The invention provides a preparation method of a modified ferruginous mineral loaded amphoteric
polymer heavy
metal adsorbent, which comprises the following steps: I, pretreating a
mineral matrix, namely crushing,
grinding and sieving ferruginous raw ore to obtain mineral
powder,
grinding and sieving
biochar to obtain
biochar powder, and calcining and activating the mineral
powder and the
biochar powder in a
muffle furnace to obtain a modified ferruginous mineral loaded amphoteric
polymer heavy
metal adsorbent; naturally cooling to obtain a calcined modified
mineral matrix; iI, preparing a precursor dispersion liquid, namely adding the calcined modified
mineral matrix into an
organic solvent, performing
ultrasonic dispersion at
room temperature for 20-40 minutes to obtain a uniform mineral dispersion liquid, sequentially adding an amino
monomer, an acrylic
monomer, a cross-linking agent and an initiator into the dispersion liquid, and uniformly stirring and mixing to obtain a polymerized precursor liquid; iII, in-situ
polymerization reaction: continuously introducing
nitrogen into the
polymerization precursor liquid to remove air in the
system, sealing, and carrying out in-situ free
radical polymerization reaction in a constant-temperature environment to obtain a
solid-phase product; and IV, post-treatment: sequentially washing the
solid-phase product with
methanol and deionized water for multiple times to remove unreacted
monomer and
oligomer impurities, and then
drying,
grinding and sieving to obtain the
magnesium iron mineral loaded amphoteric
polymer heavy
metal adsorbent. The method can be flexibly applied according to actual
wastewater pH characteristics, and the defect that a traditional adsorbent can only treat
single type of heavy metal or needs to frequently adjust the pH is overcome.