1597 results about "Tertiary amine" patented technology

The invention relates to the technical field of polyurethane production, in particular to a polyurethane super-hydrophobic foam composite material for packaging and a preparation method thereof. The polyurethane super-hydrophobic foam composite material for packaging is prepared by reacting a component A and a component B according to a mass ratio of 100: (31.7-46.5), wherein the component A comprises polyether polyol X with high molecular weight and high activity, polymer polyol, a chain extender, a cross-linking agent, an organic metal catalyst, a tertiary amine catalyst, a foam stabilizer, a foaming agent, a flame retardant, inorganic filler and the like, and the component B is isocyanate modified by polyether polyol Y with high functionality. An ester bond, a rigid benzene ring group and a Si-O-Si chain segment are introduced into a polyether polyol molecular chain segment to improve the internal soft segment structure and chemical crosslinking density of the polyurethane foam, and the prepared super-hydrophobic polyurethane foam not only has excellent hydrophobicity and high temperature resistance, but also is low in density and good in mechanical property.

Provided in the present invention is a new cationic lipid containing two tertiary amine groups. The structure is as shown in general formula (1), wherein the definition of each symbol in the formula is consistent with that described herein. The cationic lipid containing two tertiary amine groups is a pharmaceutically acceptable, biodegradable or highly biocompatible cationic lipid, and has the advantages of low toxicity, low immunogenicity and high biocompatibility. In the present invention, one or more biodegradable groups are contained between the hydrophilic head and the lipophilic tail chain of the cationic lipid containing two tertiary amine groups, thus preventing the endosome storage of an LNP prepared therefrom, increasing the endosome escape efficiency of the LNP in cells, and promoting the release of drugs into cytoplasm to serve the function thereof.

The invention relates to the technical field of petrochemical engineering, and discloses a temperature-resistant anti-swelling agent for fracturing and a preparation process thereof.The preparation method comprises the steps that glycerol triglycidyl ether and diethanol amine are subjected to a ring-opening reaction, a polyhydroxy tertiary amine monomer is obtained, then the polyhydroxy tertiary amine monomer and chloromethylated polystyrene are subjected to a quaternization reaction, and the temperature-resistant anti-swelling agent for fracturing is obtained. Quaternary ammonium salt groups of the anti-swelling agent and negative charges on the surface of clay form electrostatic interaction, and hydroxyl groups and the surface of the clay form hydrogen-bond interaction, so that the anti-swelling agent can be firmly adsorbed on the surface of the clay to form a layer of polymer film, the clay is prevented from being in contact with water, the phenomenon that the clay swells when encountering water is effectively inhibited, and the anti-swelling rate is very high. And the anti-swelling agent contains a heat-resistant polystyrene molecular chain, has excellent high temperature resistance, can maintain good structural stability at high temperature, still maintains high anti-swelling rate, and is suitable for a fracturing fluid system for high-temperature oil reservoir exploitation.

The invention belongs to the technical field of pharmaceutical chemical processes, and particularly relates to a preparation method of a penem antibiotic intermediate 4-BMA, which comprises the following steps: adding Zn powder, chlorosilane, aliphatic tertiary amine, zinc salt and 4-AA in a formula (I) into THF (tetrahydrofuran), uniformly stirring, dropwise adding a THF solution of alpha-haloamide with an induction group in a formula (II) for reaction, filtering the reaction solution, removing the zinc powder, and drying to obtain the penem antibiotic intermediate 4-BMA. Extracting the filtrate to obtain a THF phase, washing with an aqueous solution of potassium oxalate, and recovering THF to obtain a formula (III); and carrying out oxidative hydrolysis, sulfur dioxide quenching, sulfur dioxide acid regulation crystallization and recrystallization on the formula (III) to obtain the intermediate 4-BMA. According to the preparation method disclosed by the invention, a zinc salt is used as a catalyst during preparation of the formula (III), potassium oxalate is used for removing residual Zn (II) in a THF phase, SO2 is used for quenching hydrogen peroxide and acid regulation and crystallization of 4-BMA, the oxygenolysis problem of 4-BMA is solved, and the preparation method has the characteristics of greenness, safety and high efficiency, is strong in product competitive advantage and is suitable for industrial production.

The invention relates to the technical field of CO2 capture and separation, and particularly discloses an anhydrous absorbent with a self-extraction function as well as application and a recovery method. The anhydrous absorbent is synergistically composed of a mixed amine absorption enhancer with specific composition and a hydrophobic organic solvent, wherein the mixed amine absorption enhancer comprises primary amine, secondary amine and tertiary amine. The mixed amine absorption accelerant combines the advantages of high reaction activity of primary amine, low regeneration heat of secondary amine and high absorption capacity and strong hydrophobicity of tertiary amine, so that the anhydrous absorbent shows excellent self-extraction capacity in the adsorption and desorption processes of acid gas, particularly, the anhydrous absorbent after absorbing the acid gas forms a less-water CO2 rich phase, and the CO2 rich phase has excellent self-extraction capacity. And due to the characteristic of less water, sensible heat and latent heat of vaporization required by a rich phase in a CO2 desorption stage are remarkably reduced, so that the problem that the energy consumption is too high in the regeneration process of the existing water-based absorbent is effectively solved.

A photobase generator includes a compound including: first skeletons represented by the following formula (a); and a second skeleton including nitrogen atoms bonding to bonding positions of the first skeletons to form amide groups, wherein, in a molecule, a number of the first skeletons is two or more, a number of the nitrogen atoms, configuring the amide groups, in the second skeleton is the same as the number of the first skeletons, and at least one of the nitrogen atoms configuring the amide groups is converted into a nitrogen atom configuring a secondary amine or a tertiary amine by light irradiation. In the formula (a), G is a divalent aromatic group, and * represents the bonding position with the nitrogen atom.

The preparation method comprises the following steps: mixing 20-40 parts by mass of substituted hydroxymethyl glycoluril, 45-85 parts by mass of mercaptocarboxylic acid and 0.5-3 parts by mass of an acidic catalyst, stirring and reacting for 1-10 hours at the temperature of 50-150 DEG C under the pressure condition of-0.01 to-0.1 MPa, adding 300-800 parts by mass of an organic solvent for diluting after the reaction is finished, washing and purifying with deionized water, and collecting an organic layer, thereby obtaining the mercaptan curing agent. Concentrating and drying to obtain the mercaptan curing agent. According to the thiol curing agent, the rigid glycoluril group is introduced, so that the rigidity of a cured product structure is improved, and the mechanical property, the adhesive property, the heat resistance and the damp-heat aging resistance of a cured product are improved; four tertiary amine groups in the substituted glycoluril have a certain self-promotion effect on a thiol curing epoxy reaction, and the curing reaction temperature is reduced under the condition that an accelerant is not added; the glycoluril-containing thiol epoxy resin curing agent disclosed by the invention has good application value and development prospect.

The invention relates to an impact-resistant chlorinated polyvinyl chloride composite material and a preparation method thereof, and belongs to the technical field of polymer composite materials. The composite material comprises the following components: 100 parts of CPVC resin, 6.5 to 9.5 parts of a modified impact modifier, 2.6 to 3.2 parts of a heat stabilizer, 1.5 to 2 parts of a lubricant, 1.2 to 1.6 parts of a processing aid, 0.2 to 0.25 part of a light stabilizer and 8 to 11 parts of a filler, the modified impact modifier takes a POSS cage structure as a core, a branch chain sequentially contains thioamide-secondary amine-tertiary amine structures, a polarity gradient is formed and fully extends into a macromolecular chain of CPVC to transmit and dissipate impact energy, meanwhile, the amine structure interacts with chlorine groups in a molecular chain of CPVC to form molecular anchoring, expansion of crazes is inhibited, and the impact strength of the CPVC is improved. The continuity and the stability of a bonding interface are maintained, so that the composite material keeps relatively high mechanical strength and thermal stability.

The invention belongs to the technical field of coatings, and relates to a polysiloxane epoxy hybrid environment-friendly coating and a preparation method thereof. The coating belongs to an environment-friendly solvent type coating with low VOC content, modified epoxy resin is adopted as a base, auxiliaries such as a film-forming agent and a dispersing agent are added, and benzophenone and tertiary amine composite photoinitiator is supplemented, so that the prepared coating has good corrosion resistance, high temperature resistance and the like, and the coating can quickly form a film at normal temperature and under the UV illumination condition, shortens the curing period, and is suitable for large-scale popularization and application. The emission of VOC (volatile organic compounds) is reduced.

The invention discloses preparation and application of an imido covalent organic framework material containing imidazolyl ionic liquid. The imido covalent organic framework material (ILs-TPN-COFs) containing the imidazolyl ionic liquid is obtained by connecting the imidazolyl ionic liquid [CnCmILs (at) Br] to an imido covalent organic framework TPN-COFs through a covalent bond. The material has an ionic liquid tertiary amine N active site and a halogen anion active site, and can promote CO2 activation and ring opening of epoxide. The ILs-TPN-COFs catalytic material has the advantages of uniform distribution of active sites, better stability, easiness in separation of the catalyst from a reaction system, better repeatability and the like. According to the invention, the prepared novel ILs-TPN-COFs material is applied to catalysis of synthesis of propylene carbonate from carbon dioxide and epoxypropane, and shows excellent catalytic performance under mild reaction conditions.

A method for preparing a sorbent material (3) for separating gaseous carbon dioxide from a gas mixture, preferably from at least one of ambient atmospheric air (1), flue gas and biogas, containing said gaseous carbon dioxide as well as further gases different from gaseous carbon dioxide, by cyclic adsorption / desorption using a sorbent material (3) capable of reversibly binding carbon dioxide and adsorbing said gaseous carbon dioxide in a unit (8), wherein the sorbent material (3) comprises: primary amine moieties as well as at least one of secondary amine, and tertiary amine moieties immobilized on a solid support, and is made using an amination pathway avoiding cross-linking.

The invention discloses high-strength concrete, a well lid and a preparation method of the well lid, and relates to the field of building materials. The high-strength concrete comprises cement, coarse aggregate, fine aggregate, modified steel fibers, a polycarboxylic acid water reducer and water. Wherein the coarse aggregate comprises broken stones with the continuous grading of 5-8 mm and broken stones with the continuous grading of 10-16 mm; the fine aggregate adopts medium-coarse sand with the particle size range of 1.8-2.2 mm; the preparation raw materials of the modified steel fiber comprise an amino silane coupling agent, an epoxy resin coating and steel fiber, and the preparation raw materials of the epoxy resin coating comprise bisphenol A epoxy resin, nanoparticles, hydroxy acrylic resin, a tertiary amine catalyst and a curing agent. According to the modified steel fiber, the reinforcing effect of the steel fiber on a concrete matrix can be fully exerted, so that concrete which is high in pressure resistance and bearing capacity and especially suitable for well lid manufacturing is obtained.

The disclosed technology provides a vitrimeric poly(diketoenamine) network comprising: a plurality of multifunctional triketone dimers; a plurality of multifunctional amine species containing primary or secondary amine groups, but no tertiary amine groups; and optionally, one or more amine-reactive groups. The disclosed technology also provides a method of making a vitrimeric polymer network, comprising: obtaining multifunctional triketone dimers; obtaining a multifunctional imine compound, with imine groups blocking amine groups; mixing the multifunctional triketone dimers with the multifunctional imine compound, thereby forming a polymer precursor mixture; applying the polymer precursor mixture onto a substrate; and allowing the multifunctional imine compound to undergo hydrolysis with water, unblocking the amine functional groups and generating a multifunctional amine compound. The multifunctional amine compound reacts with the multifunctional triketone dimers to form a vitrimeric polymer network. The vitrimeric polymer network may be depolymerized back to monomers, which may be repolymerized in a closed-loop system.

The invention discloses a two-phase absorbent and application thereof. The two-phase absorbent comprises the following components in percentage by mass: 10-35% of a main absorbent, 20-50% of a phase-splitting agent, 0-15% of an accelerant and 0-70% of water, wherein the total mass of the two-phase absorbent is 100%; wherein the main absorbent is polyamine, the polyamine contains more than three amino groups, more than three carbon atoms are arranged between the adjacent amino groups, and at least one of the more than three amino groups is a tertiary amino group; the phase splitting agent is an alcohol ether compound. The two-phase absorbent provided by the invention has better absorption performance, can reduce the generation of oxidative degradation, and has higher oxidation stability.

The invention discloses a kind of preparation method of amino hyperbranched siloxane and its modified polyimide aerogel material.First, alkoxysilane X with amino active functional group, alkoxysilane Y of inactive functional group and water are carried out autocatalytic controlled hydrolysis condensation under sub-stoichiometric ratio, obtain multifunctional group (such as other active groups, alkoxyl group, amino) amino hyperbranched siloxane liquid (HPSi NH2) with controllable amino content, then using HPSi NH2 as cross-linking agent and anhydride-terminated polyamic acid solution reaction to obtain functionalized polyamic acid, which is stirred with tertiary amine and deionized water to obtain functionalized polyamic acid wet gel, which is passed through freeze drying, high temperature imidization treatment to obtain amino hyperbranched siloxane modified polyimide aerogel material. This material has excellent flexibility, resilience, heat resistance and flame retardancy, and can be applied to aerospace, communication, catalysis and filtration fields.

The present invention relates to a tandem organic light-emitting device comprising a plurality of light-emitting layers and, more specifically, to an organic light-emitting device comprising a novel charge generation layer (CGL). The CGL according to the present invention has a first compound having 4,5-diazaspirobifluorene as the core thereof, which is applied as an electron transport material of an N-type CGL. In addition, a second compound having at least one tertiary amine as the core thereof is applied as a hole transport material of a P-type CGL, and the combination of the first compound and the second compound lowers the driving voltage of the device and further improves the efficiency and lifespan thereof. Furthermore, the organic light-emitting device of the present invention can achieve further improved device performance through a CGL comprising the first compound, lithium or ytterbium, the second compound and a third compound at the same time.

The invention discloses a self-crosslinking hydrogel with a tertiary amine group and preparation and application thereof, and belongs to the field of biomedical polymer materials, the self-crosslinking hydrogel comprises aminophenylboronic acid modified oxidized glucan, tertiary amine compound modified oxidized glucan and a solvent medium; the preparation method comprises the following steps: dissolving amino phenylboronic acid modified oxidized dextran and tertiary amine compound modified oxidized dextran in a solvent medium, mixing, standing for a certain time, and carrying out self-crosslinking to obtain the self-crosslinking hydrogel with tertiary amine groups. A cross-linking point (phenylboronic acid) of the gel network is a response unit of glucose. In addition, the hydrogel can effectively avoid uncontrollable drug release caused by non-responsive factors, and the response release efficiency of the drug is improved; by loading the hypoglycemic drug insulin to be applied to the treatment research process of diabetes, the occurrence of hypoglycemia can be avoided, and meanwhile, the possibility is provided for realizing intelligent controlled release of insulin through blood glucose response.

The invention relates to the technical field of water treatment, in particular to a composite flocculant for tunnel construction wastewater treatment and a preparation method thereof. The method comprises the following steps: carrying out a reaction on triethanolamine and isocyano ethyl methacrylate to prepare tertiary amine acrylate; reacting tertiary amine acrylate with methoxyl-polyethylene glycol-chlorine to prepare polyethylene glycol modified quaternary ammonium salt acrylate; further reacting with methyl dichlorosilane to prepare a modifier; and compounding the modifier with hydrotalcite, sodium silicate and an iron-magnesium-calcium mixed solution to prepare the composite flocculant. The flocculant realizes efficient flocculation and pH regulation through mechanisms such as electric neutralization and adsorption bridging, has the characteristics of quickly gathering suspended particles, reducing sludge yield and improving floc compactness and dehydration performance, is suitable for treatment of high-concentration suspended solids and slightly alkaline wastewater, shows comprehensive advantages of high efficiency, economy and environmental protection, and has wide application prospects. The field treatment requirements of tunnel construction wastewater are met.

The invention discloses a method for separating iron and lithium in a lithium iron phosphate iron salt leaching solution and recycling iron phosphate, and belongs to the technical field of waste lithium battery recycling. The method comprises the following steps: constructing a bis (2-ethylhexyl) phosphate and trioctyl decyl tertiary amine mixed extraction system for selective extraction of Fe < 3 + >, adopting phosphoric acid for reverse extraction, recycling phosphoric acid reverse extraction liquid, preparing iron phosphate and the like. According to the method, efficient enrichment of Fe < 3 + > and efficient elution of Fe < 3 + > from a loaded organic phase are realized. The purity of the raffinate Li solution is relatively high, so that the subsequent preparation of battery-grade lithium carbonate is facilitated. The strip liquor can be recycled for multiple times, an iron intermediate is precipitated through pH adjustment, and the FePO4 product can be finally prepared through washing, aging and high-temperature calcination. The method is high in extraction selectivity, recyclable in process and mild in operation condition, has good separation effect and resource utilization efficiency, and is suitable for popularization and application of a Fe / Li separation process in lithium battery recovery.

The invention discloses solvent-free hydrophilic block silicone oil and a preparation method thereof, and the method comprises the following steps: carrying out equilibrium reaction on chloropropyl alkyl alkoxy silane and hydroxyl-terminated polydimethylsiloxane in an acid catalyst to prepare linear silicone oil of which the two end structures are chloropropyl alkyl alkoxy; the linear silicone oil is neutralized and filtered and then reacts with tertiary amine, and the quaternary ammonium salt-terminated hydrophilic block silicone oil is prepared. According to the method, no solvent participates in the whole synthesis process of the block silicone oil, a monomer polymerization process is adopted, and compared with a traditional method, operation is easy, raw materials are easy to obtain, cost is low, and the process saves energy, reduces consumption, is environmentally friendly and is suitable for industrial production of a monomer factory. The block silicone oil prepared by the invention has excellent hydrophilicity, and can endow fabrics with excellent fluffy, soft and smooth handfeel and hydrophilic performance when being used as a finishing agent for fabrics such as cotton, polyester, polyester cotton and the like.

The invention discloses an impact-resistant industrial coating and a manufacturing method thereof, and relates to the technical field of industrial coatings. The impact-resistant industrial coating comprises the following raw materials in parts by weight: 80-100 parts of epoxy resin, 2-5 parts of graphene oxide, 3-5 parts of an antistatic agent, 5-8 parts of a modified thickener, 1-3 parts of a dispersant, 0.5-1.5 parts of a leveling agent, 2-3 parts of an antioxidant, 8-12 parts of a curing agent and 100-140 parts of deionized water. The preparation method comprises the following steps: reacting polyethylene glycol diethylene oxide methyl ether with 2-(methacrylic acid) ethyl ester 3, 5-diaminobenzoic acid to generate a polymer; reacting the polymer with 3-(dimethylamino)-1-propanethiol to generate a tertiary amine-terminated polymer; and carrying out quaternization reaction on the tertiary amine-terminated polymer and bromododecane to obtain the antistatic agent. The impact-resistant industrial coating prepared by the invention has excellent antistatic property and rheological property.

The invention relates to the technical field of organic synthesis, in particular to a method for homogeneous catalytic synthesis of dimethyl carbonate by using a liquid separation method to separate a catalyst, which comprises the following steps: by using 0.3-15% long-chain tertiary amine as a homogeneous catalyst, carrying out homogeneous reaction on cyclic carbonate and methanol in a mass ratio of 1: (1.2-5.5) at 60-80 DEG C for 4-7 hours. And after the homogeneous transesterification reaction is completed, carrying out atmospheric distillation on the reaction mixture, and collecting fractions to obtain the target product dimethyl carbonate. Carrying out liquid separation on the heterogeneous atmospheric distillation residual liquid, and collecting a lower-layer material to obtain a by-product; and the collected material is a catalyst which can be directly recycled subsequently. The dimethyl carbonate synthesis method provided by the invention has the characteristics of high catalytic efficiency, easy catalyst separation, environmental protection, energy saving and the like.

The present disclosure relates to a preparation method for a composite quaternary ammonium salt cationic collector and a use of the preparation method. The method comprises: adding halogenated alkyl into alkyl tertiary amine containing amide groups for a quaternization reaction to obtain an intermediate; and adding a catalyst into the intermediate for a catalytic reaction to obtain a first mixture, adding alkyl benzylamine into the first mixture for an amidation reaction to obtain a second mixture, and carrying out desalination treatment on the second mixture to obtain a composite quaternary ammonium salt cationic collector, wherein a molar ratio of the alkyl tertiary amine to the halogenated alkyl to the alkyl benzylamine is (1-1.4):(0.8-1.2):(1-1.4).

The invention discloses a surface coating modified calcium phosphate microsphere and a preparation method thereof, and belongs to the technical field of calcium phosphate microsphere preparation. The surface coating modified calcium phosphate microspheres are prepared from the following components in parts by weight: 60 to 68 parts of calcium phosphate ceramic powder, 20 to 32 parts of modified bioactive bodies, 8 to 12 parts of composite pore forming agents and 2 to 5 parts of binding agents, the modified bioactive body is prepared from vinyltriethoxysilane, butyl dibutyl phosphate, citric acid, calcium acetate, magnesium sulfate and polyether-ether-ketone fibers, and the composite pore-forming agent is prepared from octyl dimethyl tertiary amine, epoxy chloropropane, hydrolyzed soybean protein and starch. The calcium phosphate microspheres prepared by the method have excellent porosity and biological activity.

The invention belongs to the technical field of novel fertilizers, and particularly relates to a growth promoting type macroelement water-soluble fertilizer and a preparation method and application thereof.The fertilizer is prepared from, by weight, 4-6 parts of tertiary amine synergist, 220-230 parts of monopotassium phosphate, 350-360 parts of urea, 3-5 parts of compound amino acid, 3-5 parts of sorbitol and 15-20 parts of ethylene glycol, the invention relates to N, N '-tetra (2-fluorobenzyl diamido) diphenyl ether. The invention aims at innovating a macroelement water-soluble fertilizer product to prepare the novel tertiary amine synergist, so that the additional value and the use effect of the macroelement water-soluble fertilizer can be effectively improved, and a new direction and a new idea are provided for development and use of a new functional macroelement water-soluble fertilizer technology.

The invention provides an environment-friendly PUR hot melt adhesive with excellent temperature resistance as well as a preparation method and application thereof, and belongs to the technical field of adhesives. The environment-friendly PUR hot melt adhesive is prepared from the following raw materials in parts by mass: 50 to 65 parts of polyester polyol, 10 to 20 parts of polyether polyol, 15 to 30 parts of isocyanate, 5 to 10 parts of modified isocyanate, 5 to 10 parts of chain extender and 3 to 5 parts of anti-aging additive, wherein the polyester polyol is formed by carrying out dehydration polycondensation on polybasic acid and polyol through a vacuum melting method, and the polybasic acid comprises binary acid, cinnamic acid, chlorogenic acid and tannic acid according to the mass ratio of (3-5): (0.5-0.8): (1.2-1.6): 1; the anti-aging auxiliary agent is a nano inorganic oxide containing a maleimide group; the modified isocyanate is a mixture obtained by reacting polyisocyanate, sulfamic acid, hydroxycarboxylic acid and tertiary amine. The PUR hot melt adhesive prepared by the invention has excellent thermal stability, and the cohesiveness of the PUR hot melt adhesive can be kept basically unchanged in a long-term high-temperature environment and a thermal cycle environment.

The invention provides a transparent thermoplastic polyurethane elastomer and a preparation method thereof, and belongs to the technical field of thermoplastic polyurethane elastomers, the preparation method comprises the following steps: uniformly mixing polyether polyol and polyether polyol, and dehydrating under vacuumizing and heating conditions to obtain a component A; aliphatic isocyanate is used as a component B; uniformly mixing the dehydrated 1, 4-butanediol and a tertiary amine catalyst to obtain a component C; uniformly mixing the component A, the component B and the component C, injecting into a mold, cooling, demolding, and finally heating and vulcanizing to obtain the transparent thermoplastic polyurethane elastomer. The polyether polyol and the polyester polyol are compounded to serve as a two-component soft chain segment, the aliphatic isocyanate and the 1, 4-butanediol serve as a hard chain segment, the proportion and the structure of the polyether polyol and the polyester polyol are changed, the compatibility of the two is improved, the performance advantages of the polyether polyol and the polyester polyol are brought into full play, and the thermoplastic polyurethane elastomer with both mechanical performance and optical transparency is synthesized.

The invention belongs to the technical field of electrolyte materials, and particularly relates to a pH response biopolymer solid electrolyte as well as a preparation method and application thereof. The pH-responsive degradable biopolymer is taken as a main raw material, and one or more functional groups such as pyridine, sulfonic acid, carboxyl, tertiary amine, phosphoric acid and the like are contained. The organic acid and the organic acid salt are selected to adjust the pH value of a medium around the electrolyte, and the contraction / stretching behavior of a molecular chain is influenced by changing the ionization degree of the electrolyte, so that an interpenetrating polymer network structure is formed. The polar functional group of the biopolymer affects the migration behavior of lithium ions under different pH conditions, so that the migration rate and migration quantity of the lithium ions are increased, and the cycle performance of the battery is improved. The electrolyte is suitable for high-performance energy storage devices such as a lithium ion battery, can effectively improve the battery performance, reduces the environmental pollution, and has relatively strong green and environment-friendly advantages.

The invention discloses an electro-synthesis method of alpha-aminomethyl tetrazole, which comprises the following steps: by taking a platinum sheet as a cathode, a carbon rod as an anode and tetrabutylammonium tetrafluoroborate as an electrolyte under the catalysis of constant current, coupling tertiary amine, isonitrile and azido trimethylsilane by a one-pot method to prepare an alpha-aminomethyl tetrazole derivative, and carrying out post-treatment on the obtained reaction mixed solution, and carrying out column chromatography separation to obtain a pure alpha-aminomethyl tetrazole product. The alpha-aminomethyl tetrazole can be obtained only through one-step reaction, the operation steps are few, a large number of oxidizing agents and additives are not used, the post-treatment process is simple, and the product is easy to separate.

The invention provides a piperazinyl steric hindrance type liquid-solid phase change carbon trapping agent and a preparation method thereof, and relates to the field of liquid-solid phase change trapping of CO2. Alkylamine and the like are used as raw materials, piperazinyl steric hindrance type organic amine with secondary amino and tertiary amino structures is designed, and the piperazinyl steric hindrance type organic amine is prepared through ring-opening addition, nucleophilic substitution, cyclization, hydrogenation and other reactions. The piperazinyl steric hindrance type organic amine is compounded with a solvent and a functional additive to prepare the piperazinyl steric hindrance type liquid-solid phase change carbon trapping agent. According to the steric hindrance type phase change carbon trapping agent, on the basis of the electron donating effect of alkyl, the absorption rate of trapping CO2 is increased by 2.2 times compared with that of traditional steric hindrance amine (AMP); on the basis of the steric hindrance effect of the tertiary amine site, the hydrogen-bond interaction between carbamate and the solvent is weakened, liquid-solid phase splitting after the aqueous solution carbon capture system absorbs CO2 is promoted, the problem of poor cycling stability of a non-aqueous solvent system is solved, and the capture efficiency and enrichment degree of CO2 are improved.