475 results about "Methylene bisacrylamide" patented technology

The invention relates to the technical field of oilfield chemistry, and discloses a graft modified cellulose filtrate reducer and a preparation method thereof.The preparation method comprises the following steps that modified hydroxyethyl cellulose, 2-acrylamide-2-methyl propane sulfonic acid, dimethyl diallyl ammonium chloride, alkenylated cardanol and N, N '-methylene bisacrylamide are added into deionized water, stirring is conducted, and a mixture is obtained; the preparation method comprises the following steps: adding cellulose into a reaction kettle, stirring for 10-15 minutes at the temperature of 40-60 DEG C at the speed of 300-400 rpm, dropwise adding ammonium persulfate and sodium hydrogen sulfite into a system, and continuously reacting for 4-6 hours to obtain the grafted modified cellulose filtrate reducer. The filtrate reducer disclosed by the invention has good high temperature resistance and salt resistance.

The invention discloses a hydrogel patch for gastric perforation repair and a preparation method thereof, and belongs to the technical field of biomedical materials. The preparation method comprises the following steps: dissolving acryloyl valine, acrylic acid, methylene bisacrylamide, a compound A and a photoinitiator in an alcohol solvent, and defoaming to obtain a precursor solution; and placing the precursor solution in a mold, carrying out ultraviolet-induced curing, soaking the obtained hydrogel in a hydrochloric acid solution, and replacing the alcohol solvent to obtain the hydrogel patch for gastric perforation repair. The hydrogel patch provided by the invention has the advantages of strong acid corrosion resistance, good biocompatibility, low swelling ratio, stable adhesion performance in a fluctuating pH environment and the like. The tough and stable adhesion performance ensures that the hydrogel can be permanently and reliably adhered to a gastric perforation part in a dynamic gastric acid environment, and a stable platform is provided for drug delivery, so that the surgical operation time is expected to be shortened, and wound healing is promoted.

The invention relates to the technical field of functional polymer composite materials, and provides diatomite modified composite super absorbent and rapid absorbent resin and a preparation method thereof. The preparation raw materials of the diatomite modified composite high-water-absorption and rapid-water-absorption resin provided by the invention comprise acrylic acid, acrylamide, sodium hydroxide, N, N '-methylene bisacrylamide, ammonium persulfate and modified diatomite. The diatomite is modified by the silane coupling agent, the agglomeration problem of the diatomite is solved, the compatibility with organic monomers is improved, and the modified diatomite, acrylic acid and acrylamide are utilized to construct an organic-inorganic synergistic three-dimensional porous network structure, so that the resin has ultrahigh water absorption rate, rapid water absorption performance and good water retention stability. Meanwhile, the preparation method disclosed by the invention does not need nitrogen protection, has the advantages of simple process, controllable raw material cost and easiness in industrial mass production, and is suitable for multiple fields such as water-saving agriculture, soil moisturizing, landscaping and the like.

The invention relates to the technical field of fertilizer slow release, and discloses a temperature-responsive starch-based gel coated slow-release fertilizer, which comprises the following raw materials: amorphous starch: a starting material is common corn starch; the cross-linking agent is N, N '-methylene bisacrylamide (MBA); n-isopropylacrylamide (NIPAM) is used for endowing the gel with temperature responsiveness; acrylamide (AM): as a comonomer to improve gel performance; the urea is used as a core component of the slow-release fertilizer; the absolute ethyl alcohol is used for wetting the surface of urea and promoting uniform coating of the SNA powder. According to the invention, the gel can automatically adjust the internal microporous structure according to different soil temperatures, so as to accurately control the release rate of nutrients, effectively solve the problem that the traditional slow release fertilizer cannot dynamically adjust the nutrient release according to the environmental change, and meet the differentiated demands of plants for nutrients in different growth stages.

The invention relates to the technical field of biomedical dressings, in particular to a dressing for a diabetic foot wound surface and a preparation method of the dressing. 0.2 to 0.8 part of reduced graphene oxide; 2 to 5 parts of beta-1, 3-glucan modified by chondroitin sulfate; 0.08 to 0.3 part of silver nitrate; 3 to 7 parts of N-isopropyl acrylamide-co-acrylic acid; 0.15 to 0.4 part of N, N '-methylene bisacrylamide; 2 to 5 parts of sulfhydrylated hyaluronic acid; 0.3 to 0.8 part of D-alpha-vitamin E polyethylene glycol succinate; 2 to 5 parts of amino-functionalized mesoporous silica; 1 to 3 parts of L-arginine-L-glutamate; 0.1 to 0.4 part of genipin; the super-strong mechanical property and the super-strong flexibility are realized, so that the dressing can better adapt to the irregular shape of a wound surface, and continuous protection is provided.

The invention discloses a preparation method and application of a photo-thermal dual-response membrane material, and relates to the field of membrane materials. When the photo-thermal double-response membrane material is prepared, a photo-thermal material firstly reacts with 4-(triethoxysilyl) aniline and then reacts with 2, 4, 6-trihydroxy-1, 3, 5-benzenetricarboxaldehyde and p-phenylenediamine, and a modified photo-thermal material is prepared; the preparation method comprises the following steps: sequentially reacting benzaldehyde with 2-hydroxyacetophenone and 3-N, N-dimethylamino methacryloyl chloride to prepare a photo-initiation monomer; the preparation method comprises the following steps: mixing N-isopropylacrylamide, a photo-initiation monomer, N, N '-methylene bisacrylamide and a modified photo-thermal material, combining with a hydrophobic substrate membrane, preparing a membrane, and finishing the surface by using 2-bromo-1-[3, 5-di (tert-butyl)-4-hydroxyphenyl] ethanone, thereby obtaining the photo-thermal dual-response membrane material. The photo-thermal dual-response membrane material prepared by the invention has the characteristics of pollution resistance, easiness in cleaning, durability, antibacterial property, metal ion recovery and low energy consumption.

The invention belongs to the technical field of lithium ion battery solid electrolytes, and discloses a multi-component in-situ polymerized gel solid electrolyte and a preparation method and application thereof, the gel solid electrolyte is prepared by adding an amide cross-linking agent and a polymeric monomer into a basic electrolyte to obtain a precursor solution, then adding an initiator, and carrying out in-situ polymerization at 45-70 DEG C for 6-12 hours, the amide cross-linking agent is one or more of N, N '-methylene bisacrylamide, polyacrylamide, poly (2-acrylamide-2-methyl-1-propanesulfonic acid), polymethacrylamide, polyethylene glycol diacrylamide, polyether amide or adipamide. The first coulombic efficiency of an LCOLi button cell assembled by the multi-component in-situ polymerization solid-state gel electrolyte reaches 94.81%, the capacity retention rate after 500 cycles at 3-4.6 V still reaches 80% or above, and the LCOLi button cell can safely pass a needle test and can be applied to the field of solid-state electrolytes.

The invention discloses an antibacterial composite material for water treatment and a preparation method thereof in the technical field of composite materials, and the antibacterial composite material is prepared from the following components in parts by weight: 20-25 parts of a magnetic nano material, 19-22 parts of acrylic acid, 6-9 parts of allylamine, 1.8-2.2 parts of N, N '-methylene bisacrylamide, 1.3-1.6 parts of azodiisobutyronitrile and 4.3-5.5 parts of plant polyphenol. Cobalt ferrite is used as a magnetic core to prepare a magnetic nano material to improve the recovery rate, acrylic acid and allylamine are used as polymeric monomers to form a polymer layer with high adsorption capacity, and plant polyphenols are combined on the surface, so that the adsorption performance and the catalytic decomposition performance are enhanced, and the antibacterial effect of the material is improved at the same time; further, the composite material with the functions of adsorbing heavy metal ions, decomposing organic pollutants and resisting and inhibiting bacteria is obtained.

The invention belongs to the technical field of energy storage system device materials, and particularly relates to a modified silk amino acid-based gel electrolyte as well as a preparation method and application thereof. The method comprises the following steps: S1, uniformly mixing and stirring 15 to 30g of acrylamide, 50 to 60g of zinc sulfate heptahydrate, 0.1 to 1g of silk amino acid and 100g of water; adding 5mL to 10mL of ethanol, and uniformly shaking; then sequentially adding a proper amount of N-N methylene bisacrylamide and a photoinitiator, and continuously stirring until the solution is clear to obtain an electrolyte; s2, dropwise adding the prepared electrolyte into a polytetrafluoroethylene (PTFE) plate, and covering the polyurethane fiber membranes obtained by electrostatic spinning on the two sides; and carrying out light curing under ultraviolet irradiation to obtain the modified silk amino acid (M-SAA) gel electrolyte. According to the invention, silk amino acid (SAA) is introduced to construct a compact protective film with a beta folding structure, so that zinc dendrite growth and side reaction are inhibited, and the stability of the zinc negative electrode of the battery and the cycle performance of the battery are improved.

The invention relates to the technical field of oilfield chemistry and high-temperature and high-salt oil reservoir profile control and water shutoff, in particular to a preparation method, a product and application of polymer gel particles with enhanced mechanical properties through a double-crosslinking domain structure. The preparation method comprises the following steps: dissolving a monomer, a cross-linking agent and an initiator in water, and carrying out free radical polymerization reaction to obtain polymer hydrogel; and drying the polymer hydrogel to obtain the polymer gel particles, the monomers comprise acrylamide, acrylic acid, N-(hydroxymethyl) acrylamide and 2-acrylamide-2-methylpropanesulfonic acid; the cross-linking agent comprises methacrylic acid esterified lignosulfonate and / or N, N '-methylene bisacrylamide. The preparation method disclosed by the invention is simple, and the polymer gel particles prepared by utilizing the method have a unique double-crosslinking domain structure, have excellent mechanical properties and excellent temperature resistance and salt tolerance, and are suitable for profile control and water shutoff of high-temperature and high-salt oil reservoirs.

The invention relates to the technical field of ceramics, in particular to aluminum oxide ceramic slurry as well as a preparation method and application thereof. The aluminum oxide ceramic slurry is prepared from alpha-aluminum oxide coarse powder, alpha-aluminum oxide fine powder, modified aluminum oxide powder, acrylamide, N, N '-methylene bisacrylamide and deionized water, multiple active functional groups are introduced into the surface of the modified aluminum oxide powder, interface bonding of particles with a dispersion medium and a polymer monomer is enhanced, and the surface of the particles is improved. According to the present invention, with the preparation method, the particle agglomeration tendency is reduced, such that the slurry can maintain the low viscosity under the high solid content condition so as to meet the gel injection molding process requirements, and the sintering body obtained through the gel injection molding has characteristics of high bending strength and high hardness, and can be widely used in the fields of electronic devices, mechanical sealing members, biomedical apparatuses and instruments, and the like.

The invention relates to the technical field of microsphere profile control agents, in particular to a high-temperature-resistant polymer microsphere profile control agent and a preparation method thereof. At the temperature higher than 70 DEG C, the structure of a conventional polyacrylamide microsphere is easily degraded, and the water channeling phenomenon cannot be slowed down in the water injection and oil extraction process. In order to solve the technical problems, the invention provides the high-temperature-resistant polymer microsphere profile control agent, the structure of the high-temperature-resistant polymer microsphere profile control agent is a microsphere obtained by reacting acrylamide, allylamine, nitrogen-nitrogen methylene bisacrylamide and activated carbon quantum dots under a reverse emulsion polymerization condition, and the carbon quantum dots are mainly introduced into a polyacrylamide microsphere molecular structure, so that the high-temperature-resistant polymer microsphere profile control agent is prepared. The carbon quantum dots can play a role in supporting a framework in a high-temperature environment, the stability of the polyacrylamide microspheres at the high temperature can be effectively improved, it is ensured that the profile control agent effectively plays a water plugging role in the high-temperature water injection oil extraction process, and the water channeling phenomenon is remarkably reduced.

The invention discloses chitosan-based conductive hydrogel and a preparation method thereof.The method comprises the steps that chitosan is added into isopropanol, after a primary reflux reaction, an aqueous solution of 2, 3-epoxypropyltrimethylammonium chloride is added, a secondary reflux reaction continues, and quaternary ammonium chitosan is prepared; the preparation method comprises the following steps: adding quaternary ammonium chitosan into an aqueous solution of acrylic acid, stirring and dissolving, adjusting the pH value of a system to 7, then adding an aqueous solution of polyvinyl alcohol, stirring uniformly, adding ammonium persulfate and N, N '-methylene bisacrylamide, stirring and fully dissolving to obtain a hydrogel precursor; and performing polymerization treatment on the hydrogel precursor, and soaking the hydrogel precursor in a mixed solution of potassium hydroxide and zinc acetate to prepare the chitosan-based conductive hydrogel. The preparation process is simple, and the problems of insufficient conductivity, weak mechanical property and insufficient stability of the biomass-based hydrogel are systematically solved through quaternization modification, a multi-crosslinking strategy and electrolyte post-treatment.

The invention belongs to the technical field of thermoelectric materials and functional polymer materials, and particularly relates to thermoelectric hydrogel based on synergistic enhancement of zwitterions and a polar solvent as well as a method and application of the thermoelectric hydrogel. The thermoelectric hydrogel is obtained through the steps that a precursor solution is subjected to a polymerization reaction to form a gel matrix, then the gel matrix is soaked in a soaking solution, potassium ferricyanide / potassium ferrocyanide redox couple is introduced, and the thermoelectric hydrogel is obtained, and the precursor solution is prepared from acrylamide, N-isopropylacrylamide, dimethyl sulfoxide, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide and N, N-dimethylformamide. The photoinitiator is prepared by mixing N, N-dimethylformamide, 1-ethyl-3-methylimidazolium tetrafluoroborate, a zwitterionic monomer [2-(methylacryloyloxy) ethyl] dimethyl-(3-sulfopropyl) ammonium hydroxide, a cross-linking agent N, N '-methylene bisacrylamide, a photoinitiator and deionized water. The thermoelectric hydrogel prepared by the invention has high mechanical strength, high ductility and high Seebeck coefficient, and has better temperature resistance.

The invention relates to an intelligent composite material diaphragm as well as a preparation method and application thereof. The intelligent composite material diaphragm comprises a shape memory polymer foam skeleton and a gel electrolyte filled in the shape memory polymer foam skeleton, the shape memory polymer foam skeleton is prepared from the following raw materials: epoxy resin and a D-230 curing agent; the gel electrolyte is prepared from the following raw materials: N-isopropylacrylamide, acrylamide, N, N '-methylene bisacrylamide, ammonium persulfate, tetramethylethylenediamine and a lithium salt solution. The intelligent composite material diaphragm can perform real-time response according to the temperature change in the working process of the battery, adjust the ionic conductivity to control the output power of the battery, provide over-temperature protection, have an automatic thermal protection function, further have a function of inhibiting the growth of lithium dendrites, can prolong the service life of the battery, and is suitable for popularization and application. And the battery is especially suitable for battery application scenes with high energy density and high safety requirements.

The invention discloses high-strength deformable porous hydrogel for postoperative abdominal cavity tissue effusion drainage, belongs to the technical field of medical porous hydrogel, and particularly relates to a temperature-sensitive hydrogel reaction solution obtained by adding a monomer, a cross-linking agent and an initiator into water and mixing, and freezing and polymerizing to obtain ice gel; treating the ice gel in a salting-out solution to obtain porous hydrogel; the cross-linking agent is prepared from at least one of N, N-methylene bisacrylamide, N, N-methylene bisacrylamide and polyethylene glycol diacrylate. The invention provides the high-strength deformable porous hydrogel for postoperative abdominal cavity tissue effusion drainage, which has a temperature-sensitive effect, can be dynamically controlled through electric heating, and has good mechanical properties and a good drainage effect.

The invention discloses a UV photocuring adhesive, a preparation method thereof and an application of the UV photocuring adhesive in the electronic field, and relates to the field of adhesives. The preparation method comprises the following steps: when the UV photocuring adhesive is prepared, carrying out a reaction on dihydroxyl modified 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, p-phenylene diisocyanate, polyethylene glycol and 2-ethyl-4-methylimidazole, so as to obtain imidazole-terminated isocyanate, and carrying out a reaction on the imidazole-terminated isocyanate and the 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, so as to obtain the UV photocuring adhesive. The modified lignin, butanediamine and N, N '-methylene bisacrylamide are subjected to a reaction, and a double-bond reactant is prepared; the preparation method comprises the following steps: reacting epoxy-terminated siloxane with octamethylcyclotetrasiloxane, tetramethyltetravinyl cyclotetrasiloxane and tetramethylammonium hydroxide to obtain modified siloxane, and finally, uniformly mixing imidazole-terminated isocyanate, a double-bond reactant, modified polysiloxane and benzoin butyl ether to obtain the polyurethane adhesive. The UV light-cured adhesive prepared by the invention has good adhesive property, anti-aging property and flame retardant property.

The invention discloses a core-shell structure P (MMA-MBA) copolymer heat-storage phase-change microcapsule, the microstructure is of a spherical structure, the core-shell structure is adopted, the core structure is hexadecane, the shell structure is a methyl methacrylate (MMA) and N, N-methylene bisacrylamide (MBA) copolymer, the emulsifier is lauryl sodium sulfate (SDS), the initiator is potassium persulfate, and the pH value of the core-shell structure P (MMA-MBA) copolymer heat-storage phase-change microcapsule is 7-8. And the coating efficiency is 70-75%. The preparation method comprises the following steps: 1, preparing an oil phase and a water phase; and 2, polymerization reaction of the microcapsule. A phase change cement material based on a core-shell structure P (MMA-MBA) copolymer heat storage phase change microcapsule is prepared by compounding the P (MMA-MBA) copolymer heat storage phase change microcapsule and a cement matrix, and has hydrophobicity; obvious weightlessness exists in two times.

The invention relates to the field of copper plating solutions, and provides a low-stress chemical copper plating solution for a glass substrate and a preparation method of the low-stress chemical copper plating solution. The invention discloses a copper ion carboxyl chelate, which is composed of copper ion carboxyl chelate, 2, 2 '-bipyridine, polyethylene glycol-8000, lauryl sodium sulfate, a sodium carbonate buffer agent, deionized water and a pretreatment solvent, and the copper ion carboxyl chelate is prepared by chelating a polyacrylate-itaconic acid copolymer with copper chloride and then carrying out stepwise cross-linking with epichlorohydrin and N, N'-methylene bisacrylamide. The copper-bis-salicylaldehyde ethylenediamine complex is obtained by reacting bis-salicylaldehyde ethylenediamine with copper acetate, crystallizing and purifying. The preparation method comprises the steps of solvent premixing, chelating activation, staged additive integration, pH dynamic regulation and control and plating solution purification, through nitrogen protection, high-shear stirring and accurate pH regulation, the problems that a traditional chemical copper plating layer is high in stress and poor in conductivity are solved, and the method is suitable for high-precision glass substrate surface metallization.

The invention discloses a preparation method of an environment-friendly lithium battery fire extinguishing agent based on nanofiber gel, and relates to the technical field of fire extinguishing. When the environment-friendly lithium battery fire extinguishing agent is prepared, nano sodium carboxymethyl cellulose reacts with N-isopropylacrylamide and N, N-methylene bisacrylamide to prepare semi-interpenetrating network hydrogel; the semi-interpenetrating network hydrogel and calcium lactate are cross-linked, and nano sodium carboxymethyl cellulose hydrogel is prepared; and mixing and stirring the nano sodium carboxymethyl cellulose hydrogel, the modified silicon carbide and a flame retardant to prepare the environment-friendly lithium battery fire extinguishing agent. The prepared environment-friendly lithium battery fire extinguishing agent has good fire extinguishing performance.

The invention relates to the technical field of hydrogel, in particular to a preparation method of a high-moisture-retention polyoxyethylene modified polyacrylate gel film, and the preparation method comprises the following steps: S1, adding acrylate, ammonium persulfate and N, N '-methylene bisacrylamide, and carrying out primary cross-linking to obtain a pre-cross-linked solution; s2, adding modified nano montmorillonite to obtain a reaction solution; s3, adding a polyoxyethylene solution, and carrying out secondary crosslinking to obtain a dry film; and S4, soaking the dry film obtained in the step S3 into a sodium chloride solution for 6-24 hours to obtain the high-moisture-retention polyoxyethylene modified polyacrylate gel film. The prepared high-moisture-retention polyoxyethylene modified polyacrylate gel film forms a high-strength cross-linked structure, and is high in mechanical property and high in ionic conductivity.

The invention relates to high-strength degradable self-healing hydrogel and a preparation method thereof, and belongs to the technical field of high polymer materials. The hydrogel is prepared from the following components in percentage by mass: 15 to 20 percent of carboxymethyl cellulose, 10 to 14 percent of acrylic acid, 15 to 20 percent of N-isopropylacrylamide, 4 to 8 percent of tannic acid, 2 to 4 percent of borax, 0.06 to 0.1 percent of laccase, 0.5 to 1 percent of N, N-methylene bisacrylamide, 0.4 to 0.6 percent of potassium persulfate and the balance of phosphate buffer solution. According to the hydrogel disclosed by the invention, through dual-network structure design, dynamic covalent bond crosslinking and enzyme catalysis green synthesis, collaborative optimization of high strength, high self-healing property, degradability and multi-responsiveness is realized, and the problems of poor mechanical property, low repairing efficiency, environmental unfriendliness and the like of traditional hydrogel are solved; the method has wide application potential in the fields of biomedicine, flexible electronics, intelligent packaging and the like.

The invention provides a multifunctional plugging agent for oil wells with medium and high water content and a preparation method of the multifunctional plugging agent. The plugging agent is prepared from the following substances in percentage by weight: 1-10% of high-strength nano gel particles, 2-5% of nano silicon dioxide dispersion liquid, 1-5% of PPG chitosan pre-crosslinking particles, 1-5% of guanidine gum dry powder, 1-2% of active calcium magnesium aluminum silicate, 0.5-1% of active silica gel, 0.5-1% of sodium sulfonate, 0.1-1% of a crosslinking regulator and the balance of water. Chitosan and cellulose nanocrystals are compounded for use, so that the strength of PPG chitosan pre-crosslinked particles is greatly improved. Chitosan reacts with an acrylamide monomer, 2-acrylamido-2-methylpropanesulfonic acid and a cross-linking agent methylene bisacrylamide to generate a double-network polymer product, so that the gel strength is greatly improved, and higher pressure bearing capacity, plugging capacity, scouring resistance and the like are achieved. Through the synergistic effect of all the components, the plugging water control effect is improved, water is plugged, oil is not plugged, and the plugging agent has important significance on plugging water control in the extra-high water cut period and improvement of oil well productivity.

The invention discloses thermal stimulation response hydrogel and a preparation method thereof, and belongs to the technical field of high polymer materials. The preparation method comprises the following steps: dissolving acryloyl valine, acrylamide, methylene bisacrylamide and a photoinitiator in an organic solvent, and defoaming to obtain a precursor solution; and S2, putting the precursor solution into a mold, carrying out ultraviolet light-induced curing, soaking the obtained hydrogel in an acid solution, replacing the organic solvent, and then carrying out heat treatment to obtain the thermal stimulation response hydrogel. Compared with other existing thermal response type hydrogel, the thermal response type hydrogel has the advantages that the fracture stress, the modulus, the tensile work and the like are remarkably improved in the order of magnitude level, and excellent comprehensive mechanical properties are shown. The thermally-induced hardening hydrogel developed by the invention has a wide application prospect in the field of engineering devices requiring higher modulus and requiring significant change of mechanical properties before and after heating.

The invention relates to the technical field of textile chemicals, in particular to an electrolyte-resistant printing thickening agent for improving the coloring effect and a preparation method thereof.The electrolyte-resistant printing thickening agent is prepared from, by weight, 10-20 parts of methacrylic acid, 15-30 parts of triethanolamine, 0.1-0.5 part of N, N '-methylene bisacrylamide, 4-8 parts of functional monomers and 2-5 parts of organic modified nano bentonite. 3-6 parts of an emulsifier, 0.1-0.6 part of sodium hydrogen sulfite, 0.1-0.6 part of sodium persulfate, 8-15 parts of an oil-phase solvent, 2-5 parts of a reverse-phase emulsifier and 30-50 parts of water; the functional monomer is prepared from p-styrene propanesulfonic acid, 2-acrylamide-2-methyl propanesulfonic acid and triphenylethyl phenol polyoxyethylene ether methacrylate according to the weight ratio of (3 to 5) to (1 to 2) to 1. According to the electrolyte-resistant printing thickening agent capable of improving the coloring effect, through matching and combination of the raw materials, the electrolyte resistance of the thickening agent can be improved, and the coloring effect in textile printing is improved.

The invention relates to the technical field of blood purification materials, in particular to a zirconium-titanium bimetal MOF hollow microsphere adsorbent and a preparation method and application thereof. The adsorbent is based on a Zr / Ti bimetallic node and a phosphonic acid-carboxylic acid mixed ligand, a composite MOF hollow microsphere structure with high stability and high specific surface area is constructed through a solvothermal and polymerization synergistic reaction in a water-in-oil suspension system, a phosphonic acid group and Zr are strongly coordinated to improve the stability of a framework, and the composite MOF hollow microsphere structure has a high specific surface area. The carboxylic acid group keeps the hydrophilicity of the pore channel; meanwhile, a cross-linked network of acrylamide and N, N '-methylene bisacrylamide penetrates through crystal gaps in the balling process, so that the material has excellent mechanical strength and fluid stability; and a sulphobetaine amphoteric polymer brush layer is constructed on the surface of the MOF through endogenous initiation point modification and surface in-situ controllable free radical polymerization technologies, so that protein adsorption and platelet adhesion are effectively inhibited, the blood compatibility is remarkably improved, and meanwhile, the channel accessibility is maintained to promote rapid diffusion and adsorption of bilirubin.

The invention discloses a flexible self-powered triboelectric sensor, and belongs to the technical field of sensors, the flexible self-powered triboelectric sensor comprises a first silicone rubber layer, a hydrogel layer, a conductive silica gel electrode layer and a second silicone rubber layer which are sequentially arranged from top to bottom, the hydrogel layer is prepared from N-isopropylacrylamide (NIPAM), N, N-dimethylacrylamide (DMAA), N, N-dimethylacrylamide (DMAA), N, N-dimethylacrylamide (DMAA) and N, N-dimethylacrylamide (DMAA); n, N '-methylene bisacrylamide (MBA) and sodium alginate (SA) are copolymerized to form a three-dimensional network, in-situ embedding of biological source orange juice carbon dots is initiated through ultraviolet light, and the first silicone rubber layer, the hydrogel layer, the conductive silica gel electrode layer and the second silicone rubber layer are bonded and fixed on the periphery through silica gel. The invention discloses a green, safe and high-performance flexible triboelectric sensor, which realizes excellent electrical output through a simple process and is combined with an advanced signal processing technology to realize accurate recognition of multiple key physiological signals by a single sensor.

The invention discloses 3D printing direct writing ink capable of intelligently responding to hydrogel, which comprises the following components in parts by weight: 100 parts of water; 0.5 to 2.8 parts of carbomer; 6.8 to 18 parts of a hydrogel monomer N-isopropylacrylamide; 0.001 to 0.006 part of sodium hydroxide serving as a pH regulator; 0.005 to 0.02 part of a cross-linking agent, namely methylene bisacrylamide; 0.00625 to 0.0125 part of ammonium persulfate serving as an initiator; 0.00125 to 0.00375 parts of pyrrole; carbomer serves as a dispersing agent to inhibit pyrrole molecule agglomeration, pyrrole and an initiator ammonium persulfate have a synergistic effect in a polymerization reaction, a polypyrrole photo-thermal phase is generated in situ, thermal polymerization and crosslinking of a hydrogel monomer N-isopropylacrylamide are initiated, and a uniformly dispersed double-gel network is formed; through optimization of synergistic polymerization of pyrrole and ammonium persulfate and design of a carbomer dispersant, in-situ uniform dispersion of a photo-thermal phase and synchronous crosslinking of a gel network are realized, the photo-thermal conversion efficiency and material uniformity are improved, use of a toxic coagulant is avoided, the window period of 3D printing is prolonged, swelling deformation is inhibited, and the material is suitable for the fields of intelligent 4D printing, drug loading and bionic robots.

The invention discloses a preparation method and application of a gelling capillary capillary crystallization type waterproof agent based on a nano material, and belongs to the technical field of building materials. The waterproof agent is prepared from the following raw materials: carbonate, calcium salt, sodium silicate, disodium ethylene diamine tetraacetate, L-aspartic acid, a cross-linked polymer and water. The cross-linked polymer is composed of an acrylic monomer, a sodium acrylate monomer, N, N '-methylene bisacrylamide, polyvinyl alcohol, distilled water and an initiator. A novel gelatinization capillary crystallization waterproof strategy is provided, the waterproof performance, strength and durability of the cement-based material can be remarkably improved, and the method has the advantages of being simple in preparation process, low in cost, environmentally friendly, harmless and the like.

The invention discloses zwitterionic concrete internal curing hydrogel based on humidity-pH dual responsiveness and a preparation method of the zwitterionic concrete internal curing hydrogel, and belongs to the technical field of building materials. The water-based cleaning agent is prepared from the following raw material components in percentage by weight: 6%-8% of N-vinyl imidazole, 8%-12% of 2-methylimidazole, 6%-8% of 2-acrylamido-2-methylpropanesulfonic acid, 2%-4% of sodium p-styrenesulfonate, 26%-30% of acrylic acid, 18%-21% of N-vinyl pyrrolidone, 15%-18% of glycidyl methacrylate, 2%-5% of nano montmorillonite powder, 0.05%-0.1% of divinyl benzene, 0.05%-0.15% of N, N-dimethylformamide and the balance of water. The invention discloses an anti-freezing agent which is prepared from the following components in percentage by weight: 0.1%-0.3% of N, N-methylene bisacrylamide, 0.1%-0.3% of 1-[4-(2-hydroxyethoxy)-phenyl]-2-hydroxy-2-methyl-1-propane-1-ketone, 0.5%-0.8% of ammonium persulfate and 0.5%-0.8% of sodium hydrogen sulfite. Double response to the internal humidity and pH value of the concrete can be achieved, and the requirement for precise internal curing of modern high-performance concrete is met.