970 results about "Tertiary amine" patented technology

The invention belongs to the technical field of pharmaceutical chemical processes, and particularly relates to a preparation method of a penem antibiotic intermediate 4-BMA, which comprises the following steps: adding Zn powder, chlorosilane, aliphatic tertiary amine, zinc salt and 4-AA in a formula (I) into THF (tetrahydrofuran), uniformly stirring, dropwise adding a THF solution of alpha-haloamide with an induction group in a formula (II) for reaction, filtering the reaction solution, removing the zinc powder, and drying to obtain the penem antibiotic intermediate 4-BMA. Extracting the filtrate to obtain a THF phase, washing with an aqueous solution of potassium oxalate, and recovering THF to obtain a formula (III); and carrying out oxidative hydrolysis, sulfur dioxide quenching, sulfur dioxide acid regulation crystallization and recrystallization on the formula (III) to obtain the intermediate 4-BMA. According to the preparation method disclosed by the invention, a zinc salt is used as a catalyst during preparation of the formula (III), potassium oxalate is used for removing residual Zn (II) in a THF phase, SO2 is used for quenching hydrogen peroxide and acid regulation and crystallization of 4-BMA, the oxygenolysis problem of 4-BMA is solved, and the preparation method has the characteristics of greenness, safety and high efficiency, is strong in product competitive advantage and is suitable for industrial production.

A photobase generator includes a compound including: first skeletons represented by the following formula (a); and a second skeleton including nitrogen atoms bonding to bonding positions of the first skeletons to form amide groups, wherein, in a molecule, a number of the first skeletons is two or more, a number of the nitrogen atoms, configuring the amide groups, in the second skeleton is the same as the number of the first skeletons, and at least one of the nitrogen atoms configuring the amide groups is converted into a nitrogen atom configuring a secondary amine or a tertiary amine by light irradiation. In the formula (a), G is a divalent aromatic group, and * represents the bonding position with the nitrogen atom.

The preparation method comprises the following steps: mixing 20-40 parts by mass of substituted hydroxymethyl glycoluril, 45-85 parts by mass of mercaptocarboxylic acid and 0.5-3 parts by mass of an acidic catalyst, stirring and reacting for 1-10 hours at the temperature of 50-150 DEG C under the pressure condition of-0.01 to-0.1 MPa, adding 300-800 parts by mass of an organic solvent for diluting after the reaction is finished, washing and purifying with deionized water, and collecting an organic layer, thereby obtaining the mercaptan curing agent. Concentrating and drying to obtain the mercaptan curing agent. According to the thiol curing agent, the rigid glycoluril group is introduced, so that the rigidity of a cured product structure is improved, and the mechanical property, the adhesive property, the heat resistance and the damp-heat aging resistance of a cured product are improved; four tertiary amine groups in the substituted glycoluril have a certain self-promotion effect on a thiol curing epoxy reaction, and the curing reaction temperature is reduced under the condition that an accelerant is not added; the glycoluril-containing thiol epoxy resin curing agent disclosed by the invention has good application value and development prospect.

The invention relates to an impact-resistant chlorinated polyvinyl chloride composite material and a preparation method thereof, and belongs to the technical field of polymer composite materials. The composite material comprises the following components: 100 parts of CPVC resin, 6.5 to 9.5 parts of a modified impact modifier, 2.6 to 3.2 parts of a heat stabilizer, 1.5 to 2 parts of a lubricant, 1.2 to 1.6 parts of a processing aid, 0.2 to 0.25 part of a light stabilizer and 8 to 11 parts of a filler, the modified impact modifier takes a POSS cage structure as a core, a branch chain sequentially contains thioamide-secondary amine-tertiary amine structures, a polarity gradient is formed and fully extends into a macromolecular chain of CPVC to transmit and dissipate impact energy, meanwhile, the amine structure interacts with chlorine groups in a molecular chain of CPVC to form molecular anchoring, expansion of crazes is inhibited, and the impact strength of the CPVC is improved. The continuity and the stability of a bonding interface are maintained, so that the composite material keeps relatively high mechanical strength and thermal stability.

The invention belongs to the technical field of coatings, and relates to a polysiloxane epoxy hybrid environment-friendly coating and a preparation method thereof. The coating belongs to an environment-friendly solvent type coating with low VOC content, modified epoxy resin is adopted as a base, auxiliaries such as a film-forming agent and a dispersing agent are added, and benzophenone and tertiary amine composite photoinitiator is supplemented, so that the prepared coating has good corrosion resistance, high temperature resistance and the like, and the coating can quickly form a film at normal temperature and under the UV illumination condition, shortens the curing period, and is suitable for large-scale popularization and application. The emission of VOC (volatile organic compounds) is reduced.

The invention discloses a two-phase absorbent and application thereof. The two-phase absorbent comprises the following components in percentage by mass: 10-35% of a main absorbent, 20-50% of a phase-splitting agent, 0-15% of an accelerant and 0-70% of water, wherein the total mass of the two-phase absorbent is 100%; wherein the main absorbent is polyamine, the polyamine contains more than three amino groups, more than three carbon atoms are arranged between the adjacent amino groups, and at least one of the more than three amino groups is a tertiary amino group; the phase splitting agent is an alcohol ether compound. The two-phase absorbent provided by the invention has better absorption performance, can reduce the generation of oxidative degradation, and has higher oxidation stability.

The invention discloses a kind of preparation method of amino hyperbranched siloxane and its modified polyimide aerogel material.First, alkoxysilane X with amino active functional group, alkoxysilane Y of inactive functional group and water are carried out autocatalytic controlled hydrolysis condensation under sub-stoichiometric ratio, obtain multifunctional group (such as other active groups, alkoxyl group, amino) amino hyperbranched siloxane liquid (HPSi NH2) with controllable amino content, then using HPSi NH2 as cross-linking agent and anhydride-terminated polyamic acid solution reaction to obtain functionalized polyamic acid, which is stirred with tertiary amine and deionized water to obtain functionalized polyamic acid wet gel, which is passed through freeze drying, high temperature imidization treatment to obtain amino hyperbranched siloxane modified polyimide aerogel material. This material has excellent flexibility, resilience, heat resistance and flame retardancy, and can be applied to aerospace, communication, catalysis and filtration fields.

The invention discloses a method for separating iron and lithium in a lithium iron phosphate iron salt leaching solution and recycling iron phosphate, and belongs to the technical field of waste lithium battery recycling. The method comprises the following steps: constructing a bis (2-ethylhexyl) phosphate and trioctyl decyl tertiary amine mixed extraction system for selective extraction of Fe < 3 + >, adopting phosphoric acid for reverse extraction, recycling phosphoric acid reverse extraction liquid, preparing iron phosphate and the like. According to the method, efficient enrichment of Fe < 3 + > and efficient elution of Fe < 3 + > from a loaded organic phase are realized. The purity of the raffinate Li solution is relatively high, so that the subsequent preparation of battery-grade lithium carbonate is facilitated. The strip liquor can be recycled for multiple times, an iron intermediate is precipitated through pH adjustment, and the FePO4 product can be finally prepared through washing, aging and high-temperature calcination. The method is high in extraction selectivity, recyclable in process and mild in operation condition, has good separation effect and resource utilization efficiency, and is suitable for popularization and application of a Fe / Li separation process in lithium battery recovery.

The invention belongs to the technical field of electrolyte materials, and particularly relates to a pH response biopolymer solid electrolyte as well as a preparation method and application thereof. The pH-responsive degradable biopolymer is taken as a main raw material, and one or more functional groups such as pyridine, sulfonic acid, carboxyl, tertiary amine, phosphoric acid and the like are contained. The organic acid and the organic acid salt are selected to adjust the pH value of a medium around the electrolyte, and the contraction / stretching behavior of a molecular chain is influenced by changing the ionization degree of the electrolyte, so that an interpenetrating polymer network structure is formed. The polar functional group of the biopolymer affects the migration behavior of lithium ions under different pH conditions, so that the migration rate and migration quantity of the lithium ions are increased, and the cycle performance of the battery is improved. The electrolyte is suitable for high-performance energy storage devices such as a lithium ion battery, can effectively improve the battery performance, reduces the environmental pollution, and has relatively strong green and environment-friendly advantages.

The invention relates to a continuous production process and device of vinylene carbonate, chloroethylene carbonate, tertiary amine and a solvent are continuously fed in a reactor for dechlorination reaction, and temperature is controlled by a tubular heat exchanger; the reaction liquid continuously overflows from a side overflow port to enter a middle receiving tank, a vinylene carbonate crude product is obtained after desolvation, the vinylene carbonate crude product enters a melt crystallizer for melt crystallization after being purified by a low-component removal tower, a high-component removal tower and a rectifying tower, and a vinylene carbonate product with the purity of 99.99% or above is obtained; a reaction by-product tertiary amine hydrochloride settles to the lower part of the reactor, is discharged from the bottom of the reactor after being subjected to countercurrent washing by inputting a solvent through a salt leaching cavity, enters a neutralization kettle, is neutralized by liquid caustic soda and then is subjected to liquid separation, an organic phase enters a recovery system to be dehydrated, and then sequentially passes through a solvent recovery tower to recover the solvent and a tertiary amine recovery tower to recover tertiary amine; and the solvent and the tertiary amine can be recycled. The continuous production of the vinylene carbonate is realized, the consumption of raw materials is reduced, and the yield and the production efficiency are improved.

The invention relates to the technical field of dry films, in particular to a photosensitive resin composition, a photosensitive dry film and a preparation method of the photosensitive dry film. Comprising alkali-soluble resin, a photopolymerizable monomer with at least one vinyl unsaturated group, a photosensitizer and other additives, and the alkali-soluble resin at least comprises a nitrogen-containing heterochain or nitrogen heterocyclic ring monomer chain segment group; the alkali-soluble adhesive resin containing aza-chain or azacyclo-containing monomer chain segment groups is prepared by introducing an aza-chain or azacyclo-containing monomer, such as a monomer containing primary amine, secondary amine, tertiary amine, quaternary ammonium salt, pyridines, imidazoles and other groups, into alkali-soluble resin, and is used for improving the adhesive force and binding force between the resin and the surfaces of metals such as copper and the like; therefore, the resolution and adhesion capability of the photosensitive resin composition or the photosensitive dry film is improved.

The invention discloses a preparation method and application of an oil-soluble heteropolyacid ionic liquid catalyst. The catalyst is composed of organic cations and inorganic anions, the cations are one of quaternary ammonium, imidazole and pyridine cations containing long-chain alkyl, the anions are heteropolyacid anions, the long-chain alkyl enables the catalyst to have good oil solubility, the catalyst can be efficiently dispersed in the waste grease, heteropolyacid provides active sites, and the catalyst can be used for treating the waste grease. Nano-scale active particles are formed after in-situ vulcanization, and the catalytic hydrogenation effect is achieved. The invention also provides a preparation method of the oil-soluble heteropolyacid ionic liquid catalyst, the catalyst can be prepared from tertiary amine and halogenated hydrocarbon through three-step reaction of alkylation, anion exchange and acid-base neutralization, the preparation process is simple, a highly toxic reagent is avoided, and the cost is low. The catalyst provided by the invention can be used for catalytic hydroisomerization of various waste oils and fats, has the characteristics of high conversion rate, low coking rate and high product calorific value, and has relatively high industrial application potential.

A UV curable inkjet ink including a free radical polymerizable compound and an acyl phosphine oxide initiator wherein the acyl phosphine oxide initiator includes an acyl group selected from the group consisting of a benzoyl group substituted by an urea group or an oxalylamide group; a 2,6-dimethyl benzoyl group substituted in position 3 by an urea group or an oxalylamide group; a 2,6-dimethoxy benzoyl group substituted in position 3 by an urea group or an oxalylamide group; a 2,4,6-trimethyl benzoyl group substituted in position 3 by an urea group or an oxalylamide group; and a 2,4,6-trimethoxybenzoyl group substituted in position 3 by an urea group or an oxalylamide group wherein the urea group and the oxalylamide group include a tertiary amine group positioning a phosphorus atom of the acylphosphine oxide initiator in a 1 to Z position, where position 1 is defined as that of the phosphorus atom and position Z is defined as the nitrogen atom of the tertiary amine group with Z representing an integer of at least 11; and that the acyl phosphine oxide initiator contains no more than two photoinitiating moieties having a phosphine oxide group.

The invention relates to a condensate-oil-resistant and temperature-resistant foam scrubbing agent for deep coal bed gas exploitation and a preparation method of the condensate-oil-resistant and temperature-resistant foam scrubbing agent. The method comprises the following steps: (1) mixing 45-55 parts of sodium 3-chloro-2-hydroxypropanesulfonate and 14-28 parts of lauryl sodium sulfate, dissolving in an aqueous solution containing a special additive, adding 70-110 parts of aliphatic tertiary amine, heating to dissolve the aliphatic tertiary amine, adding the mixed solution into a three-neck flask, adjusting the pH value, heating, adjusting the pH value once every 25-35 minutes, reacting at 70-90 DEG C for 6-8 hours, and cooling to obtain a reaction solution; obtaining a yellow viscous product, namely the long-chain fat hydroxypropyl sulfonated betaine; and (2) adding 5-10 parts of a mixture of polyacrylamide and cellulose and 1-8 parts of nanoparticles into 80-150 parts of a product obtained in the step (1) to obtain the condensate oil-resistant temperature-resistant foam scrubbing agent. The lowest surface tension of the foam scrubbing agent can reach 28.12 mN / m, the foam scrubbing agent is high in foaming capacity, the foam height in clear water can reach 980 mL, the half-life period in high condensate oil content can reach 350 s, the condensate oil content reaches 35%, the foam height can still reach 750 mL, and the liquid carrying rate can reach 83.2%.

The invention relates to an alkyl tertiary amine quaternization reaction preparation process based on a micro-channel reactor, which comprises the following steps: mixing aliphatic tertiary amine and an alkylating agent, adding into a solvent, diluting into a mixed diluent, conveying to the micro-channel reactor, controlling the reaction temperature at 70-120 DEG C, and carrying out quaternization reaction to generate a reaction mixture containing target alkyl tertiary amine quaternary ammonium salt. The alkyl tertiary amine quaternary ammonium salt is synthesized by utilizing the micro-channel reactor, and compared with a traditional reaction kettle method production process, efficient mass and heat transfer and process enhancement in the reaction process can be realized, and continuity and accurate control of the reaction process can be realized, so that the reaction efficiency and the product quality of alkyl tertiary amine quaternization reaction are improved.

The invention relates to a cationic hydrophilic softener for chinlon dyeing in one bath as well as a preparation method and application of the cationic hydrophilic softener. The method comprises the following steps: S1, carrying out hydrosilylation reaction on end hydrogen-containing silicone oil and allyl epoxy polyether under the action of a platinum catalyst; s2, polyol containing hydroxyl and polyisocyanate are subjected to a reaction under the action of a first catalyst, and a-NCO-terminated polyurethane prepolymer is generated; a chain extender containing a tertiary amine group is added into the polyurethane prepolymer for a reaction; adding the epoxy-terminated polyether silicone oil obtained in the step S1 for reaction, and then adding acid for neutralization to obtain cationic polyurethane modified silicone oil; and S3, emulsifying. The softening agent prepared by the invention has excellent stability in a high-temperature acid dye bath, and does not demulsify and stick to a vat; the compatibility with acid dyes is good, and color spots and color spots can be effectively avoided; and after use, the chinlon fabric can be endowed with lasting, smooth and soft hand feeling and good hydrophilicity, and meanwhile, the original whiteness of the fabric is kept.

The invention discloses a photosensitive polyimide, a negative photoresist and an application of the photosensitive polyimide in preparation of a film, the structure of the photosensitive polyimide is shown in the specification, X is a tetravalent organic group and is a residue X of a polyimide polymerization monomer tetracarboxylic dianhydride; y is a divalent organic group and is a residue Y of a polyimide polymerization monomer diamine; r1 and R2 are monovalent organic groups and are residues of primary alcohol forming side chain ester bonds of side chain polyamic acid ester; side chains R1 and R2 at least contain tertiary amine structures, and at least one of the side chains R1 and R2 containing the tertiary amine structures can form ammonium salt with phosphate containing an allyl structure; and n is an integer from 2 to 150. The invention provides a photosensitive polyimide which can be developed by adopting an alkaline aqueous solution, can be cured at low temperature and can form a negative pattern, a preparation method of a photoresist composition of the photosensitive polyimide, and a photoetching curing film, which can be applied to display industry or semiconductor industry as an insulating layer, a passivation layer or an interlayer dielectric layer and the like.

The invention relates to the technical field of fibers, and particularly discloses a skin-friendly fiber, a preparation method of the skin-friendly fiber and a hygienic product with the skin-friendly fiber. The skin-friendly fiber comprises a fiber matrix and a coating layer coating the fiber matrix, and the fiber matrix comprises a core layer and a skin layer coating the core layer; the core layer is prepared from the following raw materials: PET resin, whitening master batch, a flexibilizer, a compatilizer and an antioxidant; the skin layer comprises the following raw materials: PE resin, an initiator, glycidyl methacrylate and tertiary amine; the coating layer comprises the following raw materials: red camellia oil microcapsules and polylysine; the capsule core of the red camellia oil microcapsule is red camellia oil, and the capsule wall of the red camellia oil microcapsule is prepared from the following raw materials: chitosan, hyaluronic acid and a glutaraldehyde solution in a mass ratio of 1: (2-3): (1.5-2). The skin-friendly fiber can be used for manufacturing non-woven fabrics of hygienic products, and has the advantages of being skin-friendly, soft, breathable and high in moisture penetrability.

The invention belongs to the field of medicine, particularly relates to the technical field of delivery lipid, and discloses multi-tertiary amine multi-tail-chain ionizable cationic lipid, a composition containing the same and application of the multi-tertiary amine multi-tail-chain ionizable cationic lipid. The multi-tertiary-amine multi-tail-chain ionizable cationic lipid provided by the invention comprises a structure as shown in a formula (I), can be used for nucleic acid targeted delivery, and can significantly enhance the off-target prevention effect of mRNA vaccines or drugs. # imgabs0 #

The invention discloses a ketoazine-based polymer, an anion exchange membrane and a preparation method and application of the ketoazine-based polymer and the anion exchange membrane. A first linking group and a second linking group are mixed and then mixed with an aryl monomer A in an aprotic solvent of halogen atoms; slowly adding a super acid mixture; performing polymerization reaction in an environment of-5 to 3 DEG C to obtain a reaction solution; pouring the reaction liquid into a first mixed solvent to obtain PAAz; carrying out primary quaternization reaction on PAAz through carbonate, bicarbonate or hydroxide salt of alkali metal, and adding an organic base catalyst to assist the primary quaternization reaction; in the first quaternization reaction, a quaternization reagent is added; and pouring into a second mixed solvent, and precipitating to obtain purified PAAz. Under the condition of super acid catalysis, two or more alicyclic amine derivatives containing ketone groups react with one or more aromatic fused rings to generate a polymer containing secondary or tertiary amine. And carrying out quaternization treatment to finally form the cationic polymer.

The invention discloses an alkyl ether ester ionizable lipid compound and application thereof. The alkyl ether ionizable lipid compound is composed of a head group R1, a linker L and a tail group R2 in sequence. According to the alkyl ether ionizable lipid disclosed by the invention, two tertiary amine centers are connected by adopting a cyclic carbon chain structure, so that the delivery effect is obviously higher than that of ionizable lipid linearly connected with the two tertiary amine centers, and by adding an ether bond-containing tail structure in the alkyl ether ionizable lipid, the cell endocytosis and the cell endosome escape effect of LNP are improved; therefore, more mRNA is delivered into a living body and translated and expressed into corresponding proteins. Therefore, compared with the ionizable lipid in the prior art, the alkyl ether ionizable lipid disclosed by the invention has a better delivery effect.

The invention belongs to the technical field of chemical engineering and fine fluorine chemical synthesis, and particularly relates to a preparation method of sulfuryl fluoride chloride. According to the preparation method, through the synergistic effect of a gas-liquid reaction system and a closed-loop circulation system, a tertiary amine hydrofluoric acid adduct (such as Et3N.nHF, n = 2-6) is used as a fluorinating reagent, sulfuryl fluoride chloride is generated through a rapid cross-flow reaction in excessive sulfuryl chloride (SO2Cl2) under the conditions that the temperature is 65-100 DEG C and the pressure is 0.5-2.0 MPa, and a liquid-phase byproduct tertiary amine hydrochloride hydrogen fluoride adduct (such as Et3N.HCl. (n-1) HF) is used for preparing the sulfuryl fluoride chloride. Supplementing hydrogen fluoride to regenerate the catalyst and recycling; and after a gas-phase product is pressurized, rectified and purified by a light component removal tower and a heavy component removal tower, totally returning a light component (Cl2 / SO2) and a heavy component (SO2Cl2) to a synthesis system for recycling. According to the method, the reaction temperature, the reaction pressure, the liquid phase dispersion degree and the contact time are accurately controlled, so that the reaction product generates SO2FCl with high selectivity, and the byproduct (R3N.HCl. (n-1) HF) is kept in a liquid phase, so that the reaction can be continuously carried out, and conditions are created for subsequent treatment.

The invention discloses an anti-boron salt-tolerant polymer suspension emulsion and a preparation method thereof, and relates to the technical field of suspension emulsions. The preparation method comprises the following steps: firstly, reacting 1, 3-bis (dimethylamino)-2-propanol with oxalyl chloride monoallyl ester to prepare double-bond modified tertiary amine when preparing the boron-resistant and salt-resistant polymer suspension emulsion; reacting the double-bond modified tertiary amine with propane sultone to prepare an amphoteric monomer; reacting the double-bond modified tertiary amine with 1-bromodecane to prepare a hydrophobic monomer; the preparation method comprises the following steps: copolymerizing acrylamide, maleic acid, an amphoteric monomer and a hydrophobic monomer to prepare modified polyacrylamide; and mixing the modified polyacrylamide, the slurry preparation soil, the polyacrylonitrile ammonium salt, the organic silanol, the emulsified paraffin and the boron inhibitor with water to prepare the boron-resistant and salt-resistant polymer suspension emulsion. The boron-resistant and salt-resistant polymer suspension emulsion prepared by the invention has the advantages of salt resistance, temperature resistance, good filtrate loss reduction performance and boron resistance.

The invention discloses a fluorosilicone waterborne polyurethane emulsion as well as a preparation method and application thereof, and belongs to the technical field of polyurethane emulsion synthesis. The preparation method comprises the following steps: taking fluorinated diol, sulfonic diol and alkynyl diol as raw materials, preparing a polyurethane prepolymer with a side chain containing a sulfonic group and an alkynyl group through a diisocyanate condensation reaction and organic tertiary amine neutralization salification, and connecting a catechol group and an active siloxy group to the side chain through an alkyne-azide click reaction. And finally, carrying out self-emulsification to obtain the fluorosilicone waterborne polyurethane emulsion. After the fluorosilicone waterborne polyurethane emulsion is dried into a coating, the coating has excellent adhesive force on the surfaces of various base materials, and the coating not only has friction resistance, acid and alkali resistance and organic solvent resistance, but also has super-hydrophobicity, water soaking resistance and pollution resistance.

The invention relates to the technical field of antistatic materials, and relates to an antistatic styrene copolymer for producing a carrier tape and a preparation method thereof, and the antistatic styrene copolymer comprises the following components by mass: 45%-60% of HIPS, 6%-10% of HIPS / PPO alloy, 15%-25% of conductive carbon black, 5%-15% of a compatilizer, 6%-15% of a flexibilizer, 2%-5% of a carbon black dispersant, 0.3%-0.8% of an antioxidant, and 0.5%-1% of a lubricant. The carbon black dispersing agent comprises a coupling agent and medium-chain and long-chain aliphatic tertiary amine. Through the collaborative design of the tertiary amine-coupling agent binary carbon black dispersing agent and the HIPS / PPO heat-resistant alloy, the styrene system filled with 15%-25% high carbon black has no crystal point, no carbon deposit, no melting in 225 DEG C heat sealing and no black falling in tape tearing, and the industrial-grade requirement of continuous high-speed production of carrier tapes is met.

The invention provides a biquaternary ammonium salt bactericide as well as a preparation method and application thereof, and belongs to the technical field of biquaternary ammonium salt preparation. The invention aims to develop a biquaternary ammonium salt bactericide with high potency ratio, and provides an optimized production process scheme and process flow of the biquaternary ammonium salt bactericide by systematically optimizing multiple aspects such as selection of long-chain tertiary amine and dihalide, solvent and dosage thereof, solvent adding mode, reaction conditions and the like. According to the method, the yield of the biquaternary ammonium salt bactericide can be greatly improved, meanwhile, even if the method is used for industrial large-scale production, the yield of the biquaternary ammonium salt bactericide can still be kept at the level larger than 90%, and technical support is provided for final industrial production and large-scale application of the biquaternary ammonium salt bactericide.

The invention relates to a zwitterionic particle and a preparation method and application thereof, the zwitterionic particle is of a core-shell structure, the shell is a water-soluble zwitterionic polymer, and the core is a water-insoluble cross-linked polymer; the preparation method comprises the following steps: firstly, preparing core-shell polymer particles of which shells are polydiolefin and cores are crosslinked polystyrene or crosslinked polymethacrylate polymers by combining an active anionic polymerization mediated polymerization induced self-assembly technology with a post-polymerization modification technology; then, polydiolefin of a shell layer is hydrolyzed with trifluoroacetic acid, hydroxylated polydiolefin is prepared, hydroxyl is converted into potassium alkoxide, bromoisobutyl ester or a chain transfer reagent, and allyl monomers containing tertiary amine are initiated to be subjected to controllable / active polymerization; and finally, converting the tertiary amine group into a zwitterionic group by using a modification reagent to prepare the core-shell particle of which the shell is a water-soluble zwitterionic polymer and the core is a water-insoluble polymer. According to the invention, the problem of limitation in the aspects of controllability, function expansion and the like in the prior art is solved.

The invention belongs to the field of electronic device protective coatings, and particularly relates to a water-based polyimide / POSS-GO composite coating and a preparation method and application thereof.The method comprises the steps that firstly, dianhydride and diamine monomers react to prepare polyamic acid, then tertiary amine is made into a salt agent to prepare water-soluble polyamic acid salt, and then the water-soluble polyamic acid salt is prepared into a water-soluble polyimide / POSS-GO composite coating; the preparation method comprises the following steps: modifying graphene oxide with aminated polyhedral oligomeric silsesquioxane to prepare a POSS-GO filler, uniformly dispersing the filler and water-based polyamic acid salt, spraying on the surface of a base material, and then carrying out thermal imidization treatment to prepare the water-based polyimide / POSS-GO composite coating. The composite coating prepared by the method is a novel coating material with excellent corrosion resistance and low dielectric property, not only provides a new thought for the design of a high-performance anticorrosive coating, but also provides a potential material strategy for a multifunctional protective coating of an electronic device.

A resin for grayscale digital light processing 3D printing includes a donor moiety, an acceptor moiety, a rigid moiety, a photoinitiator, and a photoabsorber. The donor moiety is an acrylate monomer with a side group of a free carbonyl, a primary amine on an acrylate, a secondary amine on an acrylate, and / or a tertiary amine on an acrylate. The acceptor moiety is different than the donor moiety and is an acrylate monomer with a side group of a free hydroxy, a primary amine, secondary amine, and / or an imine. And the rigid moiety is acrylate monomer with a side group of a cyclohexyl, a substituted cyclohexyl, or a bicyclic structure. A monolithic structure formed from the resin using grayscale digital light processing 3D printing can have a Young's modulus ranging from 0.1 MPa to 100 MPa.

A diesel fuel composition including (a) a quaternary ammonium salt additive; and (b) one or more nitrogen-free detergents; wherein the quaternary ammonium salt additive includes the quaternised reaction product of a hydrocarbyl substituted succinic acid derived acylating agent and a compound able to react with said acylating agent and which includes a tertiary amine group; wherein each molecule of the hydrocarbyl substituted succinic acid derived acylating agent includes on average at least 1.2 succinic acid moieties.