)-4-hydroxyphenyl] ethanone, thereby obtaining the photo-thermal dual-response membrane material. The photo-thermal dual-response membrane material prepared by the invention has the characteristics of pollution resistance, easiness in cleaning, durability, antibacterial property, metal ion recovery and low energy consumption.

The invention belongs to the technical field of lithium ion battery solid electrolytes, and discloses a multi-component in-situ polymerized gel solid electrolyte and a preparation method and application thereof, the gel solid electrolyte is prepared by adding an amide cross-linking agent and a polymeric monomer into a basic electrolyte to obtain a precursor solution, then adding an initiator, and carrying out in-situ polymerization at 45-70 DEG C for 6-12 hours, the amide cross-linking agent is one or more of N, N '-methylene bisacrylamide, polyacrylamide, poly (2-acrylamide-2-methyl-1-propanesulfonic acid), polymethacrylamide, polyethylene glycol diacrylamide, polyether amide or adipamide. The first coulombic efficiency of an LCOLi button cell assembled by the multi-component in-situ polymerization solid-state gel electrolyte reaches 94.81%, the capacity retention rate after 500 cycles at 3-4.6 V still reaches 80% or above, and the LCOLi button cell can safely pass a needle test and can be applied to the field of solid-state electrolytes.

The invention belongs to the technical field of thermoelectric materials and functional polymer materials, and particularly relates to thermoelectric hydrogel based on synergistic enhancement of zwitterions and a polar solvent as well as a method and application of the thermoelectric hydrogel. The thermoelectric hydrogel is obtained through the steps that a precursor solution is subjected to a polymerization reaction to form a gel matrix, then the gel matrix is soaked in a soaking solution, potassium ferricyanide / potassium ferrocyanide redox couple is introduced, and the thermoelectric hydrogel is obtained, and the precursor solution is prepared from acrylamide, N-isopropylacrylamide, dimethyl sulfoxide, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide and N, N-dimethylformamide. The photoinitiator is prepared by mixing N, N-dimethylformamide, 1-ethyl-3-methylimidazolium tetrafluoroborate, a zwitterionic monomer [2-(methylacryloyloxy) ethyl] dimethyl-(3-sulfopropyl) ammonium hydroxide, a cross-linking agent N, N '-methylene bisacrylamide, a photoinitiator and deionized water. The thermoelectric hydrogel prepared by the invention has high mechanical strength, high ductility and high Seebeck coefficient, and has better temperature resistance.

The invention discloses high-strength deformable porous hydrogel for postoperative abdominal cavity tissue effusion drainage, belongs to the technical field of medical porous hydrogel, and particularly relates to a temperature-sensitive hydrogel reaction solution obtained by adding a monomer, a cross-linking agent and an initiator into water and mixing, and freezing and polymerizing to obtain ice gel; treating the ice gel in a salting-out solution to obtain porous hydrogel; the cross-linking agent is prepared from at least one of N, N-methylene bisacrylamide, N, N-methylene bisacrylamide and polyethylene glycol diacrylate. The invention provides the high-strength deformable porous hydrogel for postoperative abdominal cavity tissue effusion drainage, which has a temperature-sensitive effect, can be dynamically controlled through electric heating, and has good mechanical properties and a good drainage effect.

The invention discloses a UV photocuring adhesive, a preparation method thereof and an application of the UV photocuring adhesive in the electronic field, and relates to the field of adhesives. The preparation method comprises the following steps: when the UV photocuring adhesive is prepared, carrying out a reaction on dihydroxyl modified 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, p-phenylene diisocyanate, polyethylene glycol and 2-ethyl-4-methylimidazole, so as to obtain imidazole-terminated isocyanate, and carrying out a reaction on the imidazole-terminated isocyanate and the 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, so as to obtain the UV photocuring adhesive. The modified lignin, butanediamine and N, N '-methylene bisacrylamide are subjected to a reaction, and a double-bond reactant is prepared; the preparation method comprises the following steps: reacting epoxy-terminated siloxane with octamethylcyclotetrasiloxane, tetramethyltetravinyl cyclotetrasiloxane and tetramethylammonium hydroxide to obtain modified siloxane, and finally, uniformly mixing imidazole-terminated isocyanate, a double-bond reactant, modified polysiloxane and benzoin butyl ether to obtain the polyurethane adhesive. The UV light-cured adhesive prepared by the invention has good adhesive property, anti-aging property and flame retardant property.

The invention discloses a core-shell structure P (MMA-MBA) copolymer heat-storage phase-change microcapsule, the microstructure is of a spherical structure, the core-shell structure is adopted, the core structure is hexadecane, the shell structure is a methyl methacrylate (MMA) and N, N-methylene bisacrylamide (MBA) copolymer, the emulsifier is lauryl sodium sulfate (SDS), the initiator is potassium persulfate, and the pH value of the core-shell structure P (MMA-MBA) copolymer heat-storage phase-change microcapsule is 7-8. And the coating efficiency is 70-75%. The preparation method comprises the following steps: 1, preparing an oil phase and a water phase; and 2, polymerization reaction of the microcapsule. A phase change cement material based on a core-shell structure P (MMA-MBA) copolymer heat storage phase change microcapsule is prepared by compounding the P (MMA-MBA) copolymer heat storage phase change microcapsule and a cement matrix, and has hydrophobicity; obvious weightlessness exists in two times.

The invention discloses a preparation method of an environment-friendly lithium battery fire extinguishing agent based on nanofiber gel, and relates to the technical field of fire extinguishing. When the environment-friendly lithium battery fire extinguishing agent is prepared, nano sodium carboxymethyl cellulose reacts with N-isopropylacrylamide and N, N-methylene bisacrylamide to prepare semi-interpenetrating network hydrogel; the semi-interpenetrating network hydrogel and calcium lactate are cross-linked, and nano sodium carboxymethyl cellulose hydrogel is prepared; and mixing and stirring the nano sodium carboxymethyl cellulose hydrogel, the modified silicon carbide and a flame retardant to prepare the environment-friendly lithium battery fire extinguishing agent. The prepared environment-friendly lithium battery fire extinguishing agent has good fire extinguishing performance.

The invention relates to high-strength degradable self-healing hydrogel and a preparation method thereof, and belongs to the technical field of high polymer materials. The hydrogel is prepared from the following components in percentage by mass: 15 to 20 percent of carboxymethyl cellulose, 10 to 14 percent of acrylic acid, 15 to 20 percent of N-isopropylacrylamide, 4 to 8 percent of tannic acid, 2 to 4 percent of borax, 0.06 to 0.1 percent of laccase, 0.5 to 1 percent of N, N-methylene bisacrylamide, 0.4 to 0.6 percent of potassium persulfate and the balance of phosphate buffer solution. According to the hydrogel disclosed by the invention, through dual-network structure design, dynamic covalent bond crosslinking and enzyme catalysis green synthesis, collaborative optimization of high strength, high self-healing property, degradability and multi-responsiveness is realized, and the problems of poor mechanical property, low repairing efficiency, environmental unfriendliness and the like of traditional hydrogel are solved; the method has wide application potential in the fields of biomedicine, flexible electronics, intelligent packaging and the like.

The invention discloses thermal stimulation response hydrogel and a preparation method thereof, and belongs to the technical field of high polymer materials. The preparation method comprises the following steps: dissolving acryloyl valine, acrylamide, methylene bisacrylamide and a photoinitiator in an organic solvent, and defoaming to obtain a precursor solution; and S2, putting the precursor solution into a mold, carrying out ultraviolet light-induced curing, soaking the obtained hydrogel in an acid solution, replacing the organic solvent, and then carrying out heat treatment to obtain the thermal stimulation response hydrogel. Compared with other existing thermal response type hydrogel, the thermal response type hydrogel has the advantages that the fracture stress, the modulus, the tensile work and the like are remarkably improved in the order of magnitude level, and excellent comprehensive mechanical properties are shown. The thermally-induced hardening hydrogel developed by the invention has a wide application prospect in the field of engineering devices requiring higher modulus and requiring significant change of mechanical properties before and after heating.

The invention relates to the technical field of textile chemicals, in particular to an electrolyte-resistant printing thickening agent for improving the coloring effect and a preparation method thereof.The electrolyte-resistant printing thickening agent is prepared from, by weight, 10-20 parts of methacrylic acid, 15-30 parts of triethanolamine, 0.1-0.5 part of N, N '-methylene bisacrylamide, 4-8 parts of functional monomers and 2-5 parts of organic modified nano bentonite. 3-6 parts of an emulsifier, 0.1-0.6 part of sodium hydrogen sulfite, 0.1-0.6 part of sodium persulfate, 8-15 parts of an oil-phase solvent, 2-5 parts of a reverse-phase emulsifier and 30-50 parts of water; the functional monomer is prepared from p-styrene propanesulfonic acid, 2-acrylamide-2-methyl propanesulfonic acid and triphenylethyl phenol polyoxyethylene ether methacrylate according to the weight ratio of (3 to 5) to (1 to 2) to 1. According to the electrolyte-resistant printing thickening agent capable of improving the coloring effect, through matching and combination of the raw materials, the electrolyte resistance of the thickening agent can be improved, and the coloring effect in textile printing is improved.

The invention relates to the technical field of blood purification materials, in particular to a zirconium-titanium bimetal MOF hollow microsphere adsorbent and a preparation method and application thereof. The adsorbent is based on a Zr / Ti bimetallic node and a phosphonic acid-carboxylic acid mixed ligand, a composite MOF hollow microsphere structure with high stability and high specific surface area is constructed through a solvothermal and polymerization synergistic reaction in a water-in-oil suspension system, a phosphonic acid group and Zr are strongly coordinated to improve the stability of a framework, and the composite MOF hollow microsphere structure has a high specific surface area. The carboxylic acid group keeps the hydrophilicity of the pore channel; meanwhile, a cross-linked network of acrylamide and N, N '-methylene bisacrylamide penetrates through crystal gaps in the balling process, so that the material has excellent mechanical strength and fluid stability; and a sulphobetaine amphoteric polymer brush layer is constructed on the surface of the MOF through endogenous initiation point modification and surface in-situ controllable free radical polymerization technologies, so that protein adsorption and platelet adhesion are effectively inhibited, the blood compatibility is remarkably improved, and meanwhile, the channel accessibility is maintained to promote rapid diffusion and adsorption of bilirubin.

The invention discloses a flexible self-powered triboelectric sensor, and belongs to the technical field of sensors, the flexible self-powered triboelectric sensor comprises a first silicone rubber layer, a hydrogel layer, a conductive silica gel electrode layer and a second silicone rubber layer which are sequentially arranged from top to bottom, the hydrogel layer is prepared from N-isopropylacrylamide (NIPAM), N, N-dimethylacrylamide (DMAA), N, N-dimethylacrylamide (DMAA), N, N-dimethylacrylamide (DMAA) and N, N-dimethylacrylamide (DMAA); n, N '-methylene bisacrylamide (MBA) and sodium alginate (SA) are copolymerized to form a three-dimensional network, in-situ embedding of biological source orange juice carbon dots is initiated through ultraviolet light, and the first silicone rubber layer, the hydrogel layer, the conductive silica gel electrode layer and the second silicone rubber layer are bonded and fixed on the periphery through silica gel. The invention discloses a green, safe and high-performance flexible triboelectric sensor, which realizes excellent electrical output through a simple process and is combined with an advanced signal processing technology to realize accurate recognition of multiple key physiological signals by a single sensor.

The invention discloses 3D printing direct writing ink capable of intelligently responding to hydrogel, which comprises the following components in parts by weight: 100 parts of water; 0.5 to 2.8 parts of carbomer; 6.8 to 18 parts of a hydrogel monomer N-isopropylacrylamide; 0.001 to 0.006 part of sodium hydroxide serving as a pH regulator; 0.005 to 0.02 part of a cross-linking agent, namely methylene bisacrylamide; 0.00625 to 0.0125 part of ammonium persulfate serving as an initiator; 0.00125 to 0.00375 parts of pyrrole; carbomer serves as a dispersing agent to inhibit pyrrole molecule agglomeration, pyrrole and an initiator ammonium persulfate have a synergistic effect in a polymerization reaction, a polypyrrole photo-thermal phase is generated in situ, thermal polymerization and crosslinking of a hydrogel monomer N-isopropylacrylamide are initiated, and a uniformly dispersed double-gel network is formed; through optimization of synergistic polymerization of pyrrole and ammonium persulfate and design of a carbomer dispersant, in-situ uniform dispersion of a photo-thermal phase and synchronous crosslinking of a gel network are realized, the photo-thermal conversion efficiency and material uniformity are improved, use of a toxic coagulant is avoided, the window period of 3D printing is prolonged, swelling deformation is inhibited, and the material is suitable for the fields of intelligent 4D printing, drug loading and bionic robots.

The invention discloses zwitterionic concrete internal curing hydrogel based on humidity-pH dual responsiveness and a preparation method of the zwitterionic concrete internal curing hydrogel, and belongs to the technical field of building materials. The water-based cleaning agent is prepared from the following raw material components in percentage by weight: 6%-8% of N-vinyl imidazole, 8%-12% of 2-methylimidazole, 6%-8% of 2-acrylamido-2-methylpropanesulfonic acid, 2%-4% of sodium p-styrenesulfonate, 26%-30% of acrylic acid, 18%-21% of N-vinyl pyrrolidone, 15%-18% of glycidyl methacrylate, 2%-5% of nano montmorillonite powder, 0.05%-0.1% of divinyl benzene, 0.05%-0.15% of N, N-dimethylformamide and the balance of water. The invention discloses an anti-freezing agent which is prepared from the following components in percentage by weight: 0.1%-0.3% of N, N-methylene bisacrylamide, 0.1%-0.3% of 1-[4-(2-hydroxyethoxy)-phenyl]-2-hydroxy-2-methyl-1-propane-1-ketone, 0.5%-0.8% of ammonium persulfate and 0.5%-0.8% of sodium hydrogen sulfite. Double response to the internal humidity and pH value of the concrete can be achieved, and the requirement for precise internal curing of modern high-performance concrete is met.

The invention discloses a preparation method and application of bamboo nanocellulose and bi-crosslinking hydrogel. The preparation method of the hydrogel comprises the following steps: (1) dispersing the bamboo nanocellulose; (2) preparing a lignin-Fe solution; and (3) preparation of the bi-crosslinked hydrogel: adding the bamboo nanocellulose suspension and acrylic acid into water, then adding ammonium persulfate and N, N '-methylene bisacrylamide, finally adding the lignin-Fe solution to obtain a precursor solution, and pouring the precursor solution into a mold to obtain the bi-crosslinked hydrogel. The moso bamboo is used as a raw material, cellulose is extracted from the plant which is extremely high in carbon sequestration capacity and rapid in production and then is processed into nano cellulose, a novel utilization way is provided for the moso bamboo, and the hydrogel prepared from the moso bamboo is good in environment friendliness, green, natural and non-toxic, can be in direct contact with skin, and has a good application prospect. And the application and development of the material in the fields of environmental protection, biomedical treatment, electronic skin, wearable sensors and the like are facilitated.

The invention provides an interface-stable and anti-fatigue Janus conductive hydrogel, a preparation method and sensing application, and the preparation method comprises the following steps: uniformly mixing acrylic acid, ethylene glycol dimethacrylate, a photoinitiator, ferric chloride hexahydrate and deionized water to obtain a support layer precursor solution; mixing acrylic acid, lauryl methacrylate, N, N '-methylene bisacrylamide and the nanocellulose suspension, performing ultrasonic treatment to obtain a Pickering emulsion, adding a photoinitiator into the Pickering emulsion, and uniformly mixing to obtain an adhesion layer precursor solution; and pouring the support layer precursor solution into a mold, then slowly pouring the adhesion layer precursor solution onto the support layer precursor solution, carrying out ultraviolet curing, taking out from the mold, and cleaning to obtain the Janus conductive hydrogel. According to the method, the Pickering emulsion phase separation and the charge shielding effect are combined through a simple and convenient one-step method, and the problems that a traditional multi-layer assembly process is complex in operation and unstable in interface are effectively solved.

The invention discloses preparation and application of an amido-functionalized polyionic liquid catalyst, vinyl imidazole hydrobromide and N-(4-vinyl) benzyl diethylamine are used as monomers, N, N '-methylene bisacrylamide is used as a cross-linking agent, and the amido-functionalized polyionic liquid catalyst is prepared through a free radical copolymerization method. The imidazole / amido functionalized cross-linked PILs with multiple active sites are prepared by one-step synthesis through a hydrothermal polymerization method. The catalyst has catalytic active sites of amido, imidazolyl and Br, so that the catalyst can efficiently catalyze the cycloaddition reaction of CO2 and epoxide at 80 DEG C and normal pressure in the absence of a solvent and a co-catalyst.

A geopolymer precursor includes an alkaline reactive solid material containing aluminum, silicon, and oxygen, and a fluid loss control material having an ionic stability property that has a first value in water and a second value in a 3M solution of NaOH, wherein a ratio of the second value to the first value is in a range of 0.5 to 2.0. The fluid loss control material may be, or may include a crosslinked polymer, which may include a reaction product of one or more of acrylamide, 2-acrylamido-2-methyl propane sulfonic acid, N,N‑dimethylacrylamide, N,N‑diethylacrylamide, vinyl acetate, or another monomer, and a crosslinker including one or more of methylene bisacrylamide, triallyl amine, pentaerythritol allyl ether, triallyl-triazine-trione, or another material. The geopolymer precursor may include an activator, an alkaline solution having pH of at least about 9, or both.

The present disclosure provides a preparation method of a porous hydrogel adsorbent based on Radix astragali residues, including the following steps: subjecting residues of Chinese herbal medicine Radix astragali as a precursor to bleaching with NaClO2, alkaline washing with KOH, and high power ultrasonic treatment, thereby obtaining a precursor solution of uniformly dispersed cellulose nanofibers (CNFs); adding the precursor solution of CNFs to a mixed solution of N,N′-methylene bisacrylamide (MBA), acrylic acid (AA) and ammonium persulfate (APS), shaking evenly, and initiating a polymerization reaction at a predetermined temperature to form a monolithic gel; and cleaning the monolithic gel, putting the cleaned monolithic gel into a dimethyl sulfoxide (DMSO) solution containing epichlorohydrin to allow reaction, and transferring the product of the reaction to an aqueous sodium hydroxide solution containing triethylene tetramine to allow reaction, thereby finally obtaining an amino-functionalized porous hydrogel adsorbent.

The present application discloses an antibacterial hydrogel dressing with integrated constant temperature photothermal effect and controlled drug release function, as well as its preparation method and application, which belongs to the field of medical biomaterial technology. The antibacterial hydrogel dressing with integrated constant temperature photothermal effect and controlled drug release function provided by the present application includes: a dressing and an antibiotic drug compounded on the dressing; the dressing is woven from photothermal water gel fiber and thermosensitive hydrogel fiber; the photothermal water gel fiber is made of photothermal dye, proton donor and phase change material as the core layer and sodium alginate as the shell layer; the thermosensitive hydrogel fiber is made of N-isopropyl acrylamide, methylene bisacrylamide, phenyl-2,4,6-trimethylbenzoyl lithium phosphinate and sodium alginate. The hydrogel dressing prepared by the present application has an inherent temperature control mechanism, can release drugs on demand and in a concentrated manner, has excellent antibacterial effect, and has broad application prospects in the preparation of biomedical materials.

The invention discloses a high-temperature-resistant and high-modulus adhesive and a preparation method thereof, and relates to the technical field of adhesives. The water-based adhesive comprises the following raw materials: 40-60 parts of a soft monomer, 20-30 parts of a hard monomer, 5-10 parts of a functional monomer, 1-3 parts of a cross-linking agent, 0.5-1.5 parts of an initiator, 2-5 parts of a modified nano filler and 30-50 parts of a solvent, the functional monomer is prepared by compounding N-methoxy methyl acrylamide, acrylic acid and 2-acrylic acid-hexahydro-4, 7-methylene-1H-indenyl ester according to a mass ratio of 2 to 1 to (1 to 1.5); the cross-linking agent is prepared by compounding N, N '-methylene bisacrylamide and 1, 1, 3, 3-tetramethyl-1, 3-divinyl disilazane according to a mass ratio of 1: (0.5 to 1). The adhesive has the advantages of favorable adhesive property, favorable high-temperature resistance and high modulus.

The invention relates to a preparation method of a novel anti-freezing rewarming antibacterial medical gel dressing, belongs to the field of composite material-based hydrogel, and is applied to prevention and treatment of frostbite of field operating personnel in high-cold regions. The preparation method comprises the following step: reacting anhydrous copper chloride, polyvinylpyrrolidone and thiourea to obtain copper sulfide. The preparation method comprises the following steps: dispersing copper sulfide, polymerizing dopamine hydrochloride in an alkaline oxygen-containing environment to gather on the surface of the copper sulfide so as to form polydopamine copper sulfide (PDA-coated CuS), adding N 'N-methylene bisacrylamide and ammonium persulfate, stirring, pouring into a mold, and polymerizing in an environment of 60 DEG C, thereby obtaining PDA-coated CuS / Pro / PAM gel. CuS and PDA are combined, so that the biocompatibility and antibacterial property of CuS are enhanced, the photo-thermal property of dopamine is improved, and proline is used as an antifreeze agent to destroy hydrogen bonds of water molecules and inhibit formation of ice crystals. The medical gel dressing has the beneficial effects that the medical gel dressing with the anti-freezing, rewarming and antibacterial functions can be used in a low-temperature environment of-24 DEG C, and a good rewarming environment is provided for a frostbite part.

The application belongs to the technical field of dental antibacterial materials, and discloses a kind of nanometer composite antibacterial coating for dental material and preparation method thereof.Method: monomer modified arginine, monomer N-isopropyl acrylamide, monomer methyl hexyl acrylate, initiator azobisdimethylamino propanamide hydrochloride, dispersing agent cetyltrimethylammonium bromide and crosslinking agent N,N-methylene bis(acrylamide) are dissolved in water, and the reaction is carried out under protective atmosphere, dialysis, to obtain nanogel dispersion;The nanogel dispersion is mixed with the nanometer zinc oxide dispersion to obtain a nanogel composite zinc oxide antibacterial coating, and a coating is formed after coating.The nanometer composite antibacterial coating for dental material has excellent retention capacity and antibacterial performance.

The invention discloses a self-repairing gel foam system and a preparation method thereof. The self-repairing gel foam system is composed of 0.3% of lauryl sodium sulfate, 3% of alpha-starch, 3% of acrylamide monomer, 0.1% of N, N '-methylene bisacrylamide cross-linking agent, 0.2% of potassium persulfate initiator and 0.002% of 30nm nano SiO2 particles modified by 0.05 wt% of fatty alcohol-polyoxyethylene ether. The preparation method comprises the following steps: enabling modified starch, acrylamide and the like to react to form starch gel, adding lauryl sodium sulfate and modified nano SiO2, and stirring to obtain the modified starch gel. Gel macromolecular aggregates in the system form a three-dimensional network structure, nanoparticles are uniformly dispersed on the surface of a liquid film to form a gas-liquid-solid three-phase skeleton, and a self-repairing function is realized through a hydrogen bond dynamic effect, so that bubble coalescence can be inhibited, and the capabilities of resisting hypersalinity, high temperature, gas condensate and methanol are enhanced; the problems that traditional foam is poor in stability and free of self-repairing capacity are solved, and the drainage gas recovery requirements of complex working conditions of western gas fields are met.

The invention discloses an anti-swelling cellulose-based supramolecular ion hydrogel sensing material as well as a preparation method and application thereof. The method comprises the following steps: esterifying hydroxypropyl methyl cellulose in ethyl acetate by using acryloyl chloride to obtain hydroxypropyl methyl cellulose acrylate; the preparation method comprises the following steps: dissolving 1-vinyl imidazole and 3-bromopropionic acid in N, N-dimethylformamide to prepare an imidazole ionic liquid; the preparation method comprises the following steps: dissolving hydroxypropyl methyl cellulose acrylate in deionized water, adding imidazole ionic liquid, acrylic acid, N, N-methylene bisacrylamide and ammonium persulfate, and reacting to obtain the anti-swelling cellulose-based supramolecular ionized water gel sensing material. The anti-swelling cellulose-based supramolecular ion hydrogel sensing material prepared by a free radical copolymerization strategy has the characteristics of good strength, flexibility, swelling resistance, freezing resistance, antibacterial property, biocompatibility, high conductivity, high sensitivity and strong environmental adaptability.

The application relates to preparation of indoor potted solid water and belongs to the field of solid water preparation. A preparation method is as follows: nitrogen is introduced into a four-necked flask for 10 min to remove air, wheat bran and wheat B starch wastewater are added, heating and stirring are carried out, sodium alginate and gellan gum are added to prepare A liquid; acrylic acid is neutralized by adding 25% NaOH solution under the condition of an ice water bath, after the neutralized liquid is cooled to room temperature, 2-acrylamide-2-methylpropanesulfonic acid, bentonite, methylene bisacrylamide and potassium persulfate are added to prepare B liquid; B liquid is slowly added into A liquid, heating and stirring are carried out to perform polymerization reaction, after the reaction is completed, filtration is carried out, anhydrous ethanol and distilled water are used for washing, and indoor potted special solid water is obtained. The indoor potted solid water provided by the application can provide convenience for office workers to maintain potted plants, can improve soil permeability and water absorption and water retention capacity, has a long use period, and is prepared by using natural degradable materials and has low cost.

The invention relates to the technical field of lithium ion battery key materials, in particular to a cross-linked polyacrylic acid / polyvinyl alcohol composite binder and a preparation method and application thereof. The binder is prepared by introducing N, N-dimethylformamide into a water-soluble acrylic monomer, an ethylenically-bond-containing acrylonitrile monomer and a vinyl ester monomer through ternary polymerization; n, N-methylene bisacrylamide (MBA) forms a rigid-flexible three-dimensional chemical cross-linked network, and then the rigid-flexible three-dimensional chemical cross-linked network and polyvinyl alcohol (PVA) construct an interpenetrating network (IPN) through hydrogen-bond interaction. The dual cross-linked network has the structural stability of chemical cross-linking and the dynamic adaptability of physical cross-linking, when the charging and discharging volume of the silicon-based negative electrode changes, stress is dissipated through network elastic deformation, meanwhile, interface bonding is strengthened through the ionic bond action of a lithium carboxylate group, active substance falling and electrode pulverization are inhibited, and the service life of the silicon-based negative electrode is prolonged. And the cycle life of the high-energy-density lithium ion battery is remarkably prolonged.